File name: Pandora135s1_ManhattanNY-CCNY_20240108_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240113T035202.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240108_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240108T125642.4Z 8773.539380 126 1 46.45 2 84.98 125.34 69.42 161.92 0.00 1 0.00 1 0 25 8.161e-01 1.104e-01 4.218e-01 5.708e-02 8.727375e-01 3.721055e-02 1.130116e-02 -6.000000e+00 5.158275e-01 223.53 -2.00 3.51 -2.00 321.40 0.00e+00 4.946157e-02 1.372260e-02 7.541839e-04 -6.000000e+00 3.100189e-02 275.66 -2.00 20.00 -2.00 321.08 0.00e+00 9.802 0.017 302.00 328.00 3 1.0063e+00 1.1782e-01 1.1536e-01 -6.0000e+00 1.2672e+00 2.3125e+00 1.2793e-01 9.6832e-02 -6.0000e+00 1.3839e+00 -2.5861e+00 6.7673e-02 2.2063e-02 -6.0000e+00 8.3140e-01 1.0392e+00 4.0403e-02 3.9564e-02 -6.0000e+00 3.7795e-01 3.0283e-06 -6.1968e-03 1.6211e-03 6.2884e-04 -6.0000e+00 2.7240e-02 -6.8576e-02 1.5710e-04 12 8 8 10 0 0 99.75 19.55 0.83 -0.06858 -0.11514 19 5 1 5 0 2444.240 24.46 20.00 19.55 8.29 22.8 898.21 900000 900000 900000 265241 900000 -23415 219760 900000 900000 137908 900000 240222 900000 900000 16279 900000 900000 900000 119405 288456 900000 900000 37823 175426 900000 900000 900000 900000 900000 88873 26539 47191 900000 63070 900000 50117 900000 900000 900000 900000 900000 55427 -8388 -11453 18286 900000 900000 900000 900000 900000 -7070 60175 221256 46299 349641 291373 6895 -19451 77151 -28009 900000 141251 -22602 50228 -30401 24744 33353 -9552 -18284 44400 -32990 59902 -1922 18128 40199 900000 83500 8882 44985 -37341 46083 55179 816 25193 -7173 -27508 64625 11632 -18747 24100 -10889 26183 10826 -14076 -31588 -19256 -11433 7543 5116 -4460 12522 2712 2856 -5469 13532 8340 4059 6810 262 4515 1155 3007 -7293 -4321 1415 -4268 -5123 -3407 8392 3990 14695 18241 20515 10787 9721 -36969 8155 1227 9879 2460 3829 -50 960 -2670 -6622 -1605 1621 8450 -4078 4933 3225 -6250 900000 900000 900000 15589 900000 -12357 12133 900000 900000 7614 900000 13263 900000 900000 3511 900000 900000 900000 13611 15926 900000 900000 5187 9686 900000 900000 900000 900000 900000 4907 2442 4516 900000 6152 900000 4389 900000 900000 900000 900000 900000 4116 -1198 -1744 2124 900000 900000 900000 900000 900000 -1319 6072 12216 5641 19304 16087 1037 -3481 5020 -4853 900000 7799 -4863 6240 -8971 4240 5261 -2219 -4839 7179 -12059 9095 -501 3646 5707 900000 6318 1384 5588 -12583 8451 10663 289 7601 -2991 -14664 14782 4496 -9851 8316 -4830 7693 3522 -5995 -17561 -11438 -7640 4984 3974 -4016 9131 1947 1783 -3468 7631 5279 2736 4823 221 4230 1293 3670 -10303 -5899 1762 -5436 -6603 -4540 10593 5515 18129 20664 21482 12055 10660 -62853 8570 1423 12075 3835 6737 -100 2038 -6059 -16695 -4063 4054 20560 -10854 11984 7393 -14385 SS 20240108T131834.6Z 8773.554567 132 1 46.72 2 81.68 129.21 68.39 166.92 0.00 1 0.00 1 0 17 7.777e-01 8.396e-03 2.844e-01 3.351e-03 8.934869e-01 1.907650e-03 9.953296e-03 -6.000000e+00 4.456981e-01 223.53 -2.00 3.51 -2.00 321.81 0.00e+00 6.977504e-03 1.017497e-03 2.037354e-03 -6.000000e+00 2.037545e-02 275.66 -2.00 20.00 -2.00 321.42 0.00e+00 6.499 0.005 302.00 328.00 3 6.5390e-01 7.0196e-03 8.2654e-02 -6.0000e+00 1.1004e+00 2.6148e-01 1.1717e-02 5.7606e-02 -6.0000e+00 1.1921e+00 -3.1648e-01 1.3862e-02 3.1668e-02 -6.0000e+00 7.0939e-01 1.2366e-01 6.3017e-03 1.4678e-02 -6.0000e+00 3.1377e-01 1.7786e-04 -1.0608e-03 8.8338e-05 1.4714e-04 -6.0000e+00 2.1261e-02 -6.8678e-02 1.3015e-04 11 8 0 10 0 0 99.82 19.56 0.32 -0.06868 -0.07665 246 69 1 5 0 189.860 24.46 19.99 19.56 8.29 22.9 898.64 -316970 900000 -284562 -35696 -167874 -319646 -264861 -178473 -166956 -264478 900000 -206680 -129719 -164932 -105563 -144543 6337 -123653 -26590 -76238 -62227 -29601 -131847 -94434 -104629 -39656 -85079 288572 -89122 -28469 -49154 -21317 -4161 -21615 4705 -46196 4349 -16717 1641 -15515 7615 -17279 -3481 -4963 -1528 10549 -1393 9446 1801 22112 -2297 9393 8048 8747 4247 8647 1284 2689 4134 -745 11674 1890 7837 3865 7477 2158 7067 3517 2288 7085 1392 4779 1227 3593 -2231 3084 -3486 -922 -2764 -219 -325 -274 -899 -690 399 -155 1072 -465 703 394 1216 -421 -135 -730 -1477 406 9 456 -771 8 -1056 27 -545 -479 -1816 -1504 -1252 -681 -277 -122 21 -355 -12 -326 -60 170 427 495 218 -38 105 1124 768 865 -21 -1014 -59 868 153 295 90 271 16 -605 -164 -172 453 310 -281 -74 -73 -285 -2259 900000 -2028 -117 -548 -2942 -1494 -583 -545 -2042 900000 -1166 -508 -1175 -621 -1459 21 -1395 -139 -697 -508 -174 -2036 -1203 -1606 -337 -1167 943 -1310 -260 -706 -299 -60 -409 68 -1086 67 -377 38 -517 231 -739 -139 -209 -64 407 -64 417 94 1040 -158 660 644 699 382 783 129 266 389 -72 1121 203 928 558 1148 357 1129 617 457 1565 362 1259 330 881 -523 612 -697 -188 -666 -63 -113 -111 -411 -337 205 -85 610 -276 411 223 640 -213 -67 -386 -910 294 7 420 -801 9 -1060 24 -428 -400 -1498 -1313 -1153 -673 -306 -156 31 -569 -19 -533 -94 257 645 781 364 -60 177 1765 1152 1257 -30 -1408 -79 1211 249 520 179 586 38 -1517 -408 -451 1204 834 -756 -189 -188 -674 SS 20240108T132913.8Z 8773.561965 135 1 46.76 2 80.14 131.15 68.01 169.39 0.00 1 0.00 1 0 25 5.729e-01 6.201e-03 1.097e-01 1.575e-03 7.839274e-01 8.663654e-04 8.871133e-03 -6.000000e+00 3.283770e-01 223.53 -2.00 3.51 -2.00 321.35 0.00e+00 5.777379e-03 4.164413e-04 8.975772e-04 -6.000000e+00 1.418326e-02 275.66 -2.00 20.00 -2.00 320.95 0.00e+00 5.586 0.003 302.00 328.00 3 4.2960e-01 2.9185e-03 6.9796e-02 -6.0000e+00 8.1062e-01 1.3346e-01 4.4116e-03 4.4755e-02 -6.0000e+00 8.7791e-01 -1.3593e-01 5.0852e-03 2.6500e-02 -6.0000e+00 5.2215e-01 4.7124e-02 2.4067e-03 1.2612e-02 -6.0000e+00 2.2909e-01 5.8707e-04 -6.0437e-04 4.1666e-05 1.2389e-04 -6.0000e+00 1.5542e-02 -6.9692e-02 1.7706e-04 10 0 0 10 0 0 60.48 19.56 0.24 -0.06969 -0.07423 467 132 1 5 0 100.110 24.46 20.01 19.56 8.84 22.8 902.88 -185111 -178589 -208266 -173512 -155207 -230764 -190003 -105099 -177240 -155499 -165029 -134102 -142680 -65848 -95986 -69689 -59291 -62988 -43072 -48433 -23906 -61806 -68674 -68933 -43027 -50234 -45590 -27872 -44924 -35748 -39941 -8743 -18314 -12500 -17570 -10749 -16249 -7701 -3821 -3169 881 -3654 627 -5797 3664 19 4806 -566 5689 3654 3252 5674 4901 5381 3801 5251 -417 1531 -1157 772 1107 2708 3145 4655 3048 2723 3056 1571 2714 1943 1749 1167 1205 2 204 49 -1908 -859 -1021 -8 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