File name: Pandora135s1_ManhattanNY-CCNY_20240422_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240423T050008.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240422_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240422 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240422T131459.2Z 8878.552074 321 1 27.62 2 55.46 104.36 131.62 302.94 0.00 1 0.00 1 0 17 1.411e-02 5.480e-03 6.079e-04 1.651e-04 3.283866e-01 8.513264e-05 3.967044e-03 -6.000000e+00 8.255798e-03 229.25 -2.00 3.51 -2.00 317.39 0.00e+00 6.166752e-04 1.257741e-05 1.328528e-04 -6.000000e+00 3.574151e-04 281.14 -2.00 20.00 -2.00 316.74 0.00e+00 1.758 0.000 302.00 328.00 3 8.9256e-02 2.2465e-04 2.4724e-02 -6.0000e+00 2.0610e-02 2.0443e-02 2.5075e-04 1.7029e-02 -6.0000e+00 2.2219e-02 -1.2297e-02 1.5526e-04 8.4037e-03 -6.0000e+00 1.3199e-02 3.7234e-03 7.9651e-05 2.4074e-03 -6.0000e+00 5.7411e-03 5.2772e-02 -3.3782e-04 4.6093e-06 2.5450e-05 -6.0000e+00 3.8348e-04 -6.2491e-02 1.3098e-04 10 0 0 10 0 0 26.88 20.00 0.25 -0.06249 -0.06503 2668 753 1 5 0 9.850 24.86 19.98 20.00 13.60 23.9 944.66 -3058 -2880 -3365 -5246 -5712 -5874 -4385 -3070 -2763 -4259 -4065 -3451 -2073 -529 -149 -513 -117 318 518 868 460 376 -672 406 180 -75 -763 -1185 -899 -22 704 1364 689 -1352 -1975 -1640 -1335 -281 19 -350 -773 -366 -509 -142 187 126 -301 -271 -198 567 958 1003 1277 921 948 991 640 499 671 913 1244 1557 1592 1100 35 38 -218 297 799 407 164 63 -70 -168 -173 -299 -524 -546 -373 -783 -989 -1426 -1901 -1426 -1004 -803 -558 -280 -113 176 321 157 594 878 523 362 404 241 -43 -337 -498 -646 64 -78 -772 -708 -678 -431 12 328 139 257 130 252 155 640 446 455 265 -77 -206 153 178 400 508 52 608 920 480 253 -40 198 -100 -118 -237 -92 191 26 -369 -226 -438 -451 -261 -273 -330 -498 -490 -481 -373 -292 -293 -484 -463 -406 -273 -81 -26 -101 -25 70 119 206 112 91 -154 98 46 -20 -206 -304 -237 -6 194 379 211 -439 -612 -493 -432 -106 8 -172 -421 -194 -279 -79 103 70 -165 -146 -114 328 543 615 833 637 635 681 450 350 460 661 861 1155 1293 905 29 32 -171 226 648 352 157 59 -65 -161 -154 -255 -406 -404 -290 -692 -932 -1409 -2028 -1502 -1123 -960 -666 -344 -139 207 371 176 608 872 554 403 503 317 -58 -449 -655 -776 76 -95 -964 -937 -938 -592 18 483 219 394 204 367 218 889 615 621 387 -114 -312 228 269 581 700 72 796 1204 678 369 -59 301 -155 -192 -390 -158 323 45 -644 -384 -748 -735 SS 20240422T131527.2Z 8878.552398 321 2 27.73 2 55.37 104.45 131.69 303.05 0.00 1 0.00 1 0 17 1.414e-02 5.476e-03 6.028e-04 1.646e-04 3.278788e-01 8.481108e-05 3.959449e-03 -6.000000e+00 8.275110e-03 229.25 -2.00 3.51 -2.00 317.39 0.00e+00 5.911166e-04 1.250862e-05 1.334408e-04 -6.000000e+00 3.582485e-04 281.14 -2.00 20.00 -2.00 316.74 0.00e+00 1.755 0.000 302.00 328.00 3 8.8896e-02 2.2380e-04 2.4672e-02 -6.0000e+00 2.0658e-02 2.0450e-02 2.4974e-04 1.6995e-02 -6.0000e+00 2.2271e-02 -1.2283e-02 1.5459e-04 8.3864e-03 -6.0000e+00 1.3230e-02 3.6832e-03 7.9298e-05 2.3983e-03 -6.0000e+00 5.7545e-03 5.3032e-02 -3.2460e-04 4.6017e-06 2.5628e-05 -6.0000e+00 3.8437e-04 -6.2439e-02 1.3420e-04 10 0 0 10 0 0 24.60 20.00 0.25 -0.06244 -0.06488 2668 753 1 5 0 9.850 24.86 19.98 20.00 13.60 23.9 945.30 -3037 -2738 -3679 -5399 -5814 -5794 -4369 -2829 -2676 -4126 -4190 -3400 -2067 -737 -219 -607 -18 388 674 845 324 441 -699 499 224 -43 -786 -1150 -833 -46 735 1409 700 -1397 -1959 -1666 -1293 -282 -18 -376 -769 -438 -457 -82 192 85 -286 -275 -185 583 920 974 1263 953 909 1019 670 518 694 910 1238 1589 1551 1140 18 17 -216 293 794 419 206 23 -55 -168 -190 -298 -534 -549 -378 -788 -998 -1417 -1886 -1429 -988 -795 -548 -283 -107 157 334 136 571 851 525 377 385 249 -49 -359 -494 -605 66 -58 -813 -711 -657 -425 20 308 144 256 129 254 161 627 438 453 266 -83 -221 138 195 429 507 85 601 914 475 245 -9 205 -93 -135 -237 -97 203 36 -379 -217 -444 -473 -260 -260 -364 -516 -503 -477 -374 -270 -285 -471 -481 -403 -274 -113 -39 -121 -4 85 155 201 79 107 -161 120 58 -12 -213 -297 -220 -12 203 393 215 -455 -609 -503 -420 -107 -8 -185 -420 -234 -251 -46 106 47 -157 -149 -106 338 524 599 826 661 610 701 471 364 476 617 859 1182 1263 940 15 14 -169 224 646 364 196 22 -52 -162 -169 -255 -415 -407 -295 -654 -942 -1403 -2014 -1508 -1106 -951 -655 -348 -131 185 386 152 586 846 557 420 455 327 -65 -479 -651 -726 79 -70 -1016 -942 -910 -583 29 455 226 392 201 371 228 871 604 618 390 -124 -336 205 296 622 700 118 788 1198 671 357 -13 312 -145 -219 -391 -168 343 62 -662 -369 -758 -771 SS 20240422T132025.0Z 8878.555845 324 1 27.77 2 54.46 105.43 132.46 304.27 0.00 1 0.00 1 0 17 1.353e-02 5.510e-03 5.611e-04 1.605e-04 3.218342e-01 8.275611e-05 3.883067e-03 -6.000000e+00 7.919426e-03 229.26 -2.00 3.51 -2.00 317.33 0.00e+00 5.977931e-04 1.201019e-05 1.295170e-04 -6.000000e+00 3.428555e-04 281.14 -2.00 20.00 -2.00 316.67 0.00e+00 1.716 0.000 302.00 328.00 3 8.6077e-02 2.1821e-04 2.4159e-02 -6.0000e+00 1.9770e-02 2.0273e-02 2.4370e-04 1.6659e-02 -6.0000e+00 2.1314e-02 -1.1774e-02 1.4982e-04 8.2281e-03 -6.0000e+00 1.2662e-02 3.6059e-03 7.6401e-05 2.3579e-03 -6.0000e+00 5.5071e-03 5.5745e-02 -3.2972e-04 4.4941e-06 2.5275e-05 -6.0000e+00 3.6786e-04 -6.2395e-02 1.3211e-04 10 0 0 10 0 0 22.77 20.01 0.25 -0.06239 -0.06487 2747 775 1 5 0 9.570 24.86 19.99 20.01 14.08 24.0 949.37 -2654 -2791 -3252 -5286 -5465 -5665 -3839 -2296 -2341 -4070 -4110 -3208 -1970 -624 -315 -499 -26 397 671 1067 568 449 -358 504 227 -100 -680 -1165 -778 68 786 1561 685 -1233 -2016 -1667 -1355 -308 0 -405 -804 -432 -450 -142 211 93 -259 -281 -190 541 918 1000 1251 943 903 1016 659 502 685 946 1267 1560 1535 1113 -2 11 -230 273 747 406 208 61 -34 -183 -186 -306 -536 -545 -419 -815 -978 -1425 -1901 -1405 -997 -797 -551 -314 -117 179 303 145 586 852 516 390 416 251 -52 -344 -496 -619 69 -55 -765 -716 -691 -432 11 303 136 252 145 240 161 653 452 466 271 -74 -203 164 194 421 482 53 620 890 485 277 -24 209 -117 -116 -232 -89 154 28 -380 -213 -448 -458 -242 -283 -341 -536 -500 -494 -347 -231 -263 -492 -499 -400 -275 -101 -59 -104 -6 91 161 243 133 105 -86 127 61 -28 -192 -313 -214 18 207 450 218 -414 -647 -519 -454 -120 0 -206 -419 -237 -254 -81 120 53 -146 -156 -104 299 534 628 836 623 618 713 473 360 480 653 896 1183 1274 934 -2 9 -183 212 615 357 190 58 -32 -167 -169 -250 -422 -409 -330 -684 -932 -1424 -2048 -1494 -1126 -963 -664 -390 -144 214 353 155 605 853 550 437 494 332 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