File name: Pandora135s1_ManhattanNY-CCNY_20240616_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T214423.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240616_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240616 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240616T133636.0Z 8933.567084 240 1 11.24 2 45.12 96.91 145.75 28.39 0.00 1 0.00 1 0 17 1.851e-02 7.930e-03 1.186e-02 5.416e-03 2.077959e-01 2.769519e-03 2.435380e-03 -6.000000e+00 1.075279e-02 232.91 -2.00 3.51 -2.00 316.48 0.00e+00 9.260890e-04 3.254970e-04 7.898367e-05 -6.000000e+00 4.768010e-04 286.82 -2.00 20.00 -2.00 315.69 0.00e+00 1.415 0.000 302.00 328.00 3 6.1526e+00 7.2995e-03 1.7878e-02 -6.0000e+00 2.7014e-02 7.7915e-03 8.1533e-03 1.0787e-02 -6.0000e+00 2.9229e-02 5.1279e-03 4.7000e-03 5.1937e-03 -6.0000e+00 1.7380e-02 -3.7020e-03 2.1814e-03 1.5022e-03 -6.0000e+00 7.3022e-03 2.1580e-04 -2.3747e-04 1.5524e-04 1.6055e-05 -6.0000e+00 5.0383e-04 1.3267e-02 0.0000e+00 12 9 1 12 1 1 999.00 21.16 0.37 0.01327 0.01148 2 4 1 5 0 3743.140 25.90 20.00 21.16 25.67 25.4 1026.15 5153 -3742 2133 -5358 1628 -15046 3557 1395 1431 -2890 -3255 -1604 -2669 3014 7 662 100 -1149 1244 -874 2083 815 -139 289 1094 1421 -1748 1553 -472 -1141 -752 2536 2331 -1612 -2094 -577 -1070 582 -228 844 -701 -681 -1862 -1834 -510 616 189 -1205 389 1044 251 917 1218 -144 644 2183 496 513 442 406 1234 2249 1498 1176 -327 -1043 42 -754 187 377 -230 1044 170 -26 1548 682 -529 -1325 164 -547 -2053 -1627 -2162 -870 -415 -884 -98 -202 -859 487 -71 178 45 -403 102 462 718 426 105 -549 -293 69 -203 -605 -545 -874 -744 -292 -64 493 421 523 -378 20 171 210 290 -527 923 305 684 602 428 765 793 -1240 137 1444 299 139 -783 698 -551 -470 -217 273 396 146 15 120 -135 -797 -768 885 -729 406 -1013 256 -2677 557 251 282 -612 -679 -337 -629 764 2 201 32 -378 412 -305 716 281 -49 106 420 558 -695 560 -162 -400 -266 933 918 -663 -810 -216 -442 269 -123 515 -456 -460 -1302 -1290 -353 419 126 -788 251 670 171 639 891 -108 491 1669 391 401 349 321 974 1888 1329 1100 -304 -920 34 -610 156 345 -224 1041 170 -25 1407 578 -420 -1009 129 -472 -1951 -1637 -2317 -939 -477 -1067 -121 -256 -1094 603 -84 194 46 -403 108 517 863 536 139 -716 -365 80 -236 -717 -682 -1159 -1002 -408 -91 722 644 800 -556 28 227 271 374 -698 1265 437 1002 872 603 1055 1064 -1612 172 1789 389 193 -1115 995 -808 -698 -333 437 635 240 25 193 -216 -1238 -1201 SS 20240616T134155.3Z 8933.570779 244 1 27.73 2 44.12 97.91 145.29 30.47 0.00 1 0.00 1 0 17 7.920e-03 5.609e-03 2.305e-04 1.306e-04 2.041813e-01 6.727190e-05 2.439904e-03 -6.000000e+00 4.599893e-03 232.91 -2.00 3.51 -2.00 315.77 0.00e+00 3.623467e-04 6.759406e-06 4.896545e-05 -6.000000e+00 2.039797e-04 286.82 -2.00 20.00 -2.00 315.02 0.00e+00 1.391 0.000 302.00 328.00 3 2.9032e-01 1.7580e-04 1.7616e-02 -6.0000e+00 1.1556e-02 6.5264e-03 1.9563e-04 1.0654e-02 -6.0000e+00 1.2504e-02 -1.6412e-03 1.1181e-04 5.1469e-03 -6.0000e+00 7.4351e-03 3.0760e-04 5.0157e-05 1.4038e-03 -6.0000e+00 3.1235e-03 7.8621e-02 -4.6175e-04 3.6945e-06 1.7056e-05 -6.0000e+00 2.1556e-04 1.3904e-02 0.0000e+00 10 0 0 10 0 0 63.01 21.17 0.28 0.01390 0.01043 2758 778 1 5 0 9.530 25.90 20.00 21.17 26.07 25.5 1030.54 -258 -845 -1639 -3212 -2502 -1645 105 987 150 -1778 -1546 -704 -233 582 357 -135 148 680 768 1100 575 634 536 798 573 182 -394 -724 -54 626 1206 1728 569 -1487 -1811 -1297 -932 93 16 -563 -871 -665 -770 -432 -249 -400 -708 -688 -452 358 712 775 1076 681 777 883 546 470 715 1019 1212 1514 1445 853 -236 -200 -402 352 830 373 195 42 52 -95 -69 -237 -535 -466 -346 -774 -1064 -1563 -1796 -1329 -882 -629 -441 -211 -66 174 232 -4 517 750 384 336 438 173 -57 -318 -468 -518 165 -173 -738 -657 -644 -436 28 294 137 267 117 183 152 513 321 359 234 -35 -80 222 273 572 650 205 718 814 434 230 -39 180 -135 -231 -225 -68 223 51 -279 -101 -369 -378 -548 -61 -215 -419 -769 -579 -361 24 252 39 -484 -412 -190 -69 194 133 -50 57 266 310 457 243 265 228 355 269 88 -188 -324 -22 272 502 768 273 -731 -836 -586 -458 50 10 -386 -647 -480 -569 -320 -183 -293 -539 -506 -322 253 527 611 833 552 644 745 469 400 597 847 1041 1309 1349 841 -231 -179 -350 296 746 358 192 43 53 -94 -67 -219 -448 -369 -286 -721 -1046 -1595 -1947 -1424 -1008 -731 -540 -265 -83 209 270 -4 521 774 397 382 521 215 -74 -409 -562 -602 193 -201 -938 -837 -857 -573 39 425 199 386 169 244 194 649 407 453 317 -48 -114 312 373 781 842 266 879 1000 569 306 -54 255 -185 -329 -325 -103 345 81 -445 -158 -557 -577 -823 SS 20240616T134223.2Z 8933.571102 244 2 27.58 2 44.03 98.00 145.25 30.65 0.00 1 0.00 1 0 17 7.871e-03 5.583e-03 2.268e-04 1.294e-04 2.040363e-01 6.664575e-05 2.437864e-03 -6.000000e+00 4.571428e-03 232.91 -2.00 3.51 -2.00 315.73 0.00e+00 3.649225e-04 6.657236e-06 4.594694e-05 -6.000000e+00 2.027180e-04 286.82 -2.00 20.00 -2.00 314.99 0.00e+00 1.389 0.000 302.00 328.00 3 2.7492e-01 1.7407e-04 1.7594e-02 -6.0000e+00 1.1485e-02 6.7461e-03 1.9374e-04 1.0647e-02 -6.0000e+00 1.2427e-02 -1.9568e-03 1.1073e-04 5.1410e-03 -6.0000e+00 7.3891e-03 4.7873e-04 4.9690e-05 1.4015e-03 -6.0000e+00 3.1042e-03 8.0020e-02 -4.6713e-04 3.6652e-06 1.7188e-05 -6.0000e+00 2.1422e-04 1.3938e-02 0.0000e+00 10 0 0 10 0 0 55.42 21.17 0.27 0.01394 0.01043 2758 778 1 5 0 9.530 25.90 20.00 21.17 26.20 25.5 1030.54 -222 -882 -1635 -3169 -2411 -1701 84 927 127 -1689 -1631 -688 -191 631 357 -111 187 645 808 1137 556 621 585 835 617 195 -379 -708 -22 620 1292 1684 572 -1471 -1811 -1300 -920 98 -27 -574 -911 -634 -783 -439 -245 -389 -716 -656 -450 367 700 795 1049 673 733 845 511 460 701 1016 1194 1513 1425 836 -251 -204 -392 344 829 400 206 58 44 -71 -70 -201 -543 -453 -336 -756 -1038 -1546 -1793 -1299 -898 -645 -432 -207 -58 190 233 9 530 780 377 331 438 183 -51 -310 -465 -504 156 -161 -750 -655 -651 -421 32 271 134 278 119 172 149 529 337 381 238 -62 -80 201 266 551 615 182 714 809 425 238 -53 186 -145 -217 -222 -73 211 43 -299 -91 -351 -364 -535 -53 -226 -422 -766 -563 -377 20 239 33 -464 -439 -187 -57 212 135 -42 72 255 329 476 237 262 251 375 292 95 -182 -319 -9 272 542 755 277 -729 -842 -592 -456 53 -18 -396 -682 -461 -583 -327 -182 -287 -549 -487 -324 262 521 591 819 550 613 719 442 395 589 851 1033 1318 1341 784 -248 -184 -343 292 751 387 205 60 45 -71 -69 -176 -457 -361 -280 -667 -1027 -1589 -1958 -1401 -1034 -754 -533 -262 -73 229 273 10 538 811 392 378 524 229 -67 -402 -562 -590 174 -188 -912 -841 -872 -558 44 377 195 405 166 231 192 673 429 484 326 -86 -115 284 365 758 801 226 881 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