File name: Pandora135s1_ManhattanNY-CCNY_20240417_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240418T045902.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240417_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240417 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240417T131013.8Z 8873.548770 251 1 7.51 2 57.65 104.76 119.68 8.89 0.00 1 0.00 1 0 17 1.477e-02 6.336e-03 5.875e-03 1.496e-03 3.253941e-01 7.705627e-04 3.935298e-03 -6.000000e+00 8.623078e-03 228.84 -2.00 3.51 -2.00 317.54 0.00e+00 8.470533e-04 1.169528e-04 3.426129e-04 -6.000000e+00 3.734324e-04 280.59 -2.00 20.00 -2.00 316.88 0.00e+00 1.862 0.000 302.00 328.00 3 3.0955e+00 2.0398e-03 2.5296e-02 -6.0000e+00 2.1509e-02 1.2384e-02 2.2829e-03 1.6825e-02 -6.0000e+00 2.3208e-02 -1.5637e-02 1.4254e-03 8.3350e-03 -6.0000e+00 1.3786e-02 3.8385e-03 7.3252e-04 2.4018e-03 -6.0000e+00 5.9898e-03 2.3978e-03 -3.9354e-04 4.2107e-05 2.4740e-05 -6.0000e+00 4.0183e-04 -5.1997e-02 1.7010e-04 12 1 1 12 1 1 91.48 20.52 0.27 -0.05200 -0.05495 34 61 1 5 0 214.350 25.28 20.00 20.52 19.81 24.5 987.87 -239 -1573 -1988 -4499 -4394 -8304 -3635 -3139 -2313 -3721 -5247 -1935 -2964 695 -1718 604 -54 462 865 233 584 105 1040 212 297 -1219 -334 -1120 -1090 -1293 187 327 -100 -1521 -3301 -2740 -2890 -611 -79 -149 -535 -482 -284 -180 306 33 -71 -607 -290 217 687 952 1707 1286 1767 1413 571 560 514 1122 1246 1896 1868 1385 469 -234 -304 146 502 788 505 339 267 -107 41 -447 -1532 -1723 -1547 -1421 -955 -1187 -1906 -1032 -972 -158 -161 364 30 430 -297 -670 -734 -712 -337 172 572 549 197 -213 -472 -624 -316 -472 -729 -601 -684 -145 97 920 586 823 650 312 -127 260 28 275 268 -41 60 465 677 570 605 -234 44 344 184 134 -169 -93 -445 -706 -547 -132 433 301 -45 106 -359 -460 -19 -138 -179 -393 -345 -650 -288 -280 -228 -391 -561 -209 -369 98 -288 110 -11 94 184 52 132 24 238 52 77 -334 -90 -289 -266 -315 48 94 -29 -458 -958 -845 -889 -216 -34 -68 -270 -256 -155 -99 168 18 -39 -328 -155 117 392 587 1034 825 1168 962 399 390 350 753 862 1405 1415 1131 389 -182 -237 111 383 680 448 314 247 -95 36 -354 -1193 -1291 -1224 -1190 -902 -1168 -2023 -1073 -1079 -186 -189 438 36 527 -340 -747 -754 -716 -360 192 710 716 260 -279 -612 -781 -372 -573 -906 -791 -943 -197 140 1339 909 1298 994 471 -178 359 39 375 391 -61 90 719 1013 821 829 -325 57 455 262 197 -264 -142 -695 -1153 -902 -227 764 541 -81 187 -609 -785 SS 20240417T131413.9Z 8873.551550 254 1 25.62 2 56.92 105.54 119.57 9.92 0.00 1 0.00 1 0 17 1.201e-02 5.328e-03 1.145e-03 3.282e-04 3.169941e-01 1.686310e-04 3.824645e-03 -6.000000e+00 7.006794e-03 228.84 -2.00 3.51 -2.00 317.35 0.00e+00 6.055626e-04 2.457787e-05 1.424211e-04 -6.000000e+00 3.034689e-04 280.59 -2.00 20.00 -2.00 316.70 0.00e+00 1.826 0.000 302.00 328.00 3 1.3955e+00 4.4464e-04 2.4724e-02 -6.0000e+00 1.7477e-02 1.3477e-02 4.9701e-04 1.6389e-02 -6.0000e+00 1.8859e-02 -1.1891e-02 3.0585e-04 8.0937e-03 -6.0000e+00 1.1203e-02 3.1366e-03 1.5568e-04 2.3187e-03 -6.0000e+00 4.8667e-03 1.3765e-02 -4.3487e-04 9.2263e-06 2.5139e-05 -6.0000e+00 3.2660e-04 -5.1924e-02 1.2550e-04 12 1 1 12 1 1 99.02 20.52 0.23 -0.05192 -0.05519 637 331 1 5 0 39.890 25.28 20.01 20.52 20.13 24.5 990.93 -1634 -2208 -2435 -4942 -4589 -5184 -2768 -1868 -1964 -3327 -3772 -2844 -1885 -335 -449 -309 -112 616 630 848 538 299 639 397 386 -111 -657 -1173 -612 14 710 1434 607 -1225 -2090 -1633 -1491 -287 -10 -418 -842 -536 -597 -261 25 -17 -429 -366 -310 462 880 885 1272 889 910 969 613 447 570 1040 1093 1525 1576 1105 13 -27 -366 267 777 530 368 196 130 -105 -72 -340 -577 -734 -461 -842 -1020 -1531 -1869 -1410 -917 -655 -419 -197 -31 275 328 114 524 695 402 305 462 164 61 -317 -510 -656 48 -200 -744 -738 -655 -404 -9 303 201 283 136 188 108 509 362 414 281 -7 -40 172 292 425 503 5 482 757 382 231 -46 161 -165 -207 -196 -46 206 82 -287 -181 -429 -484 -150 -225 -255 -500 -417 -453 -251 -190 -223 -402 -459 -358 -267 -55 -85 -65 -25 142 139 194 126 70 152 100 104 -31 -185 -314 -154 4 188 416 194 -410 -667 -508 -504 -113 -4 -214 -440 -294 -337 -148 14 -10 -242 -202 -169 255 513 557 850 587 622 679 439 319 397 715 775 1161 1312 928 11 -21 -290 207 643 468 335 186 123 -95 -64 -274 -451 -551 -365 -712 -978 -1537 -2015 -1501 -1038 -750 -506 -245 -39 326 380 121 538 698 432 344 551 217 83 -423 -669 -787 57 -245 -941 -989 -870 -561 -13 451 304 434 212 273 152 708 502 570 415 -10 -61 257 423 619 697 8 636 1003 519 341 -68 246 -258 -324 -324 -76 351 142 -503 -308 -734 -794 SS 20240417T131922.0Z 8873.555116 257 1 47.81 2 55.99 106.56 119.41 11.25 0.00 1 0.00 1 0 17 1.157e-02 5.297e-03 7.059e-04 2.099e-04 3.095747e-01 1.081347e-04 3.737588e-03 -6.000000e+00 6.752962e-03 228.84 -2.00 3.51 -2.00 317.29 0.00e+00 5.974469e-04 1.550027e-05 1.323726e-04 -6.000000e+00 2.924717e-04 280.59 -2.00 20.00 -2.00 316.64 0.00e+00 1.782 0.000 302.00 328.00 3 1.1630e+00 2.8485e-04 2.4137e-02 -6.0000e+00 1.6844e-02 1.1307e-02 3.1817e-04 1.6001e-02 -6.0000e+00 1.8175e-02 -1.1431e-02 1.9471e-04 7.9087e-03 -6.0000e+00 1.0797e-02 2.9141e-03 9.8561e-05 2.2725e-03 -6.0000e+00 4.6905e-03 1.8363e-02 -3.9815e-04 5.8960e-06 2.4216e-05 -6.0000e+00 3.1475e-04 -5.1983e-02 1.3143e-04 10 0 0 10 0 0 99.04 20.53 0.24 -0.05198 -0.05497 1632 460 1 5 0 28.680 25.39 20.00 20.53 20.55 24.6 993.84 -1669 -2082 -2496 -4698 -4479 -4826 -2523 -1373 -1526 -3326 -3618 -2535 -1738 -263 -258 -424 -192 579 718 1259 479 463 698 482 393 -190 -677 -1220 -669 -67 892 1408 714 -1362 -1997 -1687 -1470 -160 -102 -388 -813 -504 -600 -210 42 -44 -390 -483 -312 460 872 877 1177 841 903 966 606 430 614 978 1156 1574 1509 1130 -27 -74 -350 241 760 516 361 176 119 -90 -57 -355 -621 -706 -550 -823 -1038 -1430 -1831 -1408 -905 -653 -435 -134 26 302 306 143 516 747 424 335 431 158 32 -305 -489 -634 -19 -159 -765 -720 -666 -434 35 294 165 292 122 194 95 513 364 416 317 1 -77 198 220 426 487 12 526 744 390 213 -67 193 -151 -232 -195 -31 208 60 -308 -167 -438 -450 -161 -223 -275 -498 -426 -441 -239 -145 -180 -420 -459 -331 -255 -44 -50 -92 -44 137 163 295 115 111 170 125 108 -55 -195 -334 -172 -18 240 415 231 -462 -645 -532 -503 -64 -45 -200 -429 -279 -342 -121 24 -25 -221 -269 -171 255 510 553 788 596 617 676 434 307 427 673 819 1197 1255 946 -23 -63 -275 185 624 452 346 166 111 -86 -51 -304 -482 -525 -432 -734 -983 -1416 -1948 -1566 -1011 -779 -519 -164 32 374 351 159 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