File name: Pandora135s1_ManhattanNY-CCNY_20240706_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240707T050852.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240706_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240706T134350.9Z 8953.572117 181 1 47.86 2 44.97 98.41 50.24 87.97 0.00 1 0.00 1 0 17 1.275e-02 6.319e-03 3.808e-03 1.897e-03 1.997836e-01 9.926982e-04 2.402285e-03 -6.000000e+00 7.539834e-03 232.89 -2.00 3.51 -2.00 316.16 0.00e+00 2.406555e-04 1.083072e-04 9.102569e-05 -6.000000e+00 3.331193e-04 288.71 -2.00 20.00 -2.00 315.39 0.00e+00 1.411 0.000 302.00 328.00 3 5.8699e+00 2.5986e-03 1.7669e-02 -6.0000e+00 1.8940e-02 3.0005e-02 2.8767e-03 1.0477e-02 -6.0000e+00 2.0363e-02 -9.6778e-04 1.6649e-03 5.0648e-03 -6.0000e+00 1.2116e-02 -9.0536e-04 7.8414e-04 1.3888e-03 -6.0000e+00 5.2423e-03 2.8924e-04 -8.0467e-05 5.4023e-05 1.6572e-05 -6.0000e+00 3.4766e-04 -3.1280e-02 2.1940e-04 11 1 0 11 8 0 99.95 21.86 0.09 -0.03128 -0.03188 22 6 1 5 0 2175.140 26.51 20.00 21.86 32.75 26.1 1072.17 -174 -1264 -43 -2374 739 -9868 1035 359 1113 -2231 -1363 -1160 -225 2121 -1582 883 725 534 374 -110 256 687 5677 330 169 378 649 447 -1195 -1 982 1301 1210 -2351 -2419 -1853 -563 -12 -740 -507 -814 -457 -772 -868 -465 -166 -366 -1105 -515 365 545 529 1170 435 1288 795 90 161 256 679 1156 1709 1128 1208 0 -232 -189 -187 757 -76 591 437 455 369 381 -134 -1197 -1252 -660 -1123 -1413 -1340 -1853 -857 -703 -177 -16 57 76 690 296 -383 -36 474 11 -125 744 677 -21 -179 -425 -592 -157 -776 -639 -601 -721 -290 72 725 422 521 153 -29 -61 77 70 -172 321 -22 309 249 278 762 248 134 -81 383 416 31 -299 159 -73 -272 -266 301 495 256 -174 -190 -248 -950 -35 -273 -9 -492 132 -1884 189 74 251 -533 -316 -274 -58 585 -506 295 249 189 137 -42 97 258 2066 133 69 158 275 177 -447 0 367 518 514 -1034 -995 -748 -246 -6 -426 -323 -560 -326 -563 -635 -338 -119 -256 -751 -349 245 372 384 886 336 1006 636 73 130 203 552 940 1484 1030 1153 0 -206 -158 -153 642 -71 579 444 459 369 354 -115 -966 -993 -530 -984 -1344 -1390 -1986 -954 -813 -213 -21 72 96 847 346 -419 -36 482 11 -140 889 864 -28 -235 -534 -706 -180 -940 -815 -786 -985 -400 103 1069 633 779 223 -40 -79 97 88 -229 445 -32 456 363 393 1051 327 171 -102 483 541 42 -422 227 -103 -401 -405 478 786 416 -284 -304 -393 -1461 SS 20240706T134950.6Z 8953.576280 185 1 45.20 2 43.85 99.57 49.14 88.90 0.00 1 0.00 1 0 17 8.562e-03 5.682e-03 2.354e-03 1.272e-03 1.927055e-01 6.662788e-04 2.326153e-03 -6.000000e+00 5.062667e-03 232.89 -2.00 3.51 -2.00 315.89 0.00e+00 4.684395e-04 6.867855e-05 7.774731e-05 -6.000000e+00 2.236914e-04 288.71 -2.00 20.00 -2.00 315.14 0.00e+00 1.385 0.000 302.00 328.00 3 5.1516e+00 1.7402e-03 1.7230e-02 -6.0000e+00 1.2717e-02 2.0585e-02 1.9242e-03 1.0119e-02 -6.0000e+00 1.3673e-02 7.7696e-04 1.1085e-03 4.8923e-03 -6.0000e+00 8.1359e-03 -1.0498e-03 5.1559e-04 1.3559e-03 -6.0000e+00 3.5196e-03 6.1915e-04 -6.1120e-05 3.6087e-05 1.6264e-05 -6.0000e+00 2.3347e-04 -3.0921e-02 2.0208e-04 12 1 1 12 9 1 99.99 21.88 0.12 -0.03092 -0.03138 41 12 1 5 0 1075.980 26.51 20.00 21.88 33.09 26.2 1074.77 -677 -41 -1135 -1363 -778 -4934 -157 782 903 -1050 -1449 -1134 909 995 -69 -316 943 450 390 1078 717 1259 -331 1395 404 859 -736 10 -303 116 1439 1252 1067 -1645 -2138 -1830 -1257 -749 -90 -606 -771 -1095 -592 -562 53 -327 -540 -803 -926 350 36 610 792 641 841 983 263 323 401 668 1199 1402 1526 1000 96 -88 -442 -52 577 695 492 500 441 235 -85 -218 -1049 -1025 -1020 -1046 -1148 -1455 -1640 -1187 -481 -554 109 200 333 503 304 -130 331 349 -32 284 481 328 90 -173 -587 -818 -366 -623 -670 -505 -723 -404 68 401 418 456 354 5 36 54 272 81 299 29 218 357 313 595 356 -429 215 534 279 232 -32 123 -107 -326 -85 121 342 10 -202 -91 -398 -627 -158 -10 -282 -312 -158 -1000 -32 179 226 -275 -372 -297 257 307 -24 -114 345 170 151 429 289 500 -136 590 181 392 -334 4 -123 46 585 545 478 -756 -954 -804 -583 -394 -55 -407 -542 -801 -440 -419 39 -240 -398 -572 -640 239 26 464 612 517 692 821 217 273 332 552 1022 1244 1416 975 92 -79 -376 -43 497 655 490 516 452 233 -80 -191 -882 -819 -856 -954 -1104 -1490 -1778 -1309 -550 -662 136 251 425 615 351 -144 341 349 -34 321 570 415 116 -224 -730 -964 -426 -744 -846 -654 -981 -554 94 589 624 679 513 7 48 67 338 106 410 41 311 515 438 814 475 -547 265 661 359 310 -44 174 -150 -477 -127 186 539 17 -321 -144 -612 -953 SS 20240706T135858.9Z 8953.582626 191 1 21.35 2 42.15 101.41 47.46 90.35 0.00 1 0.00 1 0 17 7.907e-03 5.956e-03 9.623e-04 5.761e-04 1.864933e-01 3.027036e-04 2.258654e-03 -6.000000e+00 4.674612e-03 232.89 -2.00 3.51 -2.00 315.53 0.00e+00 3.338566e-04 2.914386e-05 7.948382e-05 -6.000000e+00 2.065803e-04 288.71 -2.00 20.00 -2.00 314.81 0.00e+00 1.347 0.000 302.00 328.00 3 3.0505e+00 7.8697e-04 1.6728e-02 -6.0000e+00 1.1742e-02 -7.0466e-03 8.6860e-04 9.7851e-03 -6.0000e+00 1.2626e-02 -1.5577e-04 4.9886e-04 4.7350e-03 -6.0000e+00 7.5128e-03 3.2072e-04 2.2844e-04 1.3024e-03 -6.0000e+00 3.2493e-03 5.3820e-03 2.3056e-05 1.6283e-05 1.5987e-05 -6.0000e+00 2.1564e-04 -2.9924e-02 1.8200e-04 12 1 1 12 1 1 99.95 21.91 0.23 -0.02992 -0.02975 145 90 1 5 0 146.170 26.51 20.00 21.91 33.69 26.2 1079.23 468 -134 -1117 -1963 -1922 -2002 63 1416 632 -1169 -1913 -982 -233 532 478 -367 160 493 935 949 870 564 379 846 774 533 -59 -374 -147 486 1181 1592 654 -1375 -2069 -1930 -1569 -601 -225 -622 -980 -684 -670 -549 -310 -421 -741 -848 -653 15 407 698 988 740 751 904 623 370 671 825 1040 1447 1498 1142 220 -201 -572 127 651 733 625 411 445 163 113 -374 -922 -1025 -947 -1065 -1135 -1563 -1735 -1303 -837 -429 -167 100 261 488 370 -135 125 253 45 305 456 472 260 -108 -606 -896 -412 -554 -682 -715 -583 -490 96 456 488 562 313 89 -101 63 59 179 328 200 234 320 316 537 528 -32 254 371 340 311 1 136 -296 -474 -74 97 296 99 -136 -125 -446 -666 130 -37 -306 -542 -473 -474 16 388 191 -338 -544 -282 -73 187 188 -155 69 217 389 407 378 243 166 388 372 263 -28 -170 -67 215 541 776 315 -673 -1032 -952 -783 -350 -144 -427 -726 -525 -524 -430 -241 -325 -557 -616 -458 11 297 540 799 625 648 743 519 307 581 714 875 1303 1450 1090 206 -183 -511 110 567 720 626 428 460 162 111 -331 -788 -835 -810 -958 -1139 -1617 -1899 -1408 -966 -500 -205 125 326 583 431 -151 126 265 47 349 544 585 337 -136 -758 -1036 -486 -651 -871 -913 -776 -677 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