File name: Pandora135s1_ManhattanNY-CCNY_20240209_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240210T051610.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240209_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240209T134343.7Z 8805.572034 92 1 41.68 2 73.21 127.69 76.69 134.55 0.00 1 0.00 1 0 17 1.431e-01 5.983e-03 7.525e-02 2.609e-03 5.150634e-01 1.357914e-03 6.082691e-03 -6.000000e+00 8.231564e-02 224.67 -2.00 3.51 -2.00 319.80 0.00e+00 2.758986e-03 4.090855e-04 4.351805e-04 -6.000000e+00 3.537620e-03 275.14 -2.00 20.00 -2.00 319.31 0.00e+00 3.408 0.001 302.00 328.00 3 3.8917e+00 3.8328e-03 4.3078e-02 -6.0000e+00 2.0374e-01 5.3506e-02 4.6206e-03 2.6779e-02 -6.0000e+00 2.2059e-01 -1.9633e-02 4.2155e-03 1.4288e-02 -6.0000e+00 1.3104e-01 -5.9477e-04 2.2255e-03 5.3053e-03 -6.0000e+00 5.7258e-02 1.8997e-04 -9.8833e-04 7.2833e-05 5.1950e-05 -6.0000e+00 3.8862e-03 -6.3758e-02 8.8842e-05 12 1 1 12 1 1 99.27 19.97 0.18 -0.06376 -0.07118 34 11 1 5 0 1190.380 24.75 20.00 19.97 12.70 23.5 931.84 -7221 -8522 -23649 -37659 90435 -109627 -37134 -23467 -24461 -26951 -10515 -25978 -4184 2098 -25710 -828 4797 -3216 -618 -1916 8410 -4902 -7199 -9194 -1670 -7565 -2882 338 -4926 -8226 -6848 481 4393 -1688 -4200 -2053 -2622 4321 1829 1223 -199 -2702 -2107 -2106 984 -796 1032 71 2445 2263 1129 1013 1936 1212 1332 1239 -725 177 -97 -84 1853 3180 1557 2419 453 147 -360 -568 1478 315 724 217 66 -365 -93 119 -786 -1146 -909 -630 -1074 -883 -2166 -1097 -762 -527 116 -118 269 1072 496 112 366 354 289 240 473 92 319 -290 -626 -791 6 -456 -932 -592 -884 -120 -123 416 52 551 264 242 23 223 362 148 234 -329 160 269 400 597 248 -1207 83 341 215 206 -201 187 -291 -382 -329 -89 415 285 -180 1 31 -302 -69 -97 -334 -597 383 -3031 -554 -347 -413 -502 -173 -547 -86 51 -973 -29 176 -139 -28 -93 379 -253 -392 -549 -100 -506 -186 21 -308 -555 -520 40 398 -173 -427 -201 -279 508 269 215 -38 -571 -464 -475 218 -183 236 17 573 557 306 305 628 426 492 456 -279 67 -37 -32 715 1320 708 1208 240 76 -178 -283 787 186 471 149 45 -238 -56 66 -406 -586 -504 -390 -773 -690 -1866 -989 -703 -518 120 -121 284 1087 472 102 313 304 271 247 535 115 429 -393 -799 -943 6 -519 -1109 -744 -1131 -161 -178 638 84 933 445 389 36 326 527 225 378 -544 264 431 637 915 366 -1785 116 484 326 337 -357 337 -546 -733 -653 -186 882 616 -391 1 64 -588 SS 20240209T143714.5Z 8805.609196 127 1 10.60 2 65.83 139.05 70.23 145.22 0.00 1 0.00 1 0 25 5.234e-02 8.047e-03 2.577e-02 3.942e-03 3.743936e-01 2.003775e-03 4.532496e-03 -6.000000e+00 3.009443e-02 224.67 -2.00 3.51 -2.00 318.45 0.00e+00 1.701732e-03 3.945167e-04 2.611456e-04 -6.000000e+00 1.293557e-03 275.14 -2.00 20.00 -2.00 317.92 0.00e+00 2.425 0.000 302.00 328.00 3 4.5124e+00 5.3637e-03 3.0840e-02 -6.0000e+00 7.4485e-02 4.3543e-02 6.0823e-03 1.9179e-02 -6.0000e+00 8.0651e-02 -2.4261e-02 4.2671e-03 9.7507e-03 -6.0000e+00 4.7911e-02 8.5717e-03 2.2865e-03 3.1591e-03 -6.0000e+00 2.0931e-02 3.1510e-04 -9.3762e-04 1.1147e-04 3.2252e-05 -6.0000e+00 1.4211e-03 -6.3054e-02 6.7780e-05 12 9 1 12 1 1 99.71 20.03 0.25 -0.06305 -0.07010 8 11 1 5 0 1177.120 24.86 20.00 20.03 13.60 23.6 938.51 -10581 3075 -16605 -5113 2785 -35867 -5118 -17906 8844 -17206 1239 -11923 1988 1418 -4989 5254 4381 4415 -2359 5510 3582 4044 -27794 4095 888 1327 -811 494 2279 -4486 97 -1059 6734 -3692 -276 -2732 -330 1491 755 403 -328 -420 -779 1374 -858 2304 -997 1588 858 1776 -103 1776 1622 419 414 965 191 -417 866 -74 1916 1529 1161 1442 397 299 -188 96 770 1142 -247 676 515 -215 -471 526 -931 -1338 -56 -1630 -740 -1732 -1748 -1966 -1041 -844 309 -4 -152 723 515 278 -340 31 -362 417 -148 744 278 -417 -330 -948 -26 -505 -474 -1087 18 -664 158 366 397 -59 235 656 -103 237 159 981 117 211 -285 235 357 739 264 -603 268 631 474 10 236 -194 50 -523 -114 -7 252 178 -456 33 -323 -405 -495 141 -968 -254 116 -2085 -230 -1032 436 -1166 71 -817 137 118 -502 540 490 523 -315 709 481 538 -5183 589 141 218 -137 78 353 -747 16 -200 1307 -830 -57 -565 -72 374 222 139 -127 -165 -319 560 -359 977 -419 670 365 764 -46 854 837 224 230 548 112 -244 490 -41 1089 942 792 1027 291 207 -127 64 527 885 -207 585 445 -179 -378 376 -634 -881 -39 -1257 -624 -1591 -1732 -1990 -1111 -933 357 -5 -182 829 568 291 -330 30 -369 456 -178 960 376 -567 -432 -1168 -30 -606 -596 -1417 24 -921 230 562 634 -98 378 1016 -153 339 227 1400 174 334 -448 371 545 1112 381 -859 360 851 692 15 381 -316 83 -892 -206 -14 477 343 -867 63 -585 -717 SS 20240209T144200.6Z 8805.612507 130 1 13.26 2 65.25 140.14 69.72 146.24 0.00 1 0.00 1 0 17 3.181e-02 6.186e-03 9.516e-03 1.713e-03 3.686913e-01 8.699900e-04 4.460182e-03 -6.000000e+00 1.829628e-02 224.67 -2.00 3.51 -2.00 318.11 0.00e+00 9.549961e-04 1.550104e-04 1.870741e-04 -6.000000e+00 7.861771e-04 275.14 -2.00 20.00 -2.00 317.56 0.00e+00 2.372 0.000 302.00 328.00 3 3.3788e+00 2.3090e-03 3.0210e-02 -6.0000e+00 4.5285e-02 3.7155e-02 2.6051e-03 1.8812e-02 -6.0000e+00 4.9029e-02 -1.5434e-02 1.7613e-03 9.4893e-03 -6.0000e+00 2.9126e-02 2.6224e-03 9.3747e-04 2.8790e-03 -6.0000e+00 1.2728e-02 1.0425e-03 -6.6323e-04 4.8163e-05 2.9802e-05 -6.0000e+00 8.6360e-04 -6.3795e-02 1.2089e-04 12 1 1 12 1 1 97.69 20.03 0.19 -0.06379 -0.06878 29 30 1 5 0 441.850 24.86 20.00 20.03 13.72 23.5 939.66 -1352 -8307 -3654 -12046 -2813 -15773 -8246 -168 -5313 -3923 -9658 -3770 -7133 -601 -5005 138 -2170 -226 -588 -696 771 -2089 22069 -2562 1040 -1282 -517 -2898 -1134 -1452 126 1688 1374 -1078 -2779 -128 -2421 -382 322 -5 -1526 -964 -447 -956 657 83 301 -532 -237 -219 934 931 1504 978 1226 801 165 818 192 1323 417 1840 1422 1583 -91 170 -340 190 985 405 753 31 334 -171 297 -186 -377 -862 -646 -826 -1074 -945 -2335 -1044 -1321 -762 -376 28 -8 447 346 231 807 412 510 90 574 121 -13 -479 -317 -678 -16 -530 -764 -680 -934 -152 130 462 171 347 7 201 96 447 301 334 334 -113 20 200 532 91 383 -278 176 813 355 222 -190 243 -216 -76 -187 209 272 -37 -290 -133 -299 -491 -68 -502 -219 -752 -152 -881 -473 -10 -359 -278 -733 -284 -639 -60 -616 18 -302 -33 -90 -111 124 -345 3055 -462 193 -255 -102 -561 -205 -275 24 361 326 -274 -685 -30 -625 -109 110 -2 -665 -426 -203 -444 301 39 138 -244 -112 -102 459 498 825 572 745 503 106 523 121 812 265 1199 1026 1192 -71 125 -243 133 735 322 657 27 296 -151 242 -142 -270 -596 -472 -664 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