File name: Pandora135s1_ManhattanNY-CCNY_20240623_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T213440.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240623_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240623T133816.4Z 8940.568246 331 1 46.04 2 45.07 96.90 120.99 259.63 0.00 1 0.00 1 0 17 2.154e-02 8.530e-03 4.871e-03 2.374e-03 1.899084e-01 1.210111e-03 2.231166e-03 -6.000000e+00 1.248829e-02 232.90 -2.00 3.51 -2.00 316.35 0.00e+00 4.997829e-04 1.383482e-04 6.153097e-05 -6.000000e+00 5.565165e-04 287.48 -2.00 20.00 -2.00 315.55 0.00e+00 1.414 0.000 302.00 328.00 3 6.2534e+00 3.1865e-03 1.7288e-02 -6.0000e+00 3.1362e-02 1.4553e-02 3.5600e-03 9.8685e-03 -6.0000e+00 3.3959e-02 7.1272e-03 2.0434e-03 4.7456e-03 -6.0000e+00 2.0200e-02 -3.8593e-03 9.3652e-04 1.3045e-03 -6.0000e+00 8.4670e-03 2.0284e-04 -2.9422e-04 6.8032e-05 1.4779e-05 -6.0000e+00 5.8693e-04 3.0662e-02 0.0000e+00 11 8 0 10 0 0 99.88 22.30 0.14 0.03066 0.02845 18 5 1 5 0 2557.430 26.83 20.00 22.30 32.96 26.0 1075.31 902 -1329 -1354 -3307 723 -13983 689 -424 945 -1674 -2566 -2307 1475 2484 -1682 -188 1329 112 1038 757 -328 471 17550 1060 -873 731 -215 -431 -1485 -383 1112 242 1084 -2281 -3007 -1439 -969 574 -321 -595 -1032 -1343 -868 -782 -276 167 -928 -1124 -1067 447 33 -12 1045 434 1800 1769 33 492 -189 590 1275 1840 1473 949 -224 -571 -211 -239 909 713 451 512 403 332 347 -761 -1125 -1554 -919 -820 -1700 -1312 -1738 -818 -735 -76 144 492 -77 911 175 238 -191 63 -512 -85 635 326 -36 -92 -153 -685 -56 -854 -593 -642 -748 -308 93 554 450 576 160 -257 216 -330 -99 -230 115 98 413 537 330 1097 592 -1770 687 493 438 336 -18 236 -324 -285 -213 43 440 299 -120 86 -120 -476 -780 179 -286 -288 -654 128 -2666 126 -85 204 -378 -572 -528 360 679 -533 -60 431 39 357 269 -119 168 5569 402 -354 298 -86 -166 -542 -136 406 95 450 -969 -1202 -564 -418 278 -181 -382 -691 -934 -612 -553 -193 116 -649 -760 -700 290 23 -9 765 332 1388 1389 26 391 -149 463 1034 1595 1335 900 -208 -499 -169 -188 767 657 450 511 400 327 316 -646 -894 -1185 -737 -713 -1608 -1346 -1831 -896 -839 -92 179 623 -98 1122 205 260 -191 64 -534 -94 748 421 -47 -121 -187 -797 -63 -1021 -745 -849 -1005 -428 131 822 675 881 233 -355 279 -418 -126 -300 157 142 611 781 467 1513 779 -2258 838 609 577 456 -25 338 -460 -422 -325 68 716 484 -195 140 -189 -749 -1216 SS 20240623T134322.6Z 8940.571789 335 1 48.57 2 44.11 97.86 121.89 260.34 0.00 1 0.00 1 0 17 7.711e-03 5.613e-03 2.325e-04 1.387e-04 1.871253e-01 7.137771e-05 2.229388e-03 -6.000000e+00 4.469359e-03 232.90 -2.00 3.51 -2.00 315.59 0.00e+00 3.071815e-04 6.965497e-06 5.488876e-05 -6.000000e+00 1.992172e-04 287.48 -2.00 20.00 -2.00 314.84 0.00e+00 1.391 0.000 302.00 328.00 3 1.0152e+00 1.8629e-04 1.7035e-02 -6.0000e+00 1.1224e-02 -6.5900e-03 2.0712e-04 9.7495e-03 -6.0000e+00 1.2154e-02 1.6926e-04 1.1828e-04 4.6988e-03 -6.0000e+00 7.2297e-03 -3.8021e-04 5.2707e-05 1.2734e-03 -6.0000e+00 3.0296e-03 3.9773e-02 -3.1472e-04 3.9218e-06 1.5670e-05 -6.0000e+00 2.1011e-04 3.2264e-02 0.0000e+00 10 0 0 10 0 0 97.94 22.31 0.26 0.03226 0.02990 2563 723 1 5 0 18.260 26.83 20.00 22.31 33.25 26.1 1077.92 140 -446 -1396 -2912 -2167 -1389 679 1278 439 -1444 -1331 -510 -10 733 407 -158 98 584 719 1045 380 573 727 834 688 336 -267 -563 38 588 1369 1702 513 -1645 -1962 -1556 -994 -26 -154 -624 -961 -746 -862 -525 -375 -508 -838 -868 -606 258 561 722 968 599 711 789 469 374 561 899 1106 1513 1476 920 -118 -201 -412 442 940 598 427 241 263 43 -7 -294 -670 -674 -543 -871 -1122 -1589 -1685 -1195 -689 -402 -163 67 194 400 317 24 370 557 239 321 430 166 32 -306 -606 -670 -68 -444 -759 -712 -649 -480 40 318 263 356 179 128 49 290 184 235 230 -20 48 248 300 645 596 123 544 560 343 213 -28 165 -134 -328 -162 26 300 129 -186 -38 -315 -394 -659 36 -123 -385 -742 -535 -330 169 357 124 -422 -379 -148 -3 263 163 -62 40 240 304 454 167 250 323 389 337 168 -131 -257 17 263 637 779 252 -816 -912 -719 -506 -15 -101 -438 -726 -582 -687 -417 -297 -398 -639 -639 -431 183 417 570 799 484 586 661 399 316 464 744 951 1394 1375 897 -113 -185 -349 365 839 567 439 242 277 44 -7 -263 -580 -558 -475 -804 -1088 -1685 -1782 -1321 -771 -481 -205 82 236 486 375 26 381 560 256 357 500 212 40 -396 -730 -787 -78 -535 -944 -931 -842 -646 57 448 385 516 247 170 63 351 224 302 303 -28 68 352 413 844 780 153 678 706 437 289 -38 224 -184 -474 -236 40 468 196 -285 -59 -477 -577 -956 SS 20240623T134846.4Z 8940.575537 338 1 47.16 2 43.10 98.89 122.85 261.10 0.00 1 0.00 1 0 17 7.880e-03 5.512e-03 6.809e-04 3.617e-04 1.847618e-01 1.848937e-04 2.194254e-03 -6.000000e+00 4.567584e-03 232.90 -2.00 3.51 -2.00 316.02 0.00e+00 2.845591e-04 1.956905e-05 7.889996e-05 -6.000000e+00 2.035770e-04 287.48 -2.00 20.00 -2.00 315.24 0.00e+00 1.368 0.000 302.00 328.00 3 2.7156e+00 4.8518e-04 1.6773e-02 -6.0000e+00 1.1471e-02 4.5569e-03 5.4099e-04 9.6193e-03 -6.0000e+00 1.2421e-02 2.0741e-03 3.0832e-04 4.6342e-03 -6.0000e+00 7.3884e-03 -1.8942e-03 1.3921e-04 1.2523e-03 -6.0000e+00 3.0964e-03 7.4253e-03 -2.1381e-04 1.0266e-05 1.4845e-05 -6.0000e+00 2.1471e-04 3.1720e-02 0.0000e+00 10 0 0 10 0 0 99.99 22.32 0.26 0.03172 0.03011 1142 322 1 5 0 40.960 26.94 20.00 22.32 33.64 26.1 1081.12 -216 -389 -1584 -2925 -1907 -1452 1190 1360 533 -1627 -1157 -594 330 737 236 -281 -111 644 500 980 183 610 966 870 548 304 -310 -616 151 624 1431 1601 605 -1835 -1915 -1630 -875 -45 -98 -734 -1070 -860 -942 -626 -476 -502 -1098 -859 -667 380 468 860 1041 733 778 863 443 365 611 864 1154 1478 1546 985 -133 -251 -435 500 928 672 414 240 206 152 -20 -227 -693 -721 -503 -828 -1074 -1609 -1599 -1102 -638 -386 -138 31 198 365 196 -39 276 614 178 379 421 -43 8 -304 -663 -680 -97 -446 -743 -711 -666 -494 92 354 306 361 216 147 40 299 96 209 204 -57 57 267 330 646 560 43 488 550 353 192 -18 119 -76 -410 -148 9 322 141 -131 33 -271 -386 -600 -49 -93 -380 -647 -373 -274 235 302 130 -413 -285 -150 91 228 81 -104 -42 247 198 397 75 248 399 378 250 142 -142 -262 59 240 571 681 275 -846 -824 -698 -412 -23 -59 -505 -731 -607 -678 -450 -339 -355 -819 -617 -464 263 340 660 772 566 613 692 361 294 483 684 948 1301 1461 973 -128 -220 -351 393 789 645 399 239 203 156 -19 -193 -579 -576 -424 -725 -1048 -1596 -1672 -1204 -745 -482 -169 39 246 462 229 -41 285 619 191 415 508 -54 10 -381 -829 -785 -108 -528 -957 -901 -881 -677 132 532 448 524 317 199 53 374 121 277 273 -81 83 383 459 856 755 55 593 677 463 268 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