File name: Pandora135s1_ManhattanNY-CCNY_20240707_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T224042.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240707_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240707 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240707T140518.9Z 8954.587025 218 1 18.65 2 41.07 102.82 57.67 86.50 0.00 1 0.00 1 0 17 1.220e-02 8.186e-03 7.584e-03 3.939e-03 1.892648e-01 2.013837e-03 2.208947e-03 -6.000000e+00 7.071137e-03 232.89 -2.00 3.51 -2.00 316.11 0.00e+00 4.612446e-04 2.197391e-04 1.095337e-04 -6.000000e+00 3.170674e-04 288.80 -2.00 20.00 -2.00 315.31 0.00e+00 1.325 0.000 302.00 328.00 3 6.3047e+00 5.2829e-03 1.6535e-02 -6.0000e+00 1.7749e-02 3.3127e-02 5.8977e-03 9.7424e-03 -6.0000e+00 1.9218e-02 2.4567e-03 3.3780e-03 4.6841e-03 -6.0000e+00 1.1440e-02 -1.5025e-03 1.5355e-03 1.2680e-03 -6.0000e+00 4.7990e-03 2.0863e-04 -3.8987e-04 1.1238e-04 1.4642e-05 -6.0000e+00 3.3256e-04 3.4187e-02 0.0000e+00 12 9 1 12 9 1 99.94 22.47 0.23 0.03419 0.03126 5 4 1 5 0 3106.790 27.05 20.00 22.47 35.22 26.0 1088.13 526 -1698 -1328 -100 -2986 -6446 -202 214 -370 -1116 -612 -2985 1200 2530 1485 -788 3366 307 1116 309 529 891 -892 304 700 -69 -1704 -387 -1665 259 1021 1538 -113 -2462 -3471 -1797 -1050 -264 -467 91 -847 -1147 619 108 948 -66 253 -1231 -251 968 -650 962 834 841 1182 1981 -506 -414 364 1582 2169 2124 1427 789 218 -793 -981 -790 -516 394 -65 734 430 819 224 44 -1637 -2360 -1955 -1245 -2398 -1286 -2198 -427 -378 -343 249 857 122 668 541 -585 -446 4 -890 315 470 615 90 -89 -502 -561 -555 -727 -670 -384 -622 -157 526 1070 1000 345 58 19 204 -473 -332 -105 725 -167 363 1002 661 1020 -108 -1621 -411 -128 -54 223 -530 400 -241 -244 -169 127 1062 562 86 375 -339 -1036 -830 113 -393 -302 -21 -582 -1260 -40 47 -89 -276 -147 -757 323 734 484 -279 1170 113 419 121 207 344 -358 127 294 -30 -750 -156 -635 95 390 625 -49 -1089 -1448 -736 -473 -135 -275 60 -591 -830 448 79 681 -48 181 -862 -169 647 -464 696 633 663 947 1603 -424 -343 294 1265 1795 1835 1333 749 206 -690 -809 -640 -453 374 -65 751 437 795 208 37 -1328 -1846 -1613 -1109 -2332 -1307 -2376 -463 -439 -415 315 1074 153 816 625 -633 -453 4 -945 353 563 783 120 -115 -621 -659 -634 -854 -853 -499 -844 -215 748 1559 1512 521 83 27 265 -586 -414 -138 989 -238 525 1420 935 1372 -143 -2066 -506 -159 -70 296 -733 555 -341 -352 -259 197 1674 907 141 593 -522 -1588 -1254 SS 20240707T140922.8Z 8954.589848 221 1 15.27 2 40.32 103.69 56.93 87.13 0.00 1 0.00 1 0 17 9.399e-03 6.193e-03 2.040e-03 1.206e-03 1.806535e-01 6.207722e-04 2.134756e-03 -6.000000e+00 5.445466e-03 232.89 -2.00 3.51 -2.00 315.65 0.00e+00 4.631658e-04 6.152194e-05 5.705500e-05 -6.000000e+00 2.442228e-04 288.80 -2.00 20.00 -2.00 314.88 0.00e+00 1.310 0.000 302.00 328.00 3 4.1825e+00 1.6209e-03 1.6174e-02 -6.0000e+00 1.3668e-02 1.3116e-02 1.8049e-03 9.3745e-03 -6.0000e+00 1.4800e-02 4.1173e-03 1.0291e-03 4.5098e-03 -6.0000e+00 8.8105e-03 -3.1593e-03 4.5657e-04 1.2325e-03 -6.0000e+00 3.6952e-03 1.8149e-03 -1.9233e-04 3.4204e-05 1.4819e-05 -6.0000e+00 2.5616e-04 3.5314e-02 0.0000e+00 12 1 1 12 9 1 99.98 22.47 0.23 0.03531 0.03387 44 39 1 5 0 339.140 27.05 20.00 22.47 35.26 26.0 1088.13 130 -838 -1476 -2444 -2038 -1559 572 1335 346 -2049 -2171 -826 -409 670 -83 -126 46 250 861 707 876 543 5697 675 678 35 -559 -736 -431 236 1142 1486 354 -1770 -2204 -1755 -1070 174 -326 -556 -827 -855 -702 -606 -359 -474 -578 -922 -605 51 497 489 897 808 635 1036 490 630 350 1213 1363 1586 1547 945 -93 -271 -325 99 766 514 366 156 261 97 114 -329 -771 -889 -783 -1059 -1387 -1611 -1736 -1107 -444 -390 -45 9 234 435 222 -230 311 374 134 315 556 42 282 -342 -665 -762 -147 -544 -739 -560 -709 -345 5 351 411 434 311 -39 111 181 181 287 414 -109 11 263 485 758 633 -54 479 509 267 96 -108 190 -185 -285 -187 37 348 230 -160 -69 -150 -568 -636 34 -233 -407 -618 -501 -370 143 341 97 -598 -618 -239 -130 238 -33 -49 18 101 357 302 377 232 2358 308 324 17 -267 -327 -193 103 517 716 168 -848 -1072 -850 -527 100 -208 -402 -599 -640 -535 -462 -272 -355 -450 -694 -440 37 377 393 704 659 528 874 419 533 292 1007 1178 1471 1443 921 -88 -249 -274 82 685 486 374 164 272 97 106 -292 -664 -734 -684 -972 -1330 -1682 -1911 -1198 -512 -481 -55 11 290 543 255 -255 312 367 140 361 661 51 360 -425 -814 -863 -171 -635 -936 -704 -931 -469 7 496 601 628 451 -52 143 221 223 373 547 -154 16 373 665 989 831 -67 567 611 341 130 -144 255 -254 -409 -268 55 535 361 -252 -106 -223 -865 -959 SS 20240707T141345.9Z 8954.592892 224 1 47.54 2 39.52 104.65 56.13 87.81 0.00 1 0.00 1 0 17 7.695e-03 5.517e-03 6.312e-04 3.430e-04 1.785760e-01 1.764487e-04 2.130069e-03 -6.000000e+00 4.458093e-03 232.89 -2.00 3.51 -2.00 315.90 0.00e+00 3.109516e-04 1.833482e-05 7.234098e-05 -6.000000e+00 1.999513e-04 288.80 -2.00 20.00 -2.00 315.11 0.00e+00 1.295 0.000 302.00 328.00 3 2.6716e+00 4.6172e-04 1.6019e-02 -6.0000e+00 1.1190e-02 7.1057e-03 5.1448e-04 9.3162e-03 -6.0000e+00 1.2117e-02 3.5881e-03 2.9366e-04 4.4936e-03 -6.0000e+00 7.2131e-03 -2.2990e-03 1.3255e-04 1.2189e-03 -6.0000e+00 3.0251e-03 8.4080e-03 -1.6412e-04 9.8391e-06 1.4965e-05 -6.0000e+00 2.0972e-04 3.5624e-02 0.0000e+00 10 0 0 10 0 0 99.99 22.48 0.28 0.03562 0.03439 1390 392 1 5 0 33.660 27.05 20.00 22.48 35.34 26.1 1089.66 286 -483 -1254 -2850 -1821 -879 1039 1651 335 -1327 -1283 -206 36 1091 265 -162 65 530 663 847 412 461 -1365 730 663 220 -251 -610 136 803 1405 1634 355 -1775 -1983 -1418 -898 122 -64 -624 -962 -684 -836 -484 -294 -517 -763 -932 -528 313 629 711 1051 621 754 872 477 453 611 1038 1149 1642 1499 984 -214 -290 -455 409 937 517 392 200 214 31 -43 -355 -739 -732 -557 -878 -1134 -1597 -1676 -1112 -663 -369 -144 112 148 344 221 -100 295 460 200 266 485 262 92 -298 -593 -689 -3 -470 -785 -674 -637 -415 76 385 296 418 178 149 18 217 116 184 196 -62 113 242 357 588 572 18 519 490 297 157 -102 169 -198 -406 -186 73 324 183 -129 -9 -289 -379 -625 67 -121 -310 -650 -368 -171 213 378 85 -346 -326 -53 10 346 94 -61 25 207 267 350 172 191 -587 323 307 104 -116 -262 54 311 566 700 163 -820 -856 -609 -426 68 -39 -431 -713 -522 -600 -376 -226 -395 -566 -666 -364 215 453 543 838 476 589 692 384 361 517 879 935 1430 1402 959 -203 -249 -391 342 785 489 399 211 223 31 -40 -296 -604 -572 -461 -754 -1085 -1668 -1845 -1187 -757 -450 -184 146 191 424 251 -111 296 452 209 305 569 337 123 -386 -716 -769 -3 -541 -984 -887 -875 -550 105 561 446 623 251 208 22 261 141 236 271 -86 159 335 513 804 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