File name: Pandora135s1_ManhattanNY-CCNY_20240216_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T193828.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240216_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240216T122021.8Z 8812.514142 80 1 46.30 2 85.22 110.92 113.76 24.42 0.00 1 0.00 1 0 25 9.057e-01 5.346e-02 4.637e-01 3.056e-02 1.247820e+00 2.097733e-02 1.366449e-02 -6.000000e+00 5.781012e-01 224.94 -2.00 3.51 -2.00 322.74 0.00e+00 1.974752e-02 1.266566e-02 4.130022e-03 -6.000000e+00 3.740982e-02 275.26 -2.00 20.00 -2.00 322.41 0.00e+00 10.166 0.019 302.00 328.00 3 -2.9255e-01 8.5185e-02 1.2884e-01 -6.0000e+00 1.4254e+00 2.7865e+00 9.2667e-02 8.7172e-02 -6.0000e+00 1.5643e+00 -3.2916e+00 5.3745e-02 3.2443e-02 -6.0000e+00 9.4359e-01 1.2690e+00 3.3075e-02 1.8059e-02 -6.0000e+00 4.1852e-01 5.9497e-06 -2.3413e-03 8.7508e-04 2.5214e-04 -6.0000e+00 3.0693e-02 -1.9084e-02 0.0000e+00 12 8 8 10 0 0 92.37 19.50 0.91 -0.01908 -0.03668 37 10 1 5 0 1251.140 24.46 20.00 19.50 7.15 23.0 893.51 548269 900000 900000 900000 900000 -31652 253595 900000 900000 78935 900000 900000 900000 900000 247640 900000 900000 900000 207719 900000 317967 900000 -64462 138906 900000 57896 900000 900000 900000 1120 89882 900000 900000 123147 165851 900000 900000 900000 900000 900000 900000 233175 130173 82924 900000 900000 900000 900000 900000 900000 5773 900000 107409 95835 91865 900000 8634 42020 80069 39207 900000 900000 28079 59077 6705 7184 41506 2197 13044 43948 -11358 45935 24656 69855 29333 900000 20415 56066 3352 5682 8807 69689 -12918 39094 6007 7797 46661 7343 -1350 2804 -10008 3361 705 -16152 -8498 3068 -14597 14659 -7526 -6888 880 5715 -1628 -6915 5041 -8257 -6004 -2754 444 1102 839 -1021 -3918 -4223 2909 -2745 -3187 -4354 5427 1310 9037 6145 5822 12429 474 -20002 -2950 3259 3793 3337 3144 3478 -673 -3597 -2206 263 1173 1904 -1160 1325 4051 -3688 -3025 16185 900000 900000 900000 900000 -6167 7486 900000 900000 2453 900000 900000 900000 900000 7310 900000 900000 900000 6132 900000 9386 900000 -9515 4101 900000 1804 900000 900000 900000 50 2653 900000 900000 3635 4896 900000 900000 900000 900000 900000 900000 6883 3843 2448 900000 900000 900000 900000 900000 900000 407 900000 3357 3495 3510 900000 666 2262 2642 1770 900000 900000 1707 3078 652 711 2955 244 1427 3968 -1913 4387 2740 4367 2343 900000 1418 2921 355 740 1361 6898 -3275 6246 1387 1828 7616 1798 -354 672 -2537 706 153 -4572 -2686 1076 -7110 6797 -4715 -4474 530 2868 -752 -3146 2118 -4201 -3169 -1549 281 838 725 -1028 -4363 -4835 3073 -3025 -3586 -5220 6222 1596 9738 6279 5914 11503 485 -23225 -3012 3384 4498 4892 5429 6742 -1491 -8978 -5876 721 3222 5189 -3210 3378 9075 -7959 -5998 SS 20240216T123143.0Z 8812.522025 83 1 46.74 2 83.23 112.85 112.84 26.97 0.00 1 0.00 1 0 17 8.773e-01 1.440e-02 3.709e-01 5.795e-03 1.094880e+00 3.453686e-03 1.138987e-02 -6.000000e+00 5.073484e-01 224.94 -2.00 3.51 -2.00 322.44 0.00e+00 6.663585e-03 2.077106e-03 7.336774e-03 -6.000000e+00 2.494218e-02 275.26 -2.00 20.00 -2.00 322.05 0.00e+00 7.745 0.008 302.00 328.00 3 1.0045e-01 1.3792e-02 1.1044e-01 -6.0000e+00 1.2657e+00 7.6071e-01 2.5245e-02 9.8983e-02 -6.0000e+00 1.3850e+00 -9.3332e-01 2.9676e-02 4.6407e-02 -6.0000e+00 8.1343e-01 3.6589e-01 1.2890e-02 1.4266e-02 -6.0000e+00 3.4566e-01 7.3966e-05 -1.2085e-03 1.4977e-04 1.6617e-04 -6.0000e+00 2.5184e-02 -1.9994e-02 0.0000e+00 12 8 8 10 0 0 15.42 19.48 0.38 -0.01999 -0.02907 173 49 1 5 0 270.130 24.35 20.00 19.48 7.72 23.0 897.35 -329641 900000 -318081 900000 -235293 -359603 -250948 900000 900000 -286071 900000 -277779 900000 -249891 900000 -125296 900000 -79560 67630 71065 1098 900000 -210416 116852 -132742 -43113 -124993 900000 -74023 211088 -45128 -11671 900000 -45310 35662 -72639 184357 -23182 46930 -27531 142113 3968 26067 25588 42478 82363 4034 73090 22180 87123 3256 56329 9770 56630 37013 48326 17293 9319 23715 -15736 45637 3371 21064 9480 16776 5671 18881 15774 12144 19252 8644 21263 4632 14052 1906 13077 -10967 -3123 -2693 2324 5045 1201 975 1418 2667 -1269 5090 392 2705 1039 2369 1281 -1548 -380 -2605 -695 -2501 -315 -1486 -691 -1182 -425 -806 -1147 -810 -1707 -814 -1872 153 -1051 -463 -502 -557 -1066 -428 -539 -352 347 422 105 565 2074 960 1861 -34 -1288 456 956 716 257 608 360 238 -849 -286 -71 898 437 -266 378 -302 -476 -1104 -3042 900000 -3424 900000 -1327 -4793 -1415 900000 900000 -2346 900000 -2706 900000 -3587 900000 -899 900000 -489 381 401 6 900000 -5285 659 -1769 -267 -1762 900000 -626 1190 -433 -105 900000 -766 261 -1516 1040 -366 450 -668 801 87 485 491 695 929 105 1030 575 1326 132 1556 485 1948 1670 2044 1024 589 1230 -1154 1827 228 1413 850 1570 617 1863 1734 1568 2448 1356 3063 769 1952 265 1578 -1595 -449 -459 428 1107 324 299 465 915 -477 1873 155 1036 389 821 427 -533 -141 -1170 -374 -1659 -243 -1310 -625 -1014 -319 -529 -722 -535 -1208 -604 -1533 140 -1155 -544 -661 -774 -1500 -584 -718 -472 483 618 157 812 2730 1205 2453 -44 -1660 565 1259 1030 447 1214 798 574 -2069 -748 -196 2489 1224 -741 995 -792 -1133 -2492 SS 20240216T124230.0Z 8812.529514 86 1 46.80 2 81.36 114.72 111.89 29.34 0.00 1 0.00 1 0 25 7.638e-01 8.900e-03 1.843e-01 2.136e-03 9.425762e-01 1.205046e-03 1.004610e-02 -6.000000e+00 4.381491e-01 224.94 -2.00 3.51 -2.00 321.93 0.00e+00 8.315361e-03 6.570500e-04 2.046327e-03 -6.000000e+00 1.957737e-02 275.26 -2.00 20.00 -2.00 321.52 0.00e+00 6.282 0.004 302.00 328.00 3 9.9464e-02 4.3770e-03 8.2640e-02 -6.0000e+00 1.0862e+00 3.3349e-01 7.4237e-03 6.0564e-02 -6.0000e+00 1.1844e+00 -3.7349e-01 8.8370e-03 3.1843e-02 -6.0000e+00 6.9797e-01 1.4542e-01 3.9873e-03 1.4836e-02 -6.0000e+00 2.9688e-01 3.4988e-04 -9.6468e-04 5.4885e-05 1.5271e-04 -6.0000e+00 2.1232e-02 -2.0582e-02 0.0000e+00 11 8 0 10 0 0 31.38 19.48 0.24 -0.02058 -0.02783 406 115 1 5 0 115.240 24.35 20.00 19.48 8.18 22.9 900.58 -318154 900000 -281498 -247886 900000 -350782 900000 -262195 900000 -295097 -62671 -269908 -80650 -188545 -132580 -115671 -91219 -49809 -112057 -6441 -87274 17748 -151612 -54627 -96732 -69482 -74891 -44036 -42945 -86036 -38168 -54884 30061 -39013 -10796 -41186 -2630 -20638 -7883 -1281 -5741 6985 -11923 7339 -6894 11901 -8220 14643 3954 12252 6481 7832 14997 7164 11273 7266 10315 1740 7348 -1492 7113 4077 5125 7928 4116 7091 2988 6085 2113 6966 3168 5449 1903 2360 -534 -530 -1835 -4073 -204 -1431 2175 -833 96 -856 -257 -446 438 285 -349 1516 -329 430 -738 442 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