File name: Pandora135s1_ManhattanNY-CCNY_20240918_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241025T000222.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240918_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240918T145621.0Z 9027.622465 376 1 46.13 2 46.92 139.46 128.13 313.64 0.00 1 0.00 1 0 17 2.116e-02 8.284e-03 7.841e-03 3.592e-03 1.944307e-01 1.809180e-03 2.341179e-03 -6.000000e+00 1.210919e-02 228.80 -2.00 3.51 -2.00 316.50 0.00e+00 5.823722e-04 2.175563e-04 1.368669e-04 -6.000000e+00 5.463498e-04 287.38 -2.00 20.00 -2.00 315.70 0.00e+00 1.462 0.000 302.00 328.00 3 6.7642e+00 4.7344e-03 1.7695e-02 -6.0000e+00 3.0110e-02 5.0520e-02 5.3130e-03 9.9992e-03 -6.0000e+00 3.2680e-02 5.1290e-03 3.0679e-03 4.8762e-03 -6.0000e+00 1.9506e-02 -3.9717e-03 1.4337e-03 1.3611e-03 -6.0000e+00 8.2699e-03 1.1391e-04 -2.8272e-04 1.0307e-04 1.5858e-05 -6.0000e+00 5.7548e-04 1.4167e-02 0.0000e+00 11 8 0 10 0 0 99.99 21.40 0.24 0.01417 0.01204 18 5 1 5 0 2561.990 26.11 20.00 21.40 28.01 26.6 1029.05 1390 -2686 -3098 -2547 4137 -19577 -216 998 3970 -3637 2367 -108 947 2334 -2971 313 1135 3517 493 3765 -1470 236 -1848 122 -517 324 690 88 -1822 -1428 1824 611 2199 -4049 -864 -1032 164 -110 -4 -104 181 -861 -1344 -1084 337 178 157 -123 632 920 148 776 802 725 1814 1931 -22 424 -216 283 2358 2016 1684 1145 -112 -364 -1202 -829 -281 -201 130 577 413 289 662 -253 -998 -2059 -1135 -1264 -1604 -1273 -1877 -773 -650 -239 415 221 -709 485 -262 -118 -719 -165 -160 50 421 1061 353 16 -544 -812 -540 -790 -1148 -515 -821 -490 -102 1297 796 822 4 -240 313 -584 -580 -218 465 71 401 878 858 955 285 283 -44 308 216 111 180 186 -57 -416 -517 172 598 351 -281 -76 201 -1025 -860 254 -545 -629 -473 640 -3671 -35 181 768 -779 467 -22 213 587 -881 96 356 1105 164 1252 -521 81 -660 45 -200 128 265 32 -623 -474 634 222 836 -1641 -329 -387 64 -50 -2 -63 118 -589 -943 -761 232 122 105 -79 392 588 97 534 580 546 1381 1493 -18 334 -168 218 1848 1700 1484 1063 -103 -317 -964 -644 -233 -181 127 582 414 279 614 -212 -784 -1549 -885 -1066 -1514 -1264 -1985 -847 -737 -289 526 279 -901 603 -303 -127 -732 -162 -166 54 507 1346 473 21 -670 -952 -607 -931 -1473 -671 -1119 -693 -146 1929 1239 1279 6 -342 417 -739 -733 -288 636 103 601 1294 1227 1305 384 361 -53 374 279 152 249 262 -81 -619 -792 274 975 585 -473 -125 318 -1634 -1345 SS 20240918T150142.0Z 9027.626181 379 1 46.27 2 46.27 141.08 128.80 315.03 0.00 1 0.00 1 0 17 1.047e-02 5.902e-03 2.886e-03 1.546e-03 1.853376e-01 7.832612e-04 2.232382e-03 -6.000000e+00 5.990439e-03 228.80 -2.00 3.51 -2.00 315.98 0.00e+00 3.756514e-04 8.383834e-05 5.801787e-05 -6.000000e+00 2.702912e-04 287.38 -2.00 20.00 -2.00 315.22 0.00e+00 1.444 0.000 302.00 328.00 3 5.5463e+00 2.0342e-03 1.7276e-02 -6.0000e+00 1.4896e-02 2.1049e-02 2.2748e-03 9.5326e-03 -6.0000e+00 1.6167e-02 3.8368e-03 1.3049e-03 4.6482e-03 -6.0000e+00 9.6497e-03 -2.4489e-03 5.9632e-04 1.2933e-03 -6.0000e+00 4.0909e-03 4.0449e-04 -3.7102e-04 4.4049e-05 1.5501e-05 -6.0000e+00 2.8471e-04 1.4669e-02 0.0000e+00 10 0 0 10 0 0 99.82 21.41 0.22 0.01467 0.01188 35 10 1 5 0 1321.790 26.11 20.00 21.41 28.17 26.6 1030.68 776 -1100 -1268 -2803 -646 -8219 76 20 679 -1912 -1149 -1007 254 1119 -502 705 264 1455 490 1546 62 1055 147 1421 462 322 76 -387 -211 -236 1740 746 1007 -1956 -1880 -1351 -1075 -180 -11 -96 -956 -456 -1038 -791 -244 -220 -727 -782 -109 470 425 1025 1195 665 1038 921 298 349 660 633 1454 1379 1524 937 -276 -280 -669 43 385 320 71 177 145 108 -87 -81 -863 -785 -562 -883 -834 -1692 -1692 -968 -532 -257 -66 -117 -150 552 197 95 226 281 -107 285 312 112 201 -171 -348 -670 -83 -593 -893 -630 -631 -240 163 497 499 540 109 -39 -89 287 26 -162 205 -70 20 365 688 734 681 -773 598 551 419 160 93 202 -348 -169 -297 135 499 324 -168 -33 -341 -678 -622 177 -262 -313 -646 -130 -1702 15 5 168 -499 -291 -259 71 335 -171 253 98 545 191 613 25 421 60 600 199 142 34 -163 -83 -90 676 313 447 -896 -803 -565 -490 -92 -6 -64 -673 -331 -774 -591 -180 -161 -520 -560 -75 321 303 746 912 531 844 762 242 292 541 518 1222 1200 1427 892 -260 -249 -565 35 335 303 71 183 149 107 -83 -72 -695 -620 -463 -786 -799 -1726 -1826 -1051 -616 -308 -81 -148 -189 683 232 105 235 281 -110 319 373 142 259 -224 -425 -780 -95 -695 -1104 -821 -831 -328 232 722 734 816 157 -53 -115 358 32 -206 280 -100 29 525 959 1008 888 -1002 724 670 541 213 129 285 -485 -244 -441 209 793 513 -269 -52 -531 -1023 -950 SS 20240918T150603.4Z 9027.629206 382 1 21.18 2 45.76 142.41 129.33 316.18 0.00 1 0.00 1 0 17 8.631e-03 5.790e-03 2.286e-03 1.359e-03 1.820396e-01 6.914687e-04 2.204808e-03 -6.000000e+00 4.937890e-03 228.80 -2.00 3.51 -2.00 315.58 0.00e+00 3.558589e-04 6.804781e-05 4.505585e-05 -6.000000e+00 2.228215e-04 287.38 -2.00 20.00 -2.00 314.85 0.00e+00 1.431 0.000 302.00 328.00 3 4.6694e+00 1.7870e-03 1.7077e-02 -6.0000e+00 1.2278e-02 1.1430e-02 1.9942e-03 9.3793e-03 -6.0000e+00 1.3327e-02 2.7745e-03 1.1406e-03 4.5751e-03 -6.0000e+00 7.9547e-03 -1.6316e-03 5.1266e-04 1.2726e-03 -6.0000e+00 3.3715e-03 9.9579e-04 -4.7728e-04 3.8482e-05 1.5954e-05 -6.0000e+00 2.3474e-04 1.5987e-02 0.0000e+00 12 1 1 12 1 1 87.73 21.42 0.27 0.01599 0.01240 23 15 1 5 0 882.100 26.11 20.00 21.42 28.35 26.7 1032.32 156 -1414 -1375 -3769 -1281 -4046 356 627 467 -1518 -959 -589 337 1510 -197 524 190 1219 338 1075 371 562 1402 683 367 211 117 -833 -294 -190 1736 1628 562 -1422 -1550 -1305 -1343 501 -555 -581 -915 -774 -687 -687 41 -395 -675 -714 -159 81 683 456 1358 683 1118 760 539 438 516 975 837 1657 1430 989 -400 -230 -461 442 552 410 225 -85 224 -72 83 -357 -410 -672 -423 -938 -1200 -1508 -1833 -954 -727 -728 -295 -113 -164 260 293 -2 439 540 401 385 644 208 22 -280 -523 -708 256 -286 -639 -815 -501 -399 87 394 122 339 1 247 126 604 200 240 158 -55 31 254 283 690 579 -106 676 643 424 196 2 302 -204 -293 -323 -144 364 220 -350 -107 -272 -396 -523 41 -400 -387 -997 -305 -948 85 167 132 -448 -274 -171 106 531 -76 214 80 518 144 468 164 246 618 317 180 106 58 -386 -130 -82 762 763 273 -705 -744 -615 -668 278 -359 -404 -689 -586 -531 -532 31 -301 -516 -527 -116 59 501 357 1072 565 941 634 456 369 439 824 713 1501 1359 960 -385 -213 -402 371 483 394 228 -87 229 -73 81 -320 -340 -546 -358 -840 -1168 -1565 -1965 -1063 -843 -883 -367 -141 -204 316 346 -2 460 547 416 428 767 260 28 -360 -644 -824 292 -335 -795 -1046 -654 -540 120 559 176 500 2 335 159 753 250 307 213 -76 44 355 393 934 745 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