File name: Pandora135s1_ManhattanNY-CCNY_20240509_L2Fit_fwvt1c15d20200411p1-8.txt File generation date: 20240511T131506.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240509_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 1654 1803 Nominal wavelengths inside fitting window [nm]: 492.0457 492.1668 492.2878 492.4089 492.5299 492.6509 492.7719 492.8929 493.0138 493.1347 493.2557 493.3766 493.4975 493.6183 493.7392 493.8600 493.9808 494.1016 494.2224 494.3432 494.4639 494.5847 494.7054 494.8261 494.9468 495.0674 495.1881 495.3087 495.4293 495.5499 495.6705 495.7911 495.9116 496.0321 496.1527 496.2732 496.3936 496.5141 496.6345 496.7550 496.8754 496.9958 497.1162 497.2365 497.3569 497.4772 497.5975 497.7178 497.8381 497.9583 498.0786 498.1988 498.3190 498.4392 498.5594 498.6795 498.7997 498.9198 499.0399 499.1600 499.2801 499.4001 499.5202 499.6402 499.7602 499.8802 500.0001 500.1201 500.2400 500.3600 500.4799 500.5997 500.7196 500.8395 500.9593 501.0791 501.1989 501.3187 501.4385 501.5582 501.6779 501.7977 501.9174 502.0370 502.1567 502.2763 502.3960 502.5156 502.6352 502.7548 502.8743 502.9939 503.1134 503.2329 503.3524 503.4719 503.5913 503.7108 503.8302 503.9496 504.0690 504.1883 504.3077 504.4270 504.5464 504.6657 504.7849 504.9042 505.0235 505.1427 505.2619 505.3811 505.5003 505.6195 505.7386 505.8577 505.9769 506.0959 506.2150 506.3341 506.4531 506.5722 506.6912 506.8102 506.9291 507.0481 507.1670 507.2860 507.4049 507.5238 507.6426 507.7615 507.8803 507.9991 508.1179 508.2367 508.3555 508.4742 508.5930 508.7117 508.8304 508.9491 509.0677 509.1864 509.3050 509.4236 509.5422 509.6608 509.7794 509.8979 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240509T131836.1Z 8895.554585 178 1 26.01 2 51.14 100.57 61.39 80.08 0.00 1 0.00 1 0 15 1.934e-03 1.935e-03 5.005e-04 5.000e-04 1.643145e+03 2.939792e+01 1.150659e+02 -6.000000e+00 1.091957e+02 283.00 -2.00 20.00 -2.00 505.26 0.00e+00 5.426280e-04 1.379089e-05 3.116730e-05 -6.000000e+00 5.463342e-05 283.00 -2.00 20.00 -2.00 500.51 0.00e+00 1.700364e-02 9.929655e-03 1.384330e-02 -6.000000e+00 3.892617e-02 230.68 -2.00 3.51 -2.00 502.09 0.00e+00 1.590 0.000 489.00 513.00 1 6.2273e+00 7.5989e-04 2.6561e-03 -6.0000e+00 2.9826e-03 -3.9260e-03 1.9754e-04 3.2987e-04 -6.0000e+00 7.7618e-04 3.0541e-03 -1.5006e-04 5.1200e-05 1.7413e-05 -6.0000e+00 2.0262e-04 -4.1982e-02 1.1787e-04 12 1 1 12 1 1 92.99 20.91 0.81 -0.04198 -0.04302 30 16 1 4 0 838.870 25.68 20.00 20.91 22.69 24.9 1007.70 -361 -432 -185 -186 -147 109 398 355 409 265 178 87 -143 -201 -145 -254 -192 16 140 -58 -75 304 161 206 328 260 149 94 -1 -377 -253 -179 -262 268 199 -130 -121 137 142 -128 73 15 17 158 211 217 179 4 87 1 -238 -297 -451 -374 -262 -135 -95 -31 -29 88 229 310 192 136 108 79 115 -11 -15 -81 -74 -86 -253 -251 49 -164 -292 -155 -1 -21 -130 -182 -320 -84 -22 -123 -204 45 103 -61 -81 199 240 97 58 90 -17 -49 -82 -48 -250 -362 -254 -91 -253 -313 -274 -171 -42 161 99 -2 36 137 238 374 370 276 236 167 117 22 164 290 197 91 204 167 -1 124 75 -67 -82 -86 -183 31 125 -189 -82 127 -9 53 70 104 -15 -50 -38 -179 -246 -289 -348 -421 -177 -184 -144 109 407 367 423 273 181 87 -142 -204 -146 -255 -195 16 143 -60 -78 317 168 216 344 264 151 98 -1 -376 -255 -179 -257 270 206 -133 -123 142 146 -130 74 15 17 165 214 220 182 4 89 1 -232 -293 -438 -364 -260 -133 -96 -31 -29 90 234 317 197 140 111 80 115 -11 -15 -81 -73 -85 -252 -244 48 -161 -283 -153 -1 -20 -127 -178 -317 -81 -22 -121 -202 45 102 -60 -81 201 245 96 57 91 -17 -48 -80 -46 -239 -350 -244 -90 -258 -310 -279 -171 -42 160 99 -2 36 139 242 381 378 282 241 168 116 21 165 292 193 89 200 163 -1 120 73 -67 -80 -83 -176 30 123 -183 -81 127 -9 54 70 106 -15 -51 -38 -175 -236 -285 SQ 20240509T132844.5Z 8895.561627 181 1 6.28 2 49.26 102.54 59.54 81.48 0.00 1 0.00 1 0 15 1.792e-03 1.788e-03 8.993e-05 8.984e-05 1.600179e+03 5.284104e+00 1.149899e+02 -6.000000e+00 1.011798e+02 283.00 -2.00 20.00 -2.00 505.26 0.00e+00 5.815369e-04 2.487713e-06 3.520750e-05 -6.000000e+00 5.062874e-05 283.00 -2.00 20.00 -2.00 500.50 0.00e+00 -1.441155e-02 1.786600e-03 1.313789e-02 -6.000000e+00 3.607724e-02 230.68 -2.00 3.51 -2.00 502.08 0.00e+00 1.529 0.000 489.00 513.00 1 5.1870e-02 1.3680e-04 2.5854e-03 -6.0000e+00 2.7642e-03 2.0361e-03 3.5550e-05 3.1366e-04 -6.0000e+00 7.1954e-04 1.4840e+00 -6.9975e-06 9.1787e-06 1.8931e-05 -6.0000e+00 1.8768e-04 -4.2395e-02 1.0120e-04 10 0 0 10 0 0 9.40 20.92 0.87 -0.04239 -0.04244 1018 287 2 4 0 5.730 25.68 20.00 20.92 23.51 25.0 1014.30 -198 -203 -95 22 -3 234 454 357 397 344 240 165 -33 -60 -57 -193 -204 -41 87 -66 -53 135 137 209 274 173 58 180 21 -209 -150 -154 -190 224 156 -173 -66 110 13 -90 2 -46 -33 23 104 81 55 -18 -49 -99 -262 -248 -362 -367 -148 -131 -168 -190 -100 -36 56 155 98 84 101 50 24 -29 36 -72 -79 -105 -236 -111 31 -128 -329 -194 -16 -70 -133 -186 -320 -142 41 -124 -128 -32 20 -36 -52 87 158 91 26 71 -85 -175 -8 -97 -262 -357 -321 -121 -291 -447 -271 -180 -101 76 78 -30 42 119 161 257 316 352 234 238 231 138 233 405 195 79 289 142 74 287 155 16 70 -11 -71 164 144 -146 -110 101 59 75 161 104 -4 -35 -67 -197 -227 -254 -193 -194 -93 22 -3 241 460 366 408 350 249 168 -33 -60 -57 -191 -204 -42 91 -68 -55 140 141 217 285 180 61 184 21 -212 -148 -152 -190 230 160 -180 -69 113 13 -91 2 -47 -34 24 108 84 57 -19 -50 -101 -261 -240 -357 -362 -144 -131 -168 -192 -101 -36 57 157 99 85 102 50 24 -29 36 -70 -77 -101 -231 -110 31 -128 -324 -188 -15 -69 -127 -179 -311 -139 41 -124 -128 -32 20 -36 -51 86 159 92 27 70 -85 -172 -7 -92 -254 -338 -312 -122 -291 -450 -271 -177 -99 76 77 -30 42 122 162 258 318 355 235 243 233 137 230 399 193 79 287 141 74 283 152 16 69 -11 -69 160 139 -144 -110 102 59 74 160 104 -4 -35 -67 -195 -220 -244 SQ 20240509T132851.0Z 8895.561702 181 2 6.28 2 49.24 102.56 59.52 81.50 0.00 1 0.00 1 0 15 1.788e-03 1.783e-03 8.995e-05 8.986e-05 1.605351e+03 5.274549e+00 1.154776e+02 -6.000000e+00 1.009889e+02 283.00 -2.00 20.00 -2.00 505.25 0.00e+00 5.839545e-04 2.487576e-06 3.542929e-05 -6.000000e+00 5.053323e-05 283.00 -2.00 20.00 -2.00 500.50 0.00e+00 -1.824199e-02 1.784958e-03 1.316437e-02 -6.000000e+00 3.600918e-02 230.68 -2.00 3.51 -2.00 502.08 0.00e+00 1.529 0.000 489.00 513.00 1 5.4918e-02 1.3665e-04 2.5872e-03 -6.0000e+00 2.7590e-03 2.1191e-03 3.5547e-05 3.1434e-04 -6.0000e+00 7.1818e-04 1.4800e+00 -1.0756e-05 9.1858e-06 1.8880e-05 -6.0000e+00 1.8733e-04 -4.2342e-02 1.0088e-04 10 0 0 10 0 0 1.13 20.92 0.87 -0.04234 -0.04242 1018 287 2 4 0 5.730 25.68 20.00 20.92 23.51 24.9 1014.30 -211 -201 -74 19 7 235 451 348 406 341 239 176 -7 -55 -66 -182 -178 -23 100 -53 -35 123 133 198 265 177 54 169 10 -208 -146 -164 -209 223 143 -187 -93 114 27 -90 -15 -42 -30 37 104 95 60 -30 -45 -118 -247 -226 -386 -356 -150 -139 -164 -197 -113 -18 62 156 101 68 103 60 15 -23 21 -62 -94 -97 -239 -102 22 -136 -324 -190 -12 -60 -141 -168 -311 -142 24 -142 -147 -34 12 -45 -47 74 173 72 14 77 -78 -161 -37 -92 -281 -355 -326 -111 -292 -462 -257 -169 -84 80 59 -29 45 113 186 247 333 356 218 240 226 161 248 413 190 88 265 155 90 290 157 17 73 -12 -79 170 134 -146 -90 89 42 61 153 94 9 -26 -61 -177 -237 -241 -206 -191 -72 19 7 241 455 356 415 347 248 180 -7 -55 -65 -179 -177 -24 104 -55 -36 127 138 205 275 184 56 173 10 -211 -144 -161 -209 228 146 -195 -97 117 28 -91 -16 -43 -31 38 107 99 62 -31 -46 -120 -245 -225 -379 -351 -145 -139 -168 -199 -114 -18 63 157 103 69 104 59 15 -23 21 -60 -91 -94 -233 -101 22 -135 -319 -183 -12 -59 -139 -161 -301 -139 23 -141 -147 -34 12 -45 -48 73 173 73 14 77 -78 -158 -35 -90 -272 -335 -316 -111 -291 -465 -256 -166 -85 80 57 -29 46 116 191 248 335 359 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