File name: Pandora135s1_ManhattanNY-CCNY_20240927_L2Fit_fout2c15d20200411p1-8.txt File generation date: 20240928T045303.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c15p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v15d20200411.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20240927_L1_smca1c15d20200411p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20240927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: PRNU discussion ValPeriod2020-today, ValPeriod3 (change HCHO and NO2 MLE to E-MLE) First and last pixel inside fitting window: 234 375 Nominal wavelengths inside fitting window [nm]: 305.1262 305.2670 305.4078 305.5486 305.6894 305.8301 305.9709 306.1116 306.2524 306.3931 306.5338 306.6745 306.8152 306.9558 307.0965 307.2371 307.3778 307.5184 307.6590 307.7996 307.9402 308.0808 308.2214 308.3620 308.5025 308.6430 308.7836 308.9241 309.0646 309.2051 309.3456 309.4861 309.6265 309.7670 309.9074 310.0478 310.1883 310.3287 310.4691 310.6094 310.7498 310.8902 311.0305 311.1709 311.3112 311.4515 311.5918 311.7321 311.8724 312.0127 312.1529 312.2932 312.4334 312.5737 312.7139 312.8541 312.9943 313.1345 313.2746 313.4148 313.5549 313.6951 313.8352 313.9753 314.1154 314.2555 314.3956 314.5357 314.6757 314.8158 314.9558 315.0959 315.2359 315.3759 315.5159 315.6559 315.7958 315.9358 316.0757 316.2157 316.3556 316.4955 316.6354 316.7753 316.9152 317.0551 317.1949 317.3348 317.4746 317.6144 317.7542 317.8940 318.0338 318.1736 318.3134 318.4531 318.5929 318.7326 318.8723 319.0120 319.1517 319.2914 319.4311 319.5708 319.7104 319.8501 319.9897 320.1293 320.2689 320.4085 320.5481 320.6877 320.8273 320.9668 321.1064 321.2459 321.3854 321.5249 321.6644 321.8039 321.9434 322.0828 322.2223 322.3617 322.5011 322.6405 322.7799 322.9193 323.0587 323.1981 323.3374 323.4768 323.6161 323.7554 323.8948 324.0341 324.1733 324.3126 324.4519 324.5911 324.7304 324.8696 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240927T144313.4Z 9036.613350 350 1 45.48 2 51.19 138.88 26.28 231.74 0.00 1 0.00 1 0 17 2.116e-02 9.664e-03 6.056e-03 2.893e-03 1.994749e-01 1.484882e-03 2.436185e-03 -6.000000e+00 1.228763e-02 227.81 -2.00 3.51 -2.00 316.29 0.00e+00 7.601817e-04 1.694470e-04 1.277651e-04 -6.000000e+00 5.473029e-04 286.29 -2.00 20.00 -2.00 315.57 0.00e+00 1.592 0.000 302.00 328.00 3 6.3400e+00 3.8578e-03 1.8900e-02 -6.0000e+00 3.0513e-02 6.1566e-02 4.2946e-03 1.0284e-02 -6.0000e+00 3.2936e-02 -2.9418e-03 2.4996e-03 5.0414e-03 -6.0000e+00 1.9651e-02 3.4210e-04 1.1958e-03 1.4539e-03 -6.0000e+00 8.5829e-03 1.5106e-04 -6.2231e-04 8.2457e-05 1.6673e-05 -6.0000e+00 5.7615e-04 -3.8151e-02 1.3278e-04 12 8 8 10 0 0 99.96 21.30 0.37 -0.03815 -0.04283 13 4 1 5 0 3497.890 26.00 20.00 21.30 27.59 26.6 1026.34 1374 -308 -566 183 960 -15846 -3140 459 1748 -939 1947 -1047 2333 1909 309 532 4052 3465 2235 2184 1019 1361 -13065 1471 782 1519 -792 1121 -2085 829 179 1613 1045 -2906 -2636 -1883 -1032 -1529 682 112 60 -783 -895 -935 379 773 -40 -377 -52 820 -791 1569 1038 896 1293 1844 51 69 -323 116 1411 1826 1968 1164 133 -596 -517 -1439 258 -142 -187 864 81 243 644 230 -1574 -1854 -2027 -1811 -1303 -951 -1766 -1117 -729 2 935 114 486 547 368 -540 -295 -694 -874 -158 639 1034 390 -75 -393 -703 -703 -658 -869 -537 -828 108 242 719 983 861 291 -265 302 -735 -210 -360 408 107 336 835 880 1282 210 -2051 39 156 -298 -78 -212 88 -123 -284 -264 80 876 458 -218 3 160 -1301 260 -63 -117 35 166 -3084 -568 90 371 -203 415 -234 537 501 92 170 1290 1138 766 771 368 485 -5262 554 311 615 -322 418 -748 291 66 607 421 -1224 -1035 -746 -426 -745 374 69 39 -544 -635 -667 266 536 -27 -257 -34 534 -548 1094 765 689 1011 1459 41 56 -257 92 1140 1575 1771 1108 126 -517 -423 -1155 218 -132 -183 867 82 242 595 197 -1276 -1429 -1636 -1579 -1223 -973 -1869 -1230 -831 3 1184 146 615 685 438 -587 -299 -685 -911 -174 772 1325 514 -100 -489 -831 -797 -779 -1086 -707 -1140 149 349 1061 1508 1323 428 -372 396 -943 -268 -467 566 154 496 1212 1239 1771 279 -2714 48 192 -391 -106 -299 126 -179 -417 -411 126 1411 757 -365 5 259 -2055 SS 20240927T144948.5Z 9036.617923 354 1 47.25 2 50.39 140.74 27.27 234.22 0.00 1 0.00 1 0 17 1.845e-02 8.102e-03 6.448e-03 3.025e-03 2.021361e-01 1.550681e-03 2.451294e-03 -6.000000e+00 1.071566e-02 227.81 -2.00 3.51 -2.00 316.36 0.00e+00 3.547914e-04 1.787533e-04 1.150228e-04 -6.000000e+00 4.772866e-04 286.28 -2.00 20.00 -2.00 315.63 0.00e+00 1.565 0.000 302.00 328.00 3 6.3841e+00 4.0297e-03 1.8745e-02 -6.0000e+00 2.6610e-02 7.5222e-02 4.4869e-03 1.0378e-02 -6.0000e+00 2.8720e-02 -4.2339e-03 2.6140e-03 5.0913e-03 -6.0000e+00 1.7136e-02 -5.2569e-04 1.2551e-03 1.4402e-03 -6.0000e+00 7.4860e-03 1.4709e-04 -4.4253e-04 8.6152e-05 1.6637e-05 -6.0000e+00 5.0227e-04 -3.8170e-02 1.8948e-04 11 9 0 11 8 0 99.98 21.31 0.07 -0.03817 -0.04150 20 6 1 5 0 2362.150 26.00 20.00 21.31 27.91 26.8 1028.67 1573 -1684 -96 -3088 3633 -17075 -2551 467 -119 -2563 -2358 708 -911 3215 -1476 426 997 1887 834 1214 1644 753 1244 226 1053 214 238 929 -1039 -285 766 -232 1796 -2590 -2274 -1548 -1833 1378 -433 155 -86 -640 -1294 -676 -67 -132 373 -1429 -127 524 -239 409 990 925 1476 1478 -257 457 83 91 1502 1973 1239 1793 77 -647 -873 -1537 423 -92 461 845 154 587 535 -614 -1924 -2064 -1554 -1489 -1950 -1079 -1985 -442 -424 -86 662 632 134 571 652 -545 -575 -566 -900 -100 418 735 786 69 250 -877 -884 -1073 -583 -824 -706 -406 173 1016 826 876 255 -206 -317 -732 -687 -433 569 -3 793 937 576 797 24 -96 1 -251 -253 137 -132 323 -503 -71 -134 163 521 409 -85 -28 -246 -1250 293 -347 -20 -595 582 -3208 -438 87 -25 -560 -504 149 -215 824 -444 135 324 622 286 428 584 267 445 85 415 87 95 345 -365 -97 268 -88 710 -1075 -880 -583 -754 644 -237 97 -56 -437 -908 -473 -46 -91 257 -967 -82 337 -162 293 716 697 1131 1153 -206 362 65 71 1186 1664 1134 1656 71 -568 -702 -1208 349 -86 450 853 156 569 499 -519 -1533 -1560 -1220 -1307 -1854 -1075 -2113 -484 -482 -105 840 799 170 713 776 -594 -588 -561 -942 -110 506 943 1058 91 308 -1038 -1003 -1274 -747 -1082 -965 -575 247 1524 1255 1374 384 -296 -416 -937 -878 -577 782 -4 1152 1388 831 1097 33 -123 1 -308 -329 189 -184 457 -728 -107 -206 262 857 686 -140 -46 -393 -1945 SS 20240927T145837.7Z 9036.624048 360 1 29.61 2 49.36 143.29 28.64 237.32 0.00 1 0.00 1 0 17 7.358e-03 5.454e-03 1.157e-03 6.607e-04 1.852170e-01 3.418754e-04 2.273083e-03 -6.000000e+00 4.273761e-03 227.81 -2.00 3.51 -2.00 315.68 0.00e+00 3.367999e-04 3.391239e-05 5.361757e-05 -6.000000e+00 1.903478e-04 286.28 -2.00 20.00 -2.00 315.00 0.00e+00 1.532 0.000 302.00 328.00 3 3.4012e+00 8.8175e-04 1.8004e-02 -6.0000e+00 1.0613e-02 2.0746e-02 9.7764e-04 9.5711e-03 -6.0000e+00 1.1454e-02 1.0528e-03 5.6431e-04 4.6916e-03 -6.0000e+00 6.8338e-03 -9.2312e-04 2.6237e-04 1.3334e-03 -6.0000e+00 2.9861e-03 3.1682e-03 3.8743e-05 1.8693e-05 1.6245e-05 -6.0000e+00 2.0026e-04 -3.8951e-02 2.1673e-04 12 1 1 12 1 1 99.99 21.33 0.23 -0.03895 -0.03866 181 81 1 5 0 162.640 26.00 20.00 21.33 28.39 26.7 1031.88 -250 -351 -1407 -2550 -1715 -2006 304 816 525 -1366 -840 -932 -187 472 154 -127 226 652 477 1095 360 816 400 680 430 368 -203 -399 80 700 1397 1478 591 -1509 -1914 -1543 -1094 -130 -203 -657 -917 -686 -807 -390 -270 -348 -693 -559 -321 276 629 674 1021 542 878 911 511 439 706 908 1064 1390 1486 904 -181 -138 -312 299 561 430 191 241 154 -1 -56 -261 -728 -513 -563 -888 -1011 -1462 -1769 -1334 -835 -518 -210 -82 54 276 223 -62 366 747 276 384 471 336 94 -194 -424 -610 -22 -285 -727 -752 -612 -501 119 364 266 345 182 124 45 373 211 367 311 83 -25 297 272 473 438 -37 609 696 357 184 -48 125 -150 -310 -159 -43 234 75 -194 -157 -514 -522 -63 -95 -384 -649 -385 -430 67 202 143 -391 -234 -263 -58 163 54 -48 88 258 195 458 153 343 171 304 202 178 -97 -177 33 303 572 645 277 -724 -861 -679 -523 -72 -125 -464 -651 -504 -606 -293 -202 -258 -540 -419 -232 198 470 536 788 438 722 762 435 371 585 750 907 1267 1360 871 -172 -128 -266 246 493 399 193 253 161 -1 -53 -236 -593 -425 -487 -801 -1018 -1508 -1938 -1525 -954 -632 -270 -102 67 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