File name: Pandora135s1_ManhattanNY-CCNY_20240721_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240722T051056.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240721_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240721 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240721T134426.5Z 8968.572529 341 1 48.57 2 46.53 100.79 134.31 273.86 0.00 1 0.00 1 0 17 7.675e-03 5.442e-03 3.119e-04 1.583e-04 2.149393e-01 8.292105e-05 2.588276e-03 -6.000000e+00 4.531262e-03 232.65 -2.00 3.51 -2.00 316.09 0.00e+00 3.280147e-04 8.933226e-06 7.926772e-05 -6.000000e+00 2.013044e-04 289.65 -2.00 20.00 -2.00 315.30 0.00e+00 1.451 0.000 302.00 328.00 3 1.0586e+00 2.1668e-04 1.8481e-02 -6.0000e+00 1.1371e-02 -6.5395e-03 2.3998e-04 1.1248e-02 -6.0000e+00 1.2230e-02 -4.8726e-04 1.3886e-04 5.4498e-03 -6.0000e+00 7.2828e-03 2.8989e-04 6.5119e-05 1.5035e-03 -6.0000e+00 3.1518e-03 3.3632e-02 1.3978e-04 4.4976e-06 1.7868e-05 -6.0000e+00 2.0940e-04 -2.4526e-02 2.1588e-04 10 0 0 10 0 0 99.98 21.97 0.26 -0.02453 -0.02348 2827 797 1 5 0 16.550 26.51 20.00 21.97 31.92 26.3 1063.90 -253 -573 -1359 -2801 -2133 -1685 97 847 23 -1668 -1591 -825 -394 512 302 -148 230 593 781 1036 530 615 339 793 673 340 -192 -438 60 574 1166 1570 326 -1669 -1889 -1593 -1175 -247 -252 -637 -871 -596 -677 -366 -247 -337 -729 -740 -444 360 618 771 975 659 797 867 523 467 648 945 1148 1509 1457 924 -100 -141 -382 407 775 457 326 176 188 9 -22 -324 -725 -732 -629 -966 -1122 -1614 -1715 -1234 -745 -458 -236 21 150 365 318 24 407 623 245 356 499 218 19 -303 -582 -654 -30 -391 -791 -694 -638 -456 101 366 277 377 174 151 81 377 250 311 284 -13 41 226 280 534 459 -22 464 600 357 226 -44 148 -140 -329 -176 15 289 79 -280 -174 -451 -513 -53 -128 -305 -584 -396 -301 18 179 5 -405 -379 -201 -107 143 95 -50 80 212 287 392 204 234 132 325 290 150 -84 -178 23 213 453 654 147 -762 -809 -677 -549 -125 -152 -409 -605 -428 -497 -269 -180 -245 -518 -508 -296 241 434 577 766 506 624 693 425 376 511 745 939 1324 1294 862 -92 -126 -316 329 677 424 327 183 194 9 -21 -285 -619 -599 -510 -883 -1075 -1697 -1797 -1351 -872 -540 -292 27 189 438 373 25 418 627 264 397 616 279 25 -396 -708 -776 -34 -473 -984 -909 -873 -614 141 544 409 553 256 204 106 467 312 409 402 -19 60 324 390 748 610 -28 590 773 466 314 -61 206 -199 -490 -264 23 463 130 -461 -278 -699 -809 SS 20240721T134855.1Z 8968.575638 345 1 4.44 2 45.70 101.68 135.11 274.63 0.00 1 0.00 1 0 25 7.804e-03 5.654e-03 1.720e-03 9.403e-04 2.119881e-01 4.935068e-04 2.566518e-03 -6.000000e+00 4.606206e-03 232.65 -2.00 3.51 -2.00 315.84 0.00e+00 3.952828e-04 5.058917e-05 6.195006e-05 -6.000000e+00 2.047065e-04 289.65 -2.00 20.00 -2.00 315.08 0.00e+00 1.430 0.000 302.00 328.00 3 2.3353e+00 1.2882e-03 1.8235e-02 -6.0000e+00 1.1559e-02 -1.0753e-03 1.4246e-03 1.1133e-02 -6.0000e+00 1.2433e-02 -3.0694e-04 8.2074e-04 5.3929e-03 -6.0000e+00 7.4038e-03 9.5386e-04 3.8162e-04 1.4888e-03 -6.0000e+00 3.2033e-03 9.6048e-03 -1.9097e-04 2.6594e-05 1.7995e-05 -6.0000e+00 2.1296e-04 -2.3987e-02 1.6644e-04 12 1 1 12 1 1 80.94 21.97 0.30 -0.02399 -0.02542 50 152 1 5 0 86.980 26.62 20.00 21.97 32.31 26.3 1066.03 -80 -896 -1242 -2773 -2235 -1875 295 795 197 -1638 -879 -515 -333 836 45 116 106 1102 734 1222 346 618 1206 685 334 81 -228 -227 378 698 1065 1429 191 -1677 -1941 -1572 -1533 -200 -304 -773 -998 -631 -983 -281 -75 -321 -708 -749 -462 88 708 697 1195 735 895 708 500 477 644 934 1072 1484 1347 863 -193 -234 -481 491 868 549 282 156 173 -37 10 -351 -610 -639 -679 -861 -1145 -1563 -1677 -1135 -789 -495 -215 8 83 372 388 -1 388 597 243 370 634 313 44 -251 -687 -633 92 -440 -784 -850 -651 -475 84 303 249 362 166 195 72 375 283 406 176 -68 -40 301 383 592 520 -145 569 628 363 259 -59 196 -131 -346 -202 2 228 100 -267 -192 -456 -528 -19 -213 -295 -668 -479 -387 64 193 48 -419 -219 -132 -95 267 16 41 39 413 285 487 141 248 492 295 152 38 -104 -97 163 294 434 624 90 -802 -871 -699 -752 -106 -193 -525 -731 -449 -716 -204 -54 -246 -530 -543 -325 62 522 514 923 594 739 597 428 405 535 775 924 1291 1265 851 -187 -207 -418 415 748 535 281 162 177 -37 9 -323 -509 -511 -576 -774 -1153 -1628 -1849 -1239 -920 -587 -267 10 105 448 453 -1 394 630 258 411 776 400 56 -328 -836 -747 105 -529 -974 -1113 -846 -642 118 432 369 535 234 264 94 463 351 530 236 -98 -59 432 533 785 687 -183 714 799 470 357 -81 273 -186 -513 -303 3 349 156 -421 -294 -708 -791 SS 20240721T135303.7Z 8968.578515 348 1 48.92 2 44.93 102.53 135.84 275.36 0.00 1 0.00 1 0 17 7.756e-03 5.539e-03 2.307e-04 1.264e-04 2.092848e-01 6.625002e-05 2.529182e-03 -6.000000e+00 4.577925e-03 232.65 -2.00 3.51 -2.00 315.86 0.00e+00 3.341706e-04 6.828377e-06 6.936894e-05 -6.000000e+00 2.034534e-04 289.65 -2.00 20.00 -2.00 315.10 0.00e+00 1.410 0.000 302.00 328.00 3 7.1047e-01 1.7283e-04 1.7985e-02 -6.0000e+00 1.1488e-02 -7.3260e-03 1.9141e-04 1.0969e-02 -6.0000e+00 1.2357e-02 -6.5399e-04 1.0998e-04 5.3162e-03 -6.0000e+00 7.3583e-03 4.7432e-04 5.0926e-05 1.4652e-03 -6.0000e+00 3.1837e-03 5.0117e-02 -1.6273e-04 3.5696e-06 1.7626e-05 -6.0000e+00 2.1165e-04 -2.4275e-02 1.5453e-04 10 0 0 10 0 0 22.04 21.98 0.26 -0.02427 -0.02550 3279 925 1 5 0 14.270 26.62 20.00 21.98 32.60 26.2 1067.88 -189 -589 -1502 -2875 -2242 -1706 165 893 77 -1684 -1513 -853 -361 499 280 -123 184 658 798 1122 527 689 773 799 635 366 -154 -396 92 668 1254 1537 404 -1621 -1871 -1473 -1112 -195 -213 -645 -888 -646 -743 -392 -261 -403 -736 -742 -476 328 569 740 985 653 782 841 514 471 637 982 1149 1504 1455 872 -138 -155 -391 440 807 473 305 144 152 -13 -74 -311 -734 -686 -596 -927 -1121 -1623 -1731 -1206 -750 -482 -228 13 150 366 293 21 433 625 253 357 489 240 6 -313 -568 -615 27 -407 -765 -698 -658 -429 78 343 265 368 175 172 112 441 291 302 264 -33 30 230 261 555 493 17 525 630 360 225 -47 179 -128 -313 -194 -13 271 42 -313 -176 -452 -495 -45 -137 -384 -682 -473 -346 35 213 20 -424 -407 -235 -101 157 99 -46 72 262 328 438 209 270 310 337 282 167 -69 -165 39 275 540 654 185 -755 -817 -637 -530 -109 -132 -427 -633 -477 -561 -296 -196 -301 -536 -522 -326 224 408 565 789 513 627 688 427 388 514 792 961 1351 1326 835 -130 -141 -329 361 717 447 313 145 151 -13 -70 -278 -635 -568 -523 -859 -1093 -1737 -1852 -1348 -849 -583 -275 16 184 450 332 23 453 638 276 405 581 297 8 -395 -705 -742 31 -474 -970 -886 -872 -590 107 496 399 552 251 237 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