File name: Pandora135s1_ManhattanNY-CCNY_20240606_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T214829.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240606_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240606 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240606T144319.3Z 8923.613418 247 1 47.97 2 32.95 113.17 31.15 105.41 0.00 1 0.00 1 0 17 1.649e-02 8.457e-03 4.725e-03 2.582e-03 1.803112e-01 1.322115e-03 2.129942e-03 -6.000000e+00 9.557728e-03 232.45 -2.00 3.51 -2.00 315.92 0.00e+00 7.362386e-04 1.377228e-04 5.091496e-05 -6.000000e+00 4.230346e-04 285.84 -2.00 20.00 -2.00 315.18 0.00e+00 1.191 0.000 302.00 328.00 3 6.6413e+00 3.4599e-03 1.5223e-02 -6.0000e+00 2.3991e-02 5.0504e-02 3.8566e-03 9.3446e-03 -6.0000e+00 2.5980e-02 -8.7752e-04 2.2050e-03 4.5057e-03 -6.0000e+00 1.5445e-02 8.7998e-04 9.9427e-04 1.2848e-03 -6.0000e+00 6.4818e-03 1.7152e-04 -3.7704e-04 7.3667e-05 1.4560e-05 -6.0000e+00 4.4902e-04 1.9915e-02 0.0000e+00 11 8 0 10 0 0 99.96 21.83 0.33 0.01991 0.01708 15 4 1 5 0 3194.820 26.41 20.00 21.83 31.21 25.7 1065.12 224 795 286 -2969 414 -14497 408 -572 1440 -1676 530 -1837 983 2664 -1576 941 1114 1368 1096 1798 165 1875 -4818 1523 696 1171 -258 -324 -1347 -135 1679 313 1729 -2420 -2356 -1650 -1463 626 -599 -185 -840 -230 -1052 -82 75 487 32 -790 -402 679 -277 815 1433 439 1832 1363 392 644 -102 336 1688 1944 1436 1374 -122 -98 -89 -1120 -63 231 -337 476 0 412 442 -957 -1679 -1772 -1211 -1307 -1572 -1539 -1719 -869 -700 -781 271 849 693 620 45 121 -1107 -342 -1107 -551 620 307 305 -38 154 -1096 -106 -650 -557 -266 -269 -225 562 602 754 925 211 9 -201 -578 -334 -545 146 208 663 706 626 1180 219 -2224 214 128 409 170 38 159 -169 98 -411 299 866 581 -181 94 -244 -923 -997 53 200 72 -704 84 -3280 87 -134 360 -441 133 -480 275 826 -547 339 410 533 424 711 67 765 -2055 636 306 524 -114 -139 -542 -52 663 134 771 -1120 -1016 -697 -675 320 -369 -125 -614 -173 -786 -63 57 366 24 -562 -275 459 -197 609 1117 359 1505 1105 324 526 -86 280 1437 1710 1364 1318 -116 -87 -75 -924 -56 220 -339 491 0 406 418 -849 -1349 -1398 -995 -1159 -1504 -1603 -1833 -961 -802 -961 337 1078 877 776 52 130 -1131 -336 -1154 -606 744 392 395 -50 186 -1277 -122 -764 -687 -345 -364 -306 793 895 1128 1376 309 12 -255 -717 -413 -710 197 290 944 992 882 1578 289 -2850 261 158 515 227 51 217 -235 141 -609 461 1364 909 -286 149 -376 -1380 -1514 SS 20240606T144806.6Z 8923.616743 250 1 47.34 2 32.12 114.52 30.29 106.56 0.00 1 0.00 1 0 17 7.547e-03 5.595e-03 4.609e-04 2.836e-04 1.721188e-01 1.456228e-04 2.054696e-03 -6.000000e+00 4.372654e-03 232.45 -2.00 3.51 -2.00 315.44 0.00e+00 2.843788e-04 1.368379e-05 4.523582e-05 -6.000000e+00 1.935630e-04 285.84 -2.00 20.00 -2.00 314.74 0.00e+00 1.180 0.000 302.00 328.00 3 2.5253e+00 3.7937e-04 1.4878e-02 -6.0000e+00 1.0976e-02 2.1525e-02 4.2213e-04 8.9406e-03 -6.0000e+00 1.1887e-02 6.5281e-04 2.4049e-04 4.3199e-03 -6.0000e+00 7.0666e-03 -1.0656e-03 1.0607e-04 1.1742e-03 -6.0000e+00 2.9649e-03 1.0972e-02 -3.0269e-04 8.0230e-06 1.4764e-05 -6.0000e+00 2.0547e-04 2.1253e-02 0.0000e+00 10 0 0 10 0 0 99.97 21.83 0.30 0.02125 0.01898 1221 344 1 5 0 38.330 26.51 20.00 21.83 31.32 25.7 1066.28 71 -812 -1442 -2928 -1772 -1193 1075 1480 506 -1280 -1309 -214 37 690 261 -209 -16 553 632 964 460 536 850 785 589 188 -370 -640 88 621 1423 1715 541 -1569 -1639 -1263 -864 192 -97 -569 -996 -783 -887 -566 -323 -511 -811 -872 -448 319 644 735 1048 661 790 880 552 502 647 1014 1148 1499 1404 850 -276 -233 -448 408 842 489 363 139 146 -38 -5 -274 -479 -478 -380 -785 -1071 -1553 -1721 -1188 -782 -518 -350 -100 6 299 204 12 523 708 349 348 432 -32 32 -297 -459 -527 88 -315 -706 -686 -690 -431 62 295 162 298 119 167 137 425 266 302 249 -66 3 237 305 624 632 100 665 705 358 179 -54 187 -136 -288 -223 6 262 130 -234 -71 -340 -377 -572 21 -250 -441 -831 -442 -284 266 409 154 -406 -404 -66 13 262 101 -86 -7 236 277 433 210 241 387 375 295 97 -186 -300 38 283 668 782 264 -777 -758 -627 -430 111 -62 -415 -784 -637 -683 -469 -265 -416 -641 -664 -328 231 486 588 875 535 650 736 468 422 534 834 978 1364 1372 870 -277 -213 -403 353 727 477 358 142 148 -40 -5 -240 -406 -384 -320 -688 -1047 -1661 -1816 -1306 -918 -609 -433 -127 8 360 241 12 541 709 370 377 515 -39 40 -373 -572 -606 98 -367 -897 -863 -905 -585 88 413 236 429 174 224 178 519 326 389 325 -92 5 335 418 814 834 126 787 838 453 241 -70 247 -183 -404 -331 9 391 199 -361 -107 -497 -565 -847 SS 20240606T145245.4Z 8923.619970 253 1 49.42 2 31.32 115.89 29.47 107.73 0.00 1 0.00 1 0 17 7.497e-03 5.648e-03 1.917e-04 1.236e-04 1.705858e-01 6.377872e-05 2.044110e-03 -6.000000e+00 4.343485e-03 232.45 -2.00 3.51 -2.00 315.26 0.00e+00 3.264975e-04 5.797121e-06 3.517243e-05 -6.000000e+00 1.922761e-04 285.85 -2.00 20.00 -2.00 314.59 0.00e+00 1.170 0.000 302.00 328.00 3 9.8740e-01 1.6571e-04 1.4758e-02 -6.0000e+00 1.0903e-02 1.0777e-02 1.8392e-04 8.8765e-03 -6.0000e+00 1.1808e-02 -1.7741e-04 1.0477e-04 4.2926e-03 -6.0000e+00 7.0195e-03 -1.1871e-04 4.6193e-05 1.1750e-03 -6.0000e+00 2.9450e-03 5.1949e-02 -3.5685e-04 3.4872e-06 1.4923e-05 -6.0000e+00 2.0411e-04 2.1490e-02 0.0000e+00 10 0 0 10 0 0 99.89 21.84 0.26 0.02149 0.01881 3996 1127 1 5 0 11.710 26.51 20.00 21.84 31.51 25.8 1069.58 -16 -657 -1490 -2905 -1977 -1023 804 1346 400 -1461 -1252 -417 58 723 354 -158 97 625 713 1066 476 644 550 769 540 118 -427 -655 75 708 1374 1763 521 -1559 -1641 -1133 -745 96 -81 -634 -971 -706 -866 -500 -349 -473 -817 -758 -467 371 675 782 1005 629 745 825 506 449 704 1004 1186 1439 1328 745 -326 -258 -420 456 858 423 257 93 119 -37 -43 -221 -521 -442 -334 -787 -1066 -1600 -1738 -1232 -793 -613 -396 -170 -2 225 235 15 559 765 338 350 424 131 -65 -289 -463 -461 188 -266 -729 -650 -648 -414 40 263 130 263 134 205 181 525 334 351 224 -63 -52 217 278 614 618 188 725 739 388 194 -80 185 -99 -275 -226 -74 232 37 -270 -73 -353 -357 -575 -5 -207 -468 -922 -553 -272 223 417 125 -476 -396 -133 20 280 153 -73 46 298 349 493 224 298 259 378 279 62 -221 -317 36 330 659 896 262 -795 -846 -574 -413 57 -53 -479 -738 -555 -694 -400 -278 -372 -625 -597 -354 279 527 604 812 530 640 719 447 394 605 860 1053 1366 1270 746 -320 -245 -365 382 772 404 265 100 127 -38 -41 -202 -429 -369 -292 -720 -1020 -1676 -1924 -1338 -920 -719 -488 -215 -3 270 275 17 567 751 351 398 499 160 -83 -361 -571 -524 218 -307 -919 -815 -848 -561 54 369 190 381 185 274 233 635 406 448 292 -88 -71 306 382 802 810 234 852 873 487 244 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