File name: Pandora135s1_ManhattanNY-CCNY_20240212_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T193752.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240212_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240212 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240212T130552.5Z 8808.545747 73 1 39.02 2 78.43 119.83 96.37 87.36 0.00 1 0.00 1 0 17 3.861e-01 1.492e-02 2.453e-01 5.581e-03 7.164833e-01 3.040328e-03 8.156656e-03 -6.000000e+00 2.194760e-01 224.77 -2.00 3.51 -2.00 321.18 0.00e+00 8.550666e-03 1.379301e-03 1.438808e-03 -6.000000e+00 1.142121e-02 275.14 -2.00 20.00 -2.00 320.71 0.00e+00 4.824 0.002 302.00 328.00 3 3.4573e+00 9.8196e-03 6.0896e-02 -6.0000e+00 5.4460e-01 2.1546e-01 1.3750e-02 3.8468e-02 -6.0000e+00 5.9411e-01 -2.2458e-01 1.5030e-02 2.3999e-02 -6.0000e+00 3.5148e-01 9.0096e-02 7.2398e-03 1.2767e-02 -6.0000e+00 1.5258e-01 5.9686e-05 -1.1814e-03 1.5369e-04 1.3455e-04 -6.0000e+00 1.0780e-02 -1.7828e-02 0.0000e+00 12 9 9 12 1 1 83.40 19.55 0.23 -0.01783 -0.02671 22 8 1 5 0 1696.300 24.46 20.01 19.55 8.09 23.0 900.02 81358 900000 900000 39942 900000 -305720 -137594 53563 900000 -129113 900000 900000 900000 900000 -101394 44867 34458 27906 19814 17059 -9660 48515 -69140 -17368 -4800 29027 -25035 69635 8509 -37793 17530 -7424 120425 11949 16699 33902 6275 28860 10973 14872 11125 -2836 3370 4712 12826 18351 14634 11221 22609 20880 -84 11270 7956 6106 7241 9038 302 -3262 2267 -2571 12366 6228 638 1046 3158 1974 4261 481 -88 1792 -972 3205 745 -634 1761 5625 -1503 -784 -1668 -1708 -1445 438 -1402 -946 -1330 -2606 644 -78 217 678 145 670 -1138 -191 -1534 -1203 -581 1301 -156 -551 -744 -271 -286 -1032 -1086 -1524 -1593 -531 -107 744 154 382 -598 -361 134 -412 -298 940 897 -240 1009 1310 913 1690 506 -2841 419 244 846 67 571 168 -36 -111 -634 -285 529 196 -694 427 229 -453 -580 442 900000 900000 217 900000 -12351 -1148 291 900000 -1278 900000 900000 900000 900000 -2126 280 277 270 227 213 -156 449 -2040 -324 -87 391 -569 631 144 -1078 363 -236 1359 404 525 908 229 986 545 846 743 -228 270 388 1033 1446 1241 997 1966 1990 -11 1432 1154 981 1219 1550 58 -644 411 -480 2049 1210 151 272 866 546 1135 137 -28 638 -394 1305 308 -250 617 1697 -468 -246 -573 -702 -702 232 -837 -598 -895 -1889 476 -58 160 498 100 430 -712 -122 -1112 -1016 -552 1356 -183 -657 -837 -280 -265 -949 -1065 -1594 -1754 -619 -133 1000 233 600 -962 -563 204 -601 -432 1405 1419 -387 1643 2036 1362 2419 727 -4064 558 336 1271 113 1060 326 -74 -235 -1440 -663 1246 469 -1670 1007 506 -963 -1179 SS 20240212T131057.1Z 8808.549272 76 1 25.12 2 77.60 120.76 95.43 88.14 0.00 1 0.00 1 0 17 3.455e-01 9.819e-03 2.297e-01 4.305e-03 6.853301e-01 2.265756e-03 7.738612e-03 -6.000000e+00 1.956672e-01 224.77 -2.00 3.51 -2.00 320.91 0.00e+00 5.282633e-03 9.613877e-04 8.328979e-04 -6.000000e+00 8.632805e-03 275.14 -2.00 20.00 -2.00 320.44 0.00e+00 4.525 0.002 302.00 328.00 3 3.0004e+00 7.0724e-03 5.7411e-02 -6.0000e+00 4.8380e-01 1.5473e-01 9.5242e-03 3.6362e-02 -6.0000e+00 5.2698e-01 -1.4507e-01 1.0119e-02 2.0635e-02 -6.0000e+00 3.1306e-01 5.3758e-02 4.9823e-03 9.2172e-03 -6.0000e+00 1.3312e-01 1.3169e-04 -9.2435e-04 1.1578e-04 9.6235e-05 -6.0000e+00 9.4679e-03 -1.7874e-02 0.0000e+00 12 9 9 12 1 1 30.40 19.55 0.24 -0.01787 -0.02482 27 15 1 5 0 896.860 24.46 20.00 19.55 8.17 23.0 900.53 -93041 -62785 -35563 -89496 900000 -215369 -113850 -129468 3790 -144339 -76946 -45085 -48333 56054 -81191 56780 -2674 -1135 -28269 -16765 -13847 -36423 -114658 -31099 6416 -18677 -5955 17341 8482 -17689 489 -13656 13665 -3399 -7760 -5663 316 11008 280 7165 -581 94 -2815 -685 1114 6583 4500 2747 13839 5719 1008 8051 5615 3644 5216 4162 937 2660 590 2333 3566 3054 1168 3979 879 933 2101 788 753 1481 80 1857 1285 -21 -137 771 -701 -689 -1548 -953 -1227 -994 -1817 -518 -866 -738 337 695 -1062 681 354 279 -769 -317 -583 -460 -231 104 192 -509 168 -846 157 -1313 -1131 -553 -660 -816 -204 796 147 121 -162 -47 260 -138 157 185 351 -179 295 1038 1336 288 0 -1615 106 1081 369 439 -300 652 -23 -192 -604 -306 353 238 -361 370 -134 -482 -133 -502 -301 -149 -608 900000 -4397 -933 -1398 16 -2193 -631 -306 -435 247 -1658 393 -37 -17 -616 -345 -285 -939 -6366 -845 130 -511 -146 333 178 -523 14 -571 511 -164 -382 -267 15 561 19 532 -53 9 -301 -74 121 695 500 323 1537 740 152 1273 1005 724 1084 871 208 580 133 507 787 745 318 1195 292 307 671 262 275 619 36 861 594 -9 -58 288 -247 -244 -618 -450 -657 -609 -1239 -370 -634 -574 274 579 -898 547 266 204 -544 -228 -451 -413 -232 120 233 -632 203 -921 159 -1333 -1223 -607 -763 -1008 -264 1148 229 201 -274 -77 400 -210 238 283 566 -303 493 1649 2026 443 -1 -2340 146 1510 584 762 -559 1285 -46 -410 -1342 -714 836 555 -845 855 -292 -1016 -268 SS 20240212T131620.3Z 8808.553013 79 1 46.87 2 76.72 121.76 94.43 88.98 0.00 1 0.00 1 0 17 2.991e-01 5.645e-03 4.746e-02 1.280e-03 6.506188e-01 6.660901e-04 7.380329e-03 -6.000000e+00 1.692317e-01 224.77 -2.00 3.51 -2.00 320.63 0.00e+00 4.113562e-03 2.598391e-04 5.839919e-04 -6.000000e+00 7.346574e-03 275.14 -2.00 20.00 -2.00 320.14 0.00e+00 4.248 0.001 302.00 328.00 3 1.7365e+00 2.0137e-03 5.3979e-02 -6.0000e+00 4.1868e-01 9.2483e-02 2.6306e-03 3.4121e-02 -6.0000e+00 4.5599e-01 -6.8581e-02 2.7143e-03 1.8721e-02 -6.0000e+00 2.7108e-01 1.8288e-02 1.3592e-03 7.8055e-03 -6.0000e+00 1.1518e-01 6.3891e-04 -8.0462e-04 3.4644e-05 7.9748e-05 -6.0000e+00 8.1113e-03 -1.7910e-02 0.0000e+00 10 0 0 10 0 0 90.64 19.55 0.21 -0.01791 -0.02396 230 65 1 5 0 203.760 24.46 20.01 19.55 8.27 23.0 901.26 -96606 -76534 -104320 -71879 -94073 -126117 -136460 -58912 -108987 -89127 -84344 -73833 -58265 -39646 -33070 -31902 -5267 -26903 -8222 -23524 -3230 -19746 -11389 -19247 -14467 -15448 -17260 -6425 -22376 -8646 -15449 1020 -2407 -1122 -8380 -6183 -3938 -1214 1080 -1154 1088 -3307 900 -1907 768 308 1530 1108 2231 3032 661 4226 2279 3725 1961 2884 223 360 -517 533 1755 1771 2843 2663 2128 520 1055 -113 1527 965 1081 361 -75 211 -435 -76 -1915 -876 -1330 -431 -671 -862 -1842 -1442 -834 -804 -105 -56 482 413 938 99 412 126 64 177 198 436 100 -235 -644 -679 -153 -21 -1080 -802 -811 -386 -11 207 181 245 182 61 65 245 386 369 195 -160 -111 355 353 478 119 -334 19 805 34 -8 -99 98 -199 -345 -272 -109 307 261 -155 -83 8 -93 -118 -663 -516 -1016 -502 -763 -1370 -1755 -397 -1374 -1001 -958 -857 -735 -544 -545 -633 -92 -652 -181 -640 -74 -537 -296 -586 -457 -523 -608 -200 -813 -295 -669 46 -130 -65 -512 -363 -245 -87 85 -111 116 -401 111 -249 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