File name: Pandora135s1_ManhattanNY-CCNY_20240605_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240606T045931.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240605_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240605 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240605T133600.2Z 8922.566668 222 1 0.50 2 45.24 98.07 34.34 107.79 0.00 1 0.00 1 0 17 1.463e-02 9.058e-03 1.244e-02 6.601e-03 2.191657e-01 3.457355e-03 2.626980e-03 -6.000000e+00 8.633059e-03 232.39 -2.00 3.51 -2.00 315.94 0.00e+00 6.269482e-04 3.561336e-04 3.367471e-05 -6.000000e+00 3.774027e-04 285.74 -2.00 20.00 -2.00 315.23 0.00e+00 1.418 0.000 302.00 328.00 3 1.9905e+00 9.0221e-03 1.8340e-02 -6.0000e+00 2.1681e-02 1.5320e-02 9.9815e-03 1.1438e-02 -6.0000e+00 2.3333e-02 -4.8313e-03 5.7611e-03 5.5440e-03 -6.0000e+00 1.3864e-02 9.4911e-04 2.6870e-03 1.5840e-03 -6.0000e+00 5.9874e-03 1.3440e-02 7.7268e-05 1.8651e-04 1.8246e-05 -6.0000e+00 3.9882e-04 -3.3732e-02 1.1396e-04 12 9 1 12 1 1 999.00 21.62 0.24 -0.03373 -0.03315 1 55 2 5 0 241.480 26.32 20.00 21.62 30.39 25.7 1061.36 -603 -2226 -4354 -1931 -6224 -3228 1554 -309 2096 -3906 65 -1951 2236 -1487 2885 -356 1188 -1016 1139 1038 618 3212 1421 2038 -1037 345 -2374 542 -671 1279 113 4011 904 -2645 447 -3460 2371 -1357 93 -1312 -584 -233 466 -1956 195 -1874 -1697 -761 -1426 2693 50 1697 1318 2099 733 -127 418 1052 773 1544 1546 2044 2316 -491 -871 -1706 1267 653 334 604 535 465 -391 642 -765 228 -1643 -652 -347 -1049 -781 -1499 -2874 -2072 -314 -961 -189 -941 423 161 198 284 921 919 1476 530 115 -624 275 176 -489 -175 179 142 -1008 -703 -978 -769 680 362 235 489 78 221 -9 -66 418 887 275 -686 462 113 -102 1067 590 618 711 216 -56 848 -1005 592 308 249 -1107 -303 276 -274 94 -348 -415 -364 -133 -518 -1033 -424 -1276 -638 312 -69 501 -986 16 -504 598 -457 953 -127 431 -388 440 414 243 1256 576 839 -463 156 -1077 230 -269 509 47 1712 413 -1252 197 -1574 1088 -723 56 -883 -411 -166 337 -1454 141 -1379 -1243 -535 -1007 1836 36 1251 1027 1654 599 -104 345 877 634 1257 1277 1769 2112 -473 -822 -1549 1075 547 296 577 532 479 -403 642 -735 203 -1375 -528 -296 -969 -769 -1559 -3145 -2314 -362 -1151 -233 -1175 527 196 231 311 955 931 1547 594 138 -798 358 227 -603 -205 206 169 -1262 -908 -1299 -1042 955 523 349 722 112 303 -11 -84 533 1162 377 -974 662 161 -143 1466 788 796 887 274 -73 1149 -1420 837 436 361 -1672 -468 435 -436 149 -550 -643 -553 SS 20240605T134459.2Z 8922.572907 229 1 28.01 2 43.56 99.80 32.75 109.98 0.00 1 0.00 1 0 17 6.477e-02 1.691e-02 3.392e-02 1.124e-02 2.323172e-01 5.827866e-03 2.736491e-03 -6.000000e+00 3.826773e-02 232.39 -2.00 3.51 -2.00 317.26 0.00e+00 1.210109e-03 8.149449e-04 1.324929e-04 -6.000000e+00 1.672245e-03 285.74 -2.00 20.00 -2.00 316.49 0.00e+00 1.378 0.000 302.00 328.00 3 6.4409e+00 1.5500e-02 1.8528e-02 -6.0000e+00 9.6109e-02 7.1904e-02 1.7296e-02 1.2225e-02 -6.0000e+00 1.0338e-01 -3.9549e-03 1.0326e-02 5.8758e-03 -6.0000e+00 6.1425e-02 -1.8092e-03 5.0921e-03 1.9695e-03 -6.0000e+00 2.6563e-02 1.5407e-04 4.7781e-04 3.2615e-04 1.9949e-05 -6.0000e+00 1.7643e-03 -3.4000e-02 4.6716e-04 12 9 9 12 9 1 99.98 21.65 0.32 -0.03400 -0.03041 6 3 2 5 0 4000.000 26.32 20.00 21.65 30.71 25.5 1061.21 5231 -5850 -6687 -11716 26928 -46794 17301 -813 22477 -5848 8423 -4628 13476 4625 -11099 3811 8976 1185 6021 5673 -1613 10344 -6229 6765 -4449 7589 -2991 6663 -5884 -2063 10786 -941 14995 -7589 -3880 218 5554 2420 -1572 -689 719 -3264 -1573 1218 265 2932 -3194 630 -1209 4717 -3415 -166 -174 -2461 4616 4765 -654 -2087 -2724 -180 4275 1960 433 414 -2476 429 -1950 -1873 -761 32 -422 2532 -1673 1151 2660 552 -655 -2467 -1572 606 -987 406 -1990 210 -360 -949 2048 498 -1415 1271 496 -700 -495 -575 -2205 662 53 1017 1002 311 1466 239 -222 -494 -549 -1078 -1624 -870 -127 1078 689 849 -829 -771 984 -2224 -1485 -484 -561 396 1669 1202 -726 2037 -1199 1695 -485 460 1293 -203 -1473 196 -389 413 202 -651 515 1270 211 557 -591 -2006 617 -833 -967 -1651 2380 -7963 1693 -107 2573 -886 1126 -724 1960 842 -2586 830 1991 293 1469 1434 -444 2501 -1803 1799 -1390 2159 -930 1764 -1654 -548 2653 -281 4096 -2620 -1209 66 1745 889 -718 -358 399 -1963 -952 721 158 1694 -1915 353 -672 2479 -2045 -103 -114 -1714 3066 3217 -472 -1514 -1949 -125 2942 1484 360 363 -2196 338 -1449 -1357 -585 27 -396 2395 -1640 1053 2223 422 -473 -1727 -1146 485 -868 386 -2052 222 -409 -1123 2478 629 -1812 1571 570 -737 -491 -555 -2289 711 63 1325 1372 420 1818 275 -254 -593 -689 -1434 -2268 -1255 -190 1699 1102 1358 -1332 -1143 1309 -2982 -1977 -668 -805 598 2543 1813 -1082 2924 -1686 2195 -608 577 1714 -292 -2161 299 -584 641 333 -1132 907 2265 381 978 -1010 -3342 SS 20240605T135032.0Z 8922.576759 232 1 48.93 2 42.53 100.91 31.79 111.41 0.00 1 0.00 1 0 17 7.719e-03 5.574e-03 2.159e-04 1.205e-04 2.106046e-01 6.315811e-05 2.550668e-03 -6.000000e+00 4.555351e-03 232.39 -2.00 3.51 -2.00 315.75 0.00e+00 3.188012e-04 6.296189e-06 5.279587e-05 -6.000000e+00 1.991345e-04 285.74 -2.00 20.00 -2.00 315.05 0.00e+00 1.355 0.000 302.00 328.00 3 6.7317e-01 1.6476e-04 1.7597e-02 -6.0000e+00 1.1440e-02 8.5531e-03 1.8217e-04 1.1026e-02 -6.0000e+00 1.2312e-02 -4.6724e-03 1.0474e-04 5.3567e-03 -6.0000e+00 7.3152e-03 1.4378e-03 4.8462e-05 1.4819e-03 -6.0000e+00 3.1593e-03 5.4433e-02 -2.0394e-04 3.4002e-06 1.8022e-05 -6.0000e+00 2.1042e-04 -3.2689e-02 1.6510e-04 10 0 0 10 0 0 87.29 21.66 0.28 -0.03269 -0.03422 3433 968 1 5 0 13.630 26.32 20.00 21.66 30.96 25.7 1065.96 -414 -883 -1600 -2940 -2217 -1600 66 836 -4 -1669 -1505 -736 -272 496 252 -89 196 689 839 1083 569 690 886 748 568 205 -286 -522 116 640 1256 1695 485 -1390 -1691 -1352 -1004 -89 -145 -649 -937 -663 -740 -414 -232 -404 -733 -687 -434 342 637 823 1050 715 815 905 556 498 701 990 1112 1413 1332 767 -227 -186 -381 418 820 419 239 92 92 -67 -21 -196 -538 -496 -415 -835 -1096 -1606 -1769 -1297 -870 -609 -402 -167 -8 243 271 57 554 766 379 368 459 187 -17 -319 -495 -520 123 -252 -744 -681 -655 -411 84 305 164 283 144 170 163 538 367 400 251 -36 -72 171 232 530 559 112 650 778 428 246 -55 185 -113 -243 -187 -61 208 -1 -366 -211 -484 -499 -103 -216 -393 -734 -491 -338 15 207 -1 -438 -387 -192 -78 161 92 -35 73 263 330 438 234 281 366 325 260 97 -133 -227 51 271 555 740 228 -668 -763 -600 -487 -50 -91 -439 -685 -503 -574 -321 -179 -309 -548 -497 -305 239 466 640 805 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