File name: Pandora135s1_ManhattanNY-CCNY_20240901_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240902T050130.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240901_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240901 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240901T131742.5Z 9010.553964 179 1 32.53 2 58.27 108.59 41.86 112.68 0.00 1 0.00 1 0 17 1.715e-02 6.800e-03 4.530e-03 1.526e-03 2.583530e-01 7.879484e-04 3.124499e-03 -6.000000e+00 1.004575e-02 230.32 -2.00 3.51 -2.00 317.13 0.00e+00 4.337786e-04 1.099735e-04 1.560980e-04 -6.000000e+00 4.483408e-04 288.86 -2.00 20.00 -2.00 316.31 0.00e+00 1.894 0.000 302.00 328.00 3 4.5605e+00 2.0811e-03 2.3294e-02 -6.0000e+00 2.5073e-02 4.6553e-03 2.3252e-03 1.3514e-02 -6.0000e+00 2.7009e-02 5.8054e-03 1.3920e-03 6.5892e-03 -6.0000e+00 1.6108e-02 -2.2538e-03 6.9347e-04 1.8399e-03 -6.0000e+00 7.0082e-03 6.0863e-04 -5.6952e-05 4.3597e-05 2.0500e-05 -6.0000e+00 4.6736e-04 -3.1285e-02 1.8867e-04 12 9 1 12 1 1 99.98 21.75 0.17 -0.03129 -0.03171 41 17 1 5 0 774.320 26.41 20.00 21.75 29.30 26.5 1038.21 414 -1608 -1162 -2821 1743 -8500 529 2009 1067 -2834 -1923 -2549 1960 2471 134 840 251 2944 1103 2109 679 1421 -14096 1454 1184 -20 -335 -223 -550 780 1593 1509 954 -1617 -1767 -1357 -865 -360 -97 410 -1259 -447 -647 -342 -51 -250 -240 -370 -302 801 127 1153 1184 664 903 1246 511 423 349 875 1449 1612 1359 1043 -98 -255 -379 283 576 371 124 80 268 232 279 -453 -863 -948 -357 -1136 -1115 -1821 -1883 -1013 -713 -435 -2 -85 -14 653 289 140 289 863 173 258 525 286 -15 -558 -602 -495 -151 -590 -730 -697 -863 -358 138 553 170 351 61 182 11 441 360 192 428 -6 86 267 370 341 437 -476 713 571 352 221 44 143 -80 -520 -140 -39 444 152 -303 -161 -359 -565 49 -208 -151 -345 183 -957 58 247 146 -418 -279 -388 321 464 28 191 60 711 282 553 183 378 -4337 420 362 -6 -105 -66 -153 213 459 474 325 -549 -585 -444 -311 -147 -46 214 -727 -267 -385 -204 -30 -153 -144 -217 -173 461 78 729 791 468 633 890 373 307 256 638 1059 1270 1131 919 -86 -206 -293 215 472 325 118 77 255 218 249 -376 -674 -713 -284 -968 -1036 -1819 -1999 -1090 -799 -520 -2 -106 -18 797 335 152 295 862 181 290 638 375 -20 -736 -757 -586 -175 -704 -945 -927 -1172 -505 200 828 263 543 93 261 15 577 474 266 620 -10 129 402 539 488 610 -636 921 749 484 319 64 215 -122 -818 -228 -65 754 263 -529 -273 -602 -934 SS 20240901T132233.0Z 9010.557326 182 1 7.95 2 57.40 109.57 41.05 113.88 0.00 1 0.00 1 0 17 1.827e-02 7.180e-03 9.304e-03 3.336e-03 2.547554e-01 1.722476e-03 3.069743e-03 -6.000000e+00 1.069894e-02 230.32 -2.00 3.51 -2.00 316.98 0.00e+00 6.432394e-04 2.322090e-04 1.850850e-04 -6.000000e+00 4.775348e-04 288.86 -2.00 20.00 -2.00 316.18 0.00e+00 1.850 0.000 302.00 328.00 3 4.6738e+00 4.5377e-03 2.2794e-02 -6.0000e+00 2.6703e-02 1.6069e-02 5.0682e-03 1.3263e-02 -6.0000e+00 2.8766e-02 1.3507e-03 3.0172e-03 6.4693e-03 -6.0000e+00 1.7156e-02 -1.5430e-03 1.4919e-03 1.8181e-03 -6.0000e+00 7.4631e-03 5.6835e-04 -1.0964e-04 9.4942e-05 1.9889e-05 -6.0000e+00 4.9782e-04 -3.0763e-02 1.7782e-04 12 9 1 12 1 1 99.86 21.76 0.44 -0.03076 -0.03159 7 13 1 5 0 992.390 26.41 20.00 21.76 29.33 26.6 1039.05 -1663 1473 519 -3716 2536 -13114 4296 -2990 3844 -6256 -397 -3634 3523 -1441 -637 1299 -53 4195 77 1629 -1667 2698 -622 2907 951 1110 -1103 -1017 -644 -2339 2217 -989 1430 -3068 -756 -2875 -1256 -2553 447 31 -1764 -258 -1688 122 -747 395 -385 -520 -1086 1267 886 782 1110 -395 1714 722 483 374 750 741 2365 765 1215 976 74 -187 -646 431 215 1067 262 1262 192 47 954 -481 -884 -1104 -459 -1073 -571 -1593 -1488 -2058 -662 -798 279 10 88 540 -42 321 -143 860 -541 644 168 327 59 -499 -650 -1128 -38 -881 -675 -714 -310 -614 274 272 854 518 261 154 -177 282 361 827 -153 52 -156 1001 -87 686 324 -575 417 457 492 -505 219 30 -86 -402 17 -107 403 631 -566 -35 -868 -182 -214 199 71 -491 296 -1652 509 -412 545 -1014 -60 -592 601 -298 -142 309 -13 1047 21 449 -481 740 -181 860 303 364 -363 -314 -186 -682 686 -330 501 -1130 -256 -985 -467 -1091 222 17 -1033 -155 -1056 76 -465 242 -233 -319 -657 759 542 514 769 -280 1224 532 362 279 545 538 1756 623 1032 877 66 -154 -511 333 174 969 252 1243 189 45 858 -407 -681 -850 -360 -924 -530 -1640 -1573 -2225 -757 -949 346 13 109 653 -49 347 -147 860 -567 739 202 419 80 -662 -827 -1364 -44 -1070 -860 -932 -422 -849 395 407 1297 791 393 221 -240 372 478 1112 -217 78 -232 1491 -127 981 441 -774 545 587 679 -732 321 45 -132 -625 27 -180 672 1071 -973 -60 -1440 -296 SS 20240901T142354.3Z 9010.599934 222 1 7.74 2 47.03 123.69 31.63 132.43 0.00 1 0.00 1 0 17 1.554e-02 8.367e-03 9.569e-03 4.833e-03 2.049433e-01 2.506256e-03 2.506059e-03 -6.000000e+00 9.097154e-03 230.32 -2.00 3.51 -2.00 316.09 0.00e+00 2.942785e-04 2.736131e-04 7.885343e-05 -6.000000e+00 4.061192e-04 288.86 -2.00 20.00 -2.00 315.33 0.00e+00 1.465 0.000 302.00 328.00 3 5.5825e+00 6.5223e-03 1.8181e-02 -6.0000e+00 2.2704e-02 2.1527e-02 7.2398e-03 1.0705e-02 -6.0000e+00 2.4461e-02 5.4473e-03 4.1917e-03 5.2242e-03 -6.0000e+00 1.4588e-02 -2.0628e-03 1.9824e-03 1.4559e-03 -6.0000e+00 6.3445e-03 3.6378e-04 -3.5150e-04 1.3691e-04 1.7534e-05 -6.0000e+00 4.2348e-04 -2.9713e-02 1.4767e-04 12 9 1 12 1 1 999.00 21.90 0.23 -0.02971 -0.03235 2 5 1 5 0 2576.180 26.51 20.00 21.90 30.78 26.7 1049.27 3364 -1855 -3252 -651 -788 -8829 -110 -2535 4229 -5443 -708 -3754 2201 1366 -650 651 875 1809 -1054 3370 139 3964 409 1206 607 1834 -29 -217 -476 -793 1980 1603 1083 -4351 -947 -3010 -926 -1376 -297 -611 -741 458 -1217 -877 -1201 471 -1415 -603 -1083 1647 -916 377 672 927 1295 538 790 437 636 631 1102 1273 2259 1417 848 -701 90 178 326 -237 -89 1166 23 407 474 -289 -1484 -1261 -414 -1408 -1544 -1960 -1615 -857 -971 -1166 347 200 951 38 18 -27 508 327 -428 1110 405 1104 251 -181 -788 -399 -400 -704 -858 -1018 -509 -553 323 9 1441 655 -225 -122 33 45 -444 -424 231 468 67 669 627 846 -783 -965 847 455 366 441 783 -126 329 -1096 470 -268 440 138 -492 85 -243 -887 677 -406 -743 -133 -144 -1683 -21 -545 933 -1313 -165 -927 567 389 -211 217 299 651 -390 1229 53 1440 157 482 257 786 -12 -86 -184 -300 764 667 466 -1978 -402 -1290 -414 -705 -174 -399 -508 322 -889 -640 -876 335 -998 -419 -736 1093 -655 276 515 738 1022 436 646 356 521 517 907 1124 2072 1336 805 -617 74 147 283 -227 -90 1172 24 404 448 -253 -1220 -1015 -338 -1267 -1511 -2048 -1733 -957 -1135 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