File name: Pandora135s1_ManhattanNY-CCNY_20240802_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241024T230735.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240802_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240802 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240802T133125.7Z 8980.563492 242 1 9.56 2 50.61 101.19 28.85 109.33 0.00 1 0.00 1 0 17 8.206e-03 5.804e-03 1.175e-03 6.142e-04 2.154719e-01 3.142264e-04 2.572605e-03 -6.000000e+00 4.740699e-03 232.22 -2.00 3.51 -2.00 316.10 0.00e+00 3.784101e-04 3.448818e-05 1.027669e-04 -6.000000e+00 2.142633e-04 289.92 -2.00 20.00 -2.00 315.28 0.00e+00 1.572 0.000 302.00 328.00 3 2.1609e+00 8.2209e-04 1.9370e-02 -6.0000e+00 1.1875e-02 -9.0275e-03 9.1841e-04 1.1209e-02 -6.0000e+00 1.2865e-02 7.9520e-04 5.2520e-04 5.4103e-03 -6.0000e+00 7.6676e-03 -1.4493e-03 2.3881e-04 1.4630e-03 -6.0000e+00 3.2222e-03 1.0044e-02 -4.9854e-04 1.7415e-05 1.7528e-05 -6.0000e+00 2.2366e-04 3.9082e-02 0.0000e+00 12 1 1 12 1 1 32.21 22.58 0.20 0.03908 0.03534 133 185 1 5 0 71.260 27.15 20.00 22.58 35.37 26.7 1085.14 356 -483 -1352 -3244 -2402 -1516 659 944 260 -1291 -1658 -747 81 811 356 102 172 593 517 901 223 617 577 745 618 315 -282 -670 44 724 1261 1556 51 -2021 -2138 -1906 -1180 -233 -416 -539 -945 -627 -982 -340 -180 -356 -831 -746 -541 397 731 962 1029 770 1000 999 574 402 575 938 1095 1517 1538 919 -172 -148 -453 477 973 686 498 330 291 -33 -128 -499 -989 -982 -845 -1232 -1158 -1617 -1660 -1176 -525 -288 -74 222 295 363 171 -112 59 345 132 324 530 331 -53 -449 -716 -733 -148 -699 -845 -734 -576 -280 227 539 352 504 324 184 25 326 71 153 116 -43 67 268 360 658 545 65 591 503 330 213 -66 119 -196 -464 -296 24 329 164 -132 -13 -318 -320 -577 77 -112 -313 -699 -461 -282 130 209 63 -325 -412 -191 21 239 118 36 62 222 200 359 90 247 218 297 259 135 -118 -285 17 283 519 687 22 -899 -966 -862 -544 -126 -250 -344 -650 -446 -716 -247 -130 -256 -583 -507 -358 264 511 715 805 589 781 796 465 323 453 739 898 1338 1376 862 -158 -131 -373 386 857 643 504 325 301 -33 -117 -437 -842 -806 -694 -1144 -1128 -1629 -1767 -1310 -592 -347 -89 272 358 442 192 -120 62 354 136 370 633 412 -69 -568 -887 -884 -173 -822 -1080 -936 -767 -387 313 785 510 759 464 255 32 414 92 197 162 -61 95 376 514 896 706 84 729 633 444 291 -95 171 -276 -683 -441 37 522 267 -215 -20 -487 -497 -888 SS 20240802T134056.7Z 8980.570100 245 1 47.95 2 48.85 103.07 27.21 112.03 0.00 1 0.00 1 0 17 7.966e-03 5.670e-03 3.141e-04 1.699e-04 2.078576e-01 8.711635e-05 2.484732e-03 -6.000000e+00 4.601693e-03 232.22 -2.00 3.51 -2.00 315.98 0.00e+00 3.407856e-04 9.333004e-06 6.896551e-05 -6.000000e+00 2.079992e-04 289.92 -2.00 20.00 -2.00 315.18 0.00e+00 1.517 0.000 302.00 328.00 3 1.2531e+00 2.2759e-04 1.8693e-02 -6.0000e+00 1.1527e-02 -9.4774e-03 2.5367e-04 1.0829e-02 -6.0000e+00 1.2488e-02 6.7661e-04 1.4511e-04 5.2284e-03 -6.0000e+00 7.4430e-03 -1.0418e-03 6.5835e-05 1.4163e-03 -6.0000e+00 3.1274e-03 2.6668e-02 -4.3517e-04 4.8287e-06 1.6845e-05 -6.0000e+00 2.1712e-04 3.9714e-02 0.0000e+00 10 0 0 10 0 0 56.46 22.58 0.26 0.03971 0.03644 1873 528 1 5 0 24.980 27.15 20.00 22.58 36.11 26.7 1090.95 99 -497 -1484 -3111 -2227 -1607 558 1110 121 -1790 -1465 -591 -22 770 326 -104 236 669 737 1001 363 601 -101 870 612 310 -307 -511 110 780 1526 1717 335 -1755 -1867 -1487 -942 28 -86 -587 -935 -699 -843 -449 -342 -516 -841 -861 -546 369 586 753 970 623 752 802 435 347 526 885 1101 1535 1428 801 -240 -219 -375 585 997 618 466 229 233 -3 -144 -433 -829 -768 -692 -1027 -1194 -1732 -1716 -1127 -636 -333 -85 137 282 480 397 101 494 669 255 385 459 96 -86 -405 -732 -753 -98 -566 -859 -738 -679 -367 143 355 284 401 178 145 123 335 199 188 162 -84 27 243 296 615 492 86 629 588 380 264 10 218 -87 -328 -171 25 301 97 -222 -95 -377 -356 -542 23 -122 -363 -703 -449 -314 115 257 31 -474 -379 -158 -6 235 112 -38 89 258 293 410 151 247 -43 356 263 137 -132 -222 45 310 637 769 149 -788 -851 -677 -439 15 -52 -379 -649 -502 -618 -328 -249 -373 -593 -587 -388 263 410 560 757 508 626 638 351 278 440 742 901 1348 1352 747 -219 -193 -305 499 868 572 466 237 238 -3 -138 -374 -695 -621 -596 -937 -1144 -1817 -1794 -1232 -744 -394 -106 173 353 573 460 112 502 669 273 429 537 123 -109 -526 -884 -885 -112 -686 -1072 -968 -884 -496 202 505 419 588 248 195 160 412 249 248 219 -120 39 348 411 814 652 108 794 757 496 367 14 304 -124 -490 -258 39 462 152 -350 -152 -586 -535 -807 SS 20240802T135042.9Z 8980.576885 248 1 47.54 2 47.06 105.07 25.56 115.05 0.00 1 0.00 1 0 17 7.928e-03 5.683e-03 3.369e-04 1.886e-04 2.007850e-01 9.658373e-05 2.393723e-03 -6.000000e+00 4.580470e-03 232.22 -2.00 3.51 -2.00 315.85 0.00e+00 3.194575e-04 1.007637e-05 6.462084e-05 -6.000000e+00 2.069998e-04 289.92 -2.00 20.00 -2.00 315.05 0.00e+00 1.465 0.000 302.00 328.00 3 1.5242e+00 2.5201e-04 1.8047e-02 -6.0000e+00 1.1473e-02 -7.3688e-03 2.8112e-04 1.0439e-02 -6.0000e+00 1.2429e-02 1.9044e-03 1.6038e-04 5.0398e-03 -6.0000e+00 7.4083e-03 -1.3977e-03 7.2204e-05 1.3659e-03 -6.0000e+00 3.1135e-03 2.1638e-02 -2.6392e-04 5.3537e-06 1.6342e-05 -6.0000e+00 2.1607e-04 3.8342e-02 0.0000e+00 10 0 0 10 0 0 99.30 22.59 0.26 0.03834 0.03636 1495 422 1 5 0 31.310 27.15 20.00 22.59 36.96 26.7 1097.84 42 -495 -1684 -3011 -2276 -1438 638 1192 117 -1625 -1375 -547 77 684 335 -228 207 646 768 974 434 508 737 798 577 274 -331 -461 76 807 1442 1753 339 -1766 -1907 -1470 -895 -36 -108 -734 -896 -772 -825 -499 -379 -490 -856 -869 -557 340 579 762 976 655 762 849 421 374 554 920 1141 1468 1450 805 -231 -232 -333 584 993 608 453 233 201 -7 -139 -414 -782 -743 -692 -1020 -1213 -1682 -1733 -1129 -623 -371 -82 117 258 432 368 88 492 665 256 366 457 78 -84 -397 -696 -720 -86 -530 -856 -751 -653 -400 128 335 282 380 167 125 125 324 194 202 157 -83 60 245 306 608 522 74 590 609 377 276 -4 226 -88 -341 -184 18 300 73 -218 -97 -333 -359 -558 10 -119 -440 -725 -488 -299 140 293 32 -418 -377 -154 22 220 120 -88 81 261 319 416 173 218 298 340 259 126 -148 -208 32 333 623 809 155 -816 -894 -689 -429 -20 -67 -486 -637 -568 -619 -374 -283 -362 -617 -606 -404 246 412 576 774 541 603 684 344 303 469 781 945 1306 1388 758 -213 -206 -273 501 869 565 455 241 207 -6 -135 -359 -658 -602 -597 -931 -1163 -1763 -1810 -1233 -727 -439 -102 148 324 516 426 98 498 662 273 406 560 100 -112 -511 -833 -839 -97 -637 -1062 -979 -843 -535 179 472 413 551 242 166 160 415 238 263 209 -118 86 347 421 836 683 93 735 772 485 377 -5 309 -124 -499 -272 28 473 118 -337 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