File name: Pandora135s1_ManhattanNY-CCNY_20240613_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T214545.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240613_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240613 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240613T133603.0Z 8930.566701 206 1 15.00 2 45.17 97.07 117.43 50.96 0.00 1 0.00 1 0 17 1.136e-02 6.108e-03 4.837e-03 2.328e-03 2.128891e-01 1.191770e-03 2.536459e-03 -6.000000e+00 6.592222e-03 232.85 -2.00 3.51 -2.00 316.33 0.00e+00 4.646935e-04 1.356449e-04 8.982242e-05 -6.000000e+00 2.921066e-04 286.53 -2.00 20.00 -2.00 315.55 0.00e+00 1.416 0.000 302.00 328.00 3 5.2057e+00 3.1358e-03 1.8107e-02 -6.0000e+00 1.6561e-02 -6.3968e-03 3.4992e-03 1.1109e-02 -6.0000e+00 1.7923e-02 1.3923e-03 2.0106e-03 5.3648e-03 -6.0000e+00 1.0656e-02 -2.3320e-03 9.2660e-04 1.4638e-03 -6.0000e+00 4.4734e-03 5.5547e-04 -3.3950e-04 6.6430e-05 1.6974e-05 -6.0000e+00 3.0913e-04 1.7029e-02 0.0000e+00 12 1 1 12 9 1 -142.86 21.52 0.13 0.01703 0.01448 10 10 1 5 0 1362.430 26.21 20.00 21.52 28.99 25.5 1050.08 969 -1209 -666 -3898 -1485 -8255 962 833 -439 -1407 -1888 -314 246 2089 -1728 1067 -88 1870 469 1612 1467 -69 755 -425 477 545 -244 -1219 -282 -380 718 1131 1256 -1602 -2187 -921 -1251 -102 -874 235 -757 -657 -1420 -924 -357 -349 -195 -857 -191 165 661 496 1761 564 1523 1030 804 749 663 840 956 1613 976 1192 -494 137 -430 402 1088 81 659 341 289 63 453 -673 -688 -1011 -1035 -1414 -1290 -1185 -1989 -1237 -545 -634 -275 29 -104 507 -24 -41 150 473 261 34 638 225 -15 -728 -349 -960 82 -255 -625 -442 -472 -158 218 328 221 570 188 7 143 518 234 -105 233 261 60 73 263 645 606 -357 765 464 380 320 -18 315 -410 -186 -189 -153 338 215 -491 87 -370 -283 -494 181 -248 -136 -756 -260 -1489 168 165 -93 -310 -411 -69 60 566 -527 341 -29 630 166 581 536 -25 281 -162 190 223 -99 -481 -103 -136 267 450 516 -679 -903 -371 -536 -51 -493 145 -512 -448 -998 -649 -249 -242 -135 -579 -125 108 452 351 1298 439 1203 810 642 594 532 672 770 1387 887 1103 -456 118 -352 329 924 74 652 341 289 63 425 -589 -559 -785 -845 -1264 -1252 -1223 -2136 -1347 -617 -751 -342 36 -130 616 -28 -45 154 471 276 37 758 287 -20 -942 -429 -1148 93 -305 -795 -577 -629 -218 308 480 331 850 275 10 189 660 300 -138 321 375 86 106 371 888 812 -459 945 578 493 433 -25 453 -588 -277 -293 -243 536 348 -805 139 -585 -441 -759 SS 20240613T134051.5Z 8930.570041 210 1 49.26 2 44.27 97.97 116.76 52.01 0.00 1 0.00 1 0 17 7.996e-03 5.575e-03 2.072e-04 1.144e-04 2.087572e-01 5.878307e-05 2.490416e-03 -6.000000e+00 4.640708e-03 232.85 -2.00 3.51 -2.00 315.86 0.00e+00 3.617126e-04 6.057089e-06 5.022274e-05 -6.000000e+00 2.056703e-04 286.54 -2.00 20.00 -2.00 315.11 0.00e+00 1.395 0.000 302.00 328.00 3 5.8568e-01 1.5391e-04 1.7792e-02 -6.0000e+00 1.1658e-02 -8.6193e-04 1.7151e-04 1.0882e-02 -6.0000e+00 1.2618e-02 -2.6089e-04 9.7883e-05 5.2595e-03 -6.0000e+00 7.5021e-03 -2.6357e-04 4.4057e-05 1.4334e-03 -6.0000e+00 3.1484e-03 5.7940e-02 -4.6998e-04 3.2341e-06 1.7366e-05 -6.0000e+00 2.1768e-04 1.8716e-02 0.0000e+00 10 0 0 10 0 0 71.57 21.54 0.25 0.01872 0.01518 3764 1062 1 5 0 12.430 26.21 20.01 21.54 29.52 25.6 1054.43 -379 -732 -1834 -3119 -2636 -1649 63 857 19 -1835 -1596 -870 -104 551 396 -145 255 639 865 1030 561 726 869 834 516 231 -469 -620 -66 725 1249 1725 494 -1561 -1803 -1369 -859 -9 28 -595 -858 -648 -715 -426 -227 -369 -764 -698 -472 425 655 815 1048 733 754 909 501 479 657 1006 1189 1475 1421 774 -219 -220 -361 408 854 448 227 77 59 -107 -87 -255 -641 -485 -439 -801 -1074 -1583 -1777 -1296 -825 -606 -383 -166 4 258 276 42 582 769 385 372 426 166 -59 -329 -531 -531 113 -215 -755 -651 -644 -402 85 300 179 277 143 160 174 512 322 337 202 -80 -82 190 233 568 589 181 710 787 412 257 -52 209 -104 -300 -202 -50 246 53 -279 -96 -361 -351 -524 -92 -175 -442 -764 -574 -341 14 208 5 -473 -403 -223 -29 176 142 -56 101 240 334 410 227 290 354 357 233 107 -215 -266 -29 303 545 742 229 -742 -804 -600 -411 -5 17 -397 -620 -486 -548 -327 -173 -280 -566 -500 -328 294 474 629 795 582 613 752 422 400 538 820 1003 1333 1305 751 -210 -193 -308 338 759 425 221 78 59 -104 -83 -232 -528 -405 -361 -741 -1048 -1604 -1911 -1454 -936 -735 -466 -207 5 305 317 46 614 789 396 421 506 206 -77 -421 -666 -614 132 -250 -957 -827 -854 -554 117 434 258 400 207 224 222 646 408 426 275 -112 -116 267 318 774 762 234 868 968 543 343 -72 296 -142 -430 -307 -76 383 84 -447 -150 -547 -536 -789 SS 20240613T134613.4Z 8930.573766 213 1 48.99 2 43.26 99.01 115.99 53.16 0.00 1 0.00 1 0 17 7.892e-03 5.605e-03 2.132e-04 1.198e-04 2.052953e-01 6.158512e-05 2.451160e-03 -6.000000e+00 4.580551e-03 232.85 -2.00 3.51 -2.00 315.79 0.00e+00 3.690826e-04 6.253783e-06 4.996233e-05 -6.000000e+00 2.030124e-04 286.54 -2.00 20.00 -2.00 315.05 0.00e+00 1.371 0.000 302.00 328.00 3 7.0480e-01 1.6123e-04 1.7498e-02 -6.0000e+00 1.1507e-02 -9.9042e-05 1.7959e-04 1.0703e-02 -6.0000e+00 1.2455e-02 -8.9706e-04 1.0235e-04 5.1730e-03 -6.0000e+00 7.4049e-03 -9.5283e-05 4.5975e-05 1.4090e-03 -6.0000e+00 3.1075e-03 5.2955e-02 -4.6793e-04 3.3864e-06 1.7185e-05 -6.0000e+00 2.1487e-04 1.9087e-02 0.0000e+00 10 0 0 10 0 0 66.97 21.56 0.26 0.01909 0.01557 3420 965 1 5 0 13.680 26.21 20.00 21.56 30.19 25.6 1059.42 -175 -845 -1645 -3150 -2313 -1696 240 900 68 -1788 -1512 -733 -166 693 375 -58 159 726 824 1054 483 647 653 793 565 172 -437 -714 119 602 1308 1735 495 -1521 -1821 -1365 -902 48 -29 -596 -894 -620 -761 -414 -250 -387 -771 -693 -443 352 684 805 1071 719 822 874 546 458 678 996 1166 1467 1397 796 -227 -208 -429 412 837 478 269 112 93 -73 -63 -276 -578 -535 -437 -838 -1082 -1604 -1786 -1312 -828 -591 -383 -138 5 272 257 56 521 774 363 368 437 161 -52 -366 -513 -565 93 -264 -770 -674 -632 -404 90 321 171 302 140 172 132 509 280 350 196 -46 -67 206 256 577 589 191 718 754 418 240 -33 208 -94 -265 -199 -48 239 41 -298 -85 -365 -345 -550 -44 -209 -409 -797 -518 -363 53 225 17 -474 -392 -193 -48 226 137 -23 60 278 325 428 199 265 272 346 260 81 -204 -312 52 257 580 758 233 -732 -823 -606 -438 27 -18 -403 -653 -470 -589 -321 -193 -297 -577 -502 -311 245 499 626 818 575 672 728 462 385 558 817 990 1334 1291 776 -219 -183 -368 342 747 454 263 114 94 -75 -60 -251 -476 -447 -360 -776 -1056 -1625 -1919 -1472 -938 -716 -465 -172 7 339 295 62 549 792 373 415 517 199 -68 -466 -641 -650 109 -306 -973 -854 -836 -555 122 463 246 434 201 239 168 638 353 462 265 -63 -95 287 347 781 757 246 874 923 546 318 -45 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