File name: Pandora135s1_ManhattanNY-CCNY_20240604_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T215319.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240604_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240604 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240604T133422.0Z 8921.565532 244 1 8.21 2 45.58 97.91 28.54 130.56 0.00 1 0.00 1 0 17 8.318e-03 5.787e-03 9.963e-04 5.144e-04 2.265553e-01 2.639545e-04 2.703959e-03 -6.000000e+00 4.819917e-03 232.33 -2.00 3.51 -2.00 316.10 0.00e+00 5.285136e-04 2.845346e-05 9.531481e-05 -6.000000e+00 2.131692e-04 285.64 -2.00 20.00 -2.00 315.35 0.00e+00 1.426 0.000 302.00 328.00 3 1.7815e+00 6.9120e-04 1.8634e-02 -6.0000e+00 1.2096e-02 -3.3353e-04 7.7070e-04 1.1773e-02 -6.0000e+00 1.3099e-02 -5.7146e-03 4.4191e-04 5.7028e-03 -6.0000e+00 7.7869e-03 1.2818e-03 2.0161e-04 1.5625e-03 -6.0000e+00 3.2700e-03 1.6406e-02 -5.1496e-04 1.4538e-05 1.8160e-05 -6.0000e+00 2.2640e-04 1.6457e-02 0.0000e+00 12 1 1 12 1 1 80.10 21.39 0.23 0.01646 0.01259 181 293 1 5 0 45.070 26.11 20.01 21.39 28.18 25.5 1045.54 -251 -120 -1383 -2751 -2809 -2088 34 924 299 -2006 -1372 -1114 -103 419 421 80 198 692 826 1281 408 580 415 930 705 108 -558 -744 -509 194 650 1060 136 -1951 -2239 -1800 -1237 -268 -31 -560 -871 -594 -588 -445 -208 -216 -683 -524 -516 495 808 1027 1324 954 1052 1063 704 511 737 996 1399 1574 1602 1077 -24 -319 -665 65 701 517 399 275 216 75 -66 -423 -1023 -1083 -1105 -1144 -1192 -1517 -1665 -1273 -703 -410 -174 -1 55 233 98 -412 -72 187 -6 238 511 231 20 -243 -508 -569 -1 -318 -723 -621 -642 -293 134 424 401 513 351 235 144 385 179 256 216 95 -7 384 367 628 537 48 476 608 400 220 -103 62 -343 -517 -294 -22 279 166 -153 2 -270 -337 -598 -53 -27 -320 -595 -543 -385 6 198 71 -502 -336 -280 -26 121 137 28 72 258 319 469 153 215 157 367 294 47 -238 -297 -206 77 268 434 60 -886 -956 -754 -565 -143 -18 -356 -601 -426 -431 -328 -152 -158 -488 -363 -348 332 569 770 979 740 835 861 580 419 592 796 1154 1393 1444 1026 -23 -278 -567 54 622 489 387 277 217 73 -62 -385 -845 -853 -916 -1067 -1172 -1548 -1805 -1366 -803 -475 -212 -1 68 278 114 -462 -74 196 -7 275 617 293 27 -318 -621 -674 -1 -377 -887 -804 -869 -393 187 599 593 760 499 324 190 479 224 334 289 135 -10 554 513 839 716 60 602 774 517 305 -143 88 -492 -775 -445 -34 433 263 -245 3 -425 -511 -895 SS 20240604T134101.7Z 8921.570159 248 1 49.22 2 44.33 99.19 27.60 133.13 0.00 1 0.00 1 0 17 8.207e-03 5.563e-03 2.165e-04 1.142e-04 2.205039e-01 5.854413e-05 2.627383e-03 -6.000000e+00 4.754429e-03 232.33 -2.00 3.51 -2.00 316.04 0.00e+00 3.948500e-04 6.235880e-06 5.826497e-05 -6.000000e+00 2.103009e-04 285.64 -2.00 20.00 -2.00 315.30 0.00e+00 1.396 0.000 302.00 328.00 3 5.5175e-01 1.5320e-04 1.8186e-02 -6.0000e+00 1.1932e-02 -2.3683e-03 1.7086e-04 1.1447e-02 -6.0000e+00 1.2921e-02 -2.6553e-03 9.7744e-05 5.5449e-03 -6.0000e+00 7.6815e-03 4.0335e-04 4.4355e-05 1.5167e-03 -6.0000e+00 3.2250e-03 5.8493e-02 -4.4013e-04 3.2344e-06 1.8081e-05 -6.0000e+00 2.2337e-04 1.7751e-02 0.0000e+00 10 0 0 10 0 0 39.80 21.41 0.26 0.01775 0.01444 3979 1122 1 5 0 11.760 26.11 20.00 21.41 29.20 25.8 1053.98 -401 -859 -1810 -3240 -2677 -2035 -68 795 -12 -1932 -1799 -999 -297 573 406 -102 187 717 837 1132 592 667 615 904 562 308 -369 -608 -76 609 1328 1680 533 -1553 -1850 -1423 -1030 36 45 -497 -883 -613 -734 -400 -190 -350 -760 -710 -492 344 670 808 1055 707 778 871 529 444 626 951 1186 1499 1467 897 -193 -233 -439 345 870 481 279 133 97 -53 -70 -271 -655 -598 -452 -833 -1078 -1570 -1814 -1294 -837 -562 -344 -97 75 303 291 25 470 694 327 327 418 212 -47 -345 -544 -603 27 -281 -764 -686 -661 -423 55 295 191 305 139 158 125 485 293 329 222 -30 -18 258 303 590 604 154 649 774 410 242 -56 180 -134 -286 -194 -28 261 78 -249 -84 -379 -377 -553 -88 -203 -432 -723 -531 -385 -13 176 -3 -497 -455 -257 -77 169 135 -37 69 272 328 456 224 271 235 363 238 135 -159 -245 -31 241 549 689 236 -705 -789 -647 -472 19 27 -317 -612 -441 -541 -295 -140 -256 -543 -491 -331 231 471 606 832 547 616 703 434 362 500 757 976 1322 1316 850 -181 -213 -370 282 763 450 284 132 97 -54 -66 -243 -532 -494 -367 -764 -1044 -1580 -1940 -1445 -944 -678 -415 -120 92 375 332 28 495 711 336 370 497 264 -62 -443 -685 -698 31 -327 -968 -872 -877 -583 76 428 277 442 201 222 161 619 375 419 305 -42 -25 364 415 808 786 202 800 960 544 326 -79 259 -187 -415 -298 -42 412 127 -404 -133 -580 -584 -844 SS 20240604T134623.4Z 8921.573882 251 1 49.21 2 43.33 100.24 26.88 135.30 0.00 1 0.00 1 0 17 8.099e-03 5.561e-03 2.112e-04 1.131e-04 2.170070e-01 5.796655e-05 2.592591e-03 -6.000000e+00 4.691987e-03 232.33 -2.00 3.51 -2.00 315.99 0.00e+00 4.018957e-04 6.112069e-06 5.698490e-05 -6.000000e+00 2.075461e-04 285.64 -2.00 20.00 -2.00 315.25 0.00e+00 1.373 0.000 302.00 328.00 3 5.6003e-01 1.5165e-04 1.7902e-02 -6.0000e+00 1.1775e-02 -2.6464e-03 1.6908e-04 1.1285e-02 -6.0000e+00 1.2752e-02 -2.6266e-03 9.6680e-05 5.4684e-03 -6.0000e+00 7.5807e-03 4.4512e-04 4.3798e-05 1.4963e-03 -6.0000e+00 3.1825e-03 5.9726e-02 -4.5951e-04 3.2020e-06 1.7789e-05 -6.0000e+00 2.2045e-04 1.8080e-02 0.0000e+00 10 0 0 10 0 0 14.91 21.42 0.25 0.01808 0.01463 4051 1143 1 5 0 11.550 26.11 20.01 21.42 30.04 25.7 1060.64 -283 -818 -1744 -3177 -2693 -1765 8 830 33 -1866 -1757 -968 -259 585 435 -141 222 706 870 1135 572 683 439 895 566 264 -409 -595 -80 668 1291 1662 597 -1541 -1848 -1436 -1002 -28 55 -517 -874 -631 -736 -426 -229 -367 -730 -708 -481 365 647 797 1069 709 773 879 544 463 646 923 1171 1506 1441 899 -199 -232 -433 359 832 503 288 131 106 -40 -67 -263 -630 -560 -486 -843 -1061 -1594 -1819 -1320 -852 -569 -336 -111 53 278 279 27 452 694 312 328 417 198 -27 -345 -537 -607 31 -272 -766 -678 -638 -404 60 324 196 299 149 170 108 491 289 331 228 -42 -42 231 284 607 608 152 654 753 413 243 -51 171 -129 -283 -189 -44 260 91 -250 -85 -357 -375 -573 -64 -199 -429 -730 -550 -343 2 189 8 -452 -456 -256 -69 177 148 -52 84 273 348 431 221 261 172 366 245 117 -180 -245 -33 269 543 692 268 -709 -799 -611 -465 -15 33 -334 -613 -459 -548 -318 -170 -271 -527 -495 -327 247 459 602 848 552 617 714 449 380 519 739 970 1336 1300 856 -188 -213 -366 294 732 472 294 131 106 -41 -63 -237 -513 -463 -396 -774 -1028 -1604 -1945 -1473 -960 -686 -406 -137 65 344 319 30 475 709 339 371 494 245 -35 -441 -674 -701 36 -315 -968 -860 -844 -555 82 469 283 431 215 238 138 623 368 421 311 -58 -60 325 406 828 787 197 802 929 545 326 -72 244 -188 -409 -290 -67 406 146 -403 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