File name: Pandora135s1_ManhattanNY-CCNY_20240413_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240414T045957.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240413_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240413 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240413T131458.8Z 8869.552070 154 1 46.85 2 57.92 106.75 92.28 49.47 0.00 1 0.00 1 0 17 1.235e-02 5.326e-03 1.590e-03 4.379e-04 3.221611e-01 2.248864e-04 3.898617e-03 -6.000000e+00 7.206873e-03 228.51 -2.00 3.51 -2.00 317.39 0.00e+00 4.673423e-04 3.323230e-05 1.332388e-04 -6.000000e+00 3.117409e-04 280.15 -2.00 20.00 -2.00 316.75 0.00e+00 1.876 0.000 302.00 328.00 3 2.5198e+00 5.9308e-04 2.5266e-02 -6.0000e+00 1.7965e-02 2.2278e-02 6.6315e-04 1.6662e-02 -6.0000e+00 1.9385e-02 -3.9112e-03 4.1071e-04 8.2433e-03 -6.0000e+00 1.1516e-02 9.1143e-04 2.1043e-04 2.3563e-03 -6.0000e+00 5.0095e-03 4.1936e-03 -4.6225e-04 1.2273e-05 2.5367e-05 -6.0000e+00 3.3587e-04 -5.9124e-02 1.2385e-04 10 0 0 10 0 0 99.63 20.20 0.21 -0.05912 -0.06260 336 95 1 5 0 139.390 24.96 20.01 20.20 15.52 24.0 957.00 -1700 -2086 -2261 -4760 -4569 -6252 -3078 -1830 -1984 -3592 -3731 -2928 -1589 123 -505 -113 -206 371 446 842 367 623 -1667 727 248 59 -223 -1096 -411 41 667 1438 698 -1136 -1830 -1676 -1382 -301 99 -522 -907 -523 -602 -281 79 52 -275 -422 -338 378 795 804 1210 922 951 931 589 518 578 838 1023 1564 1545 1278 67 19 -323 253 774 478 271 96 22 -125 -59 -176 -514 -663 -439 -719 -992 -1338 -1849 -1402 -974 -747 -527 -272 -23 252 318 142 509 747 467 366 423 386 60 -289 -469 -697 -29 -178 -763 -727 -694 -467 13 337 199 296 175 236 70 521 355 349 168 -93 -167 116 210 404 550 8 514 844 496 244 54 233 -123 -181 -259 -47 161 111 -328 -190 -400 -511 -147 -201 -225 -460 -397 -527 -266 -177 -215 -417 -436 -353 -215 19 -92 -23 -44 83 96 187 84 141 -394 178 65 16 -61 -287 -101 11 172 407 218 -374 -575 -513 -457 -116 42 -262 -468 -283 -336 -158 45 30 -153 -231 -183 207 459 502 802 604 646 649 420 368 402 575 721 1179 1275 1065 57 15 -256 195 636 419 246 91 20 -114 -53 -143 -403 -497 -346 -603 -945 -1335 -1989 -1490 -1100 -853 -635 -337 -29 300 371 151 525 749 499 411 502 509 81 -387 -619 -840 -35 -217 -959 -969 -919 -646 18 500 314 454 274 345 99 725 491 478 246 -138 -255 174 303 588 760 12 677 1111 704 358 80 354 -191 -294 -426 -82 274 192 -572 -323 -683 -833 SS 20240413T132309.0Z 8869.557743 160 1 46.85 2 56.44 108.38 91.14 50.76 0.00 1 0.00 1 0 17 1.340e-02 5.228e-03 3.410e-03 9.123e-04 3.110230e-01 4.692248e-04 3.771313e-03 -6.000000e+00 7.814874e-03 228.51 -2.00 3.51 -2.00 317.48 0.00e+00 3.294383e-04 7.045418e-05 1.263155e-04 -6.000000e+00 3.380304e-04 280.15 -2.00 20.00 -2.00 316.83 0.00e+00 1.803 0.000 302.00 328.00 3 3.9526e+00 1.2393e-03 2.4355e-02 -6.0000e+00 1.9481e-02 2.6498e-02 1.3869e-03 1.6118e-02 -6.0000e+00 2.1020e-02 1.3757e-03 8.6475e-04 7.9750e-03 -6.0000e+00 1.2487e-02 -2.3239e-03 4.4373e-04 2.2715e-03 -6.0000e+00 5.4322e-03 1.0898e-03 -4.0220e-04 2.5768e-05 2.4666e-05 -6.0000e+00 3.6419e-04 -5.9152e-02 1.3263e-04 10 0 0 10 0 0 99.23 20.20 0.17 -0.05915 -0.06217 120 34 1 5 0 390.320 24.96 19.99 20.20 15.69 24.0 958.10 -1926 -2182 -3489 -3384 -2867 -8085 -3730 -755 -1713 -3203 -3612 -1940 -1114 322 -913 -391 -24 110 163 873 250 -322 5977 -414 630 -4 -362 -393 -984 -264 447 1178 812 -1386 -2501 -1296 -1409 -122 -258 -417 -806 -1058 -802 -639 51 -153 -337 -640 -261 339 551 719 1186 868 749 1149 569 479 561 875 1237 1823 1495 1146 89 -72 -395 148 935 386 155 15 175 -124 -52 -152 -661 -722 -419 -572 -1032 -1353 -1818 -1045 -910 -642 -421 -6 -19 273 304 167 477 427 504 357 479 284 34 -212 -434 -695 -21 -55 -819 -614 -756 -437 10 396 177 337 184 212 151 331 291 281 208 -246 -167 104 170 533 474 -160 409 750 393 222 88 247 -134 -286 -225 -1 208 114 -232 -87 -366 -533 -164 -207 -344 -315 -239 -678 -317 -71 -181 -362 -411 -225 -145 46 -153 -73 -5 22 35 193 57 -73 1302 -102 157 -1 -99 -101 -240 -63 114 327 237 -427 -739 -385 -434 -44 -107 -195 -416 -577 -449 -361 29 -86 -187 -350 -140 184 315 427 747 579 518 782 397 334 396 609 851 1341 1164 959 75 -57 -303 111 742 337 144 14 164 -115 -47 -122 -501 -541 -317 -474 -939 -1324 -1915 -1112 -1031 -753 -506 -8 -23 333 355 178 480 432 523 399 579 370 46 -286 -564 -851 -24 -66 -1050 -807 -1012 -610 14 587 279 526 287 317 214 451 394 386 305 -375 -253 158 251 776 656 -218 543 994 544 324 132 382 -211 -459 -372 -2 361 202 -414 -152 -628 -876 SS 20240413T133053.8Z 8869.563123 166 1 3.09 2 55.05 109.97 90.04 51.97 0.00 1 0.00 1 0 17 1.027e-02 5.589e-03 5.768e-03 1.926e-03 3.000669e-01 9.948450e-04 3.654542e-03 -6.000000e+00 5.991832e-03 228.51 -2.00 3.51 -2.00 317.00 0.00e+00 2.472700e-04 1.316218e-04 1.380513e-04 -6.000000e+00 2.591773e-04 280.15 -2.00 20.00 -2.00 316.36 0.00e+00 1.741 0.000 302.00 328.00 3 2.8824e+00 2.6096e-03 2.3489e-02 -6.0000e+00 1.4936e-02 2.3646e-02 2.9091e-03 1.5515e-02 -6.0000e+00 1.6117e-02 -3.6824e-03 1.7567e-03 7.6671e-03 -6.0000e+00 9.5740e-03 4.9109e-04 8.7861e-04 2.1766e-03 -6.0000e+00 4.1651e-03 3.4501e-03 -4.0822e-04 5.4143e-05 2.4354e-05 -6.0000e+00 2.7924e-04 -5.9654e-02 1.1366e-04 12 1 1 12 1 1 90.95 20.21 0.17 -0.05965 -0.06272 15 69 1 5 0 192.750 24.96 20.00 20.21 15.77 24.0 958.77 -1484 -90 -2764 -3778 -2584 -4250 -2082 955 -312 -3653 -3237 -2092 -1259 -150 -776 412 -395 -721 955 195 706 558 -231 502 870 601 -655 -1544 -446 154 1239 1554 648 -1206 -1186 -1075 -705 -418 -469 -615 -781 -509 -581 -319 -285 -267 -170 -686 -600 181 359 1227 1067 942 870 1139 730 487 682 797 1286 1795 1711 1200 -215 122 -405 -58 1203 488 92 183 -22 -152 144 -90 -525 -601 -179 -899 -1149 -1491 -1869 -1336 -916 -852 -489 -237 -36 160 96 -194 508 441 485 357 610 478 187 -399 -436 -580 60 -226 -1004 -633 -677 -264 -42 309 82 440 270 -37 253 388 263 391 233 -246 -5 320 456 493 524 -32 571 541 469 200 235 246 -68 -338 -245 -138 129 121 -252 -223 -472 -478 -165 -11 -353 -461 -280 -446 -226 114 -42 -536 -473 -313 -210 -29 -158 92 -94 -179 244 52 191 151 -64 147 270 194 -213 -480 -129 44 369 507 233 -419 -423 -373 -264 -169 -229 -325 -455 -311 -341 -189 -181 -169 -106 -421 -362 110 230 782 725 675 646 864 531 354 516 597 985 1378 1435 1019 -186 104 -322 -45 983 428 89 174 -21 -147 130 -77 -410 -477 -139 -794 -1083 -1475 -1988 -1483 -1024 -1020 -586 -292 -45 199 111 -216 515 460 507 414 745 615 245 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