File name: Pandora135s1_ManhattanNY-CCNY_20241105_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241106T044356.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20241105_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20241105 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241105T123337.4Z 9075.523350 62 1 46.68 2 80.30 121.02 122.50 102.06 0.00 1 0.00 1 0 17 3.561e-01 9.336e-03 2.113e-01 3.809e-03 5.977376e-01 2.004346e-03 6.848252e-03 -6.000000e+00 2.009335e-01 224.03 -2.00 3.51 -2.00 321.09 0.00e+00 5.877437e-03 9.337166e-04 1.242825e-03 -6.000000e+00 9.206975e-03 281.53 -2.00 20.00 -2.00 320.52 0.00e+00 5.664 0.003 302.00 328.00 3 2.1538e+00 6.6535e-03 6.4138e-02 -6.0000e+00 4.9477e-01 8.1910e-02 9.0277e-03 3.1888e-02 -6.0000e+00 5.3923e-01 -7.5975e-02 9.1593e-03 1.8676e-02 -6.0000e+00 3.2156e-01 2.5862e-02 4.4258e-03 8.5991e-03 -6.0000e+00 1.3838e-01 1.2333e-04 -1.1076e-03 1.0922e-04 9.5379e-05 -6.0000e+00 9.7969e-03 -2.9761e-03 0.0000e+00 12 8 8 10 0 0 99.97 20.56 0.23 -0.00298 -0.01130 106 30 1 5 0 440.310 25.39 20.00 20.56 19.27 26.1 969.97 900000 -103359 -9269 -132560 900000 -240195 -108017 152570 -66488 -77792 -84529 49935 -64674 107172 -65303 18167 36652 26783 1592 -2007 20799 -6513 -18564 -40119 5039 -17118 -20571 -5032 -32088 -13909 -16109 15858 1716 5603 -13232 20828 -4703 17972 1963 3041 189 -2071 -2377 -4310 7807 4471 11306 482 8248 4804 141 5423 3887 1859 1767 7531 -1107 4322 -1274 4548 2095 5940 1049 4495 1190 856 866 838 1576 375 1197 -483 1654 -1358 -476 59 -201 -3503 -580 48 -811 -328 -2360 436 -2031 -273 -367 220 111 684 407 -355 596 -584 300 -661 370 -142 110 -703 -356 -670 243 -554 -1434 -624 -1190 100 -314 473 -18 443 -200 -141 574 -82 596 49 589 -310 661 63 804 658 160 -1565 291 874 137 281 -207 771 -233 -411 -594 13 307 156 -382 93 170 -324 -56 900000 -863 -34 -1500 900000 -7177 -963 566 -494 -693 -847 185 -768 398 -1297 189 361 323 27 -37 317 -131 -434 -1251 108 -480 -607 -125 -1048 -411 -577 498 72 242 -639 742 -237 857 128 233 17 -204 -248 -475 780 476 1155 57 941 606 21 842 673 339 341 1429 -235 909 -277 924 454 1369 276 1286 371 262 259 257 529 146 512 -220 732 -587 -187 21 -66 -1198 -215 21 -418 -183 -1475 281 -1435 -203 -288 177 90 529 295 -242 401 -389 221 -567 363 -153 129 -839 -396 -703 232 -538 -1511 -694 -1344 119 -409 685 -28 717 -326 -220 840 -121 872 75 924 -513 1082 100 1225 1013 238 -2279 401 1239 219 487 -394 1480 -472 -887 -1321 31 732 378 -934 220 391 -707 -118 SS 20241105T123957.5Z 9075.527749 67 1 30.87 2 79.28 122.17 121.39 102.91 0.00 1 0.00 1 0 17 4.663e-01 2.160e-02 2.712e-01 9.144e-03 5.367105e-01 4.726010e-03 6.482617e-03 -6.000000e+00 2.629372e-01 224.03 -2.00 3.51 -2.00 320.75 0.00e+00 9.089881e-03 1.910825e-03 2.106039e-03 -6.000000e+00 1.196808e-02 281.53 -2.00 20.00 -2.00 320.15 0.00e+00 5.173 0.002 302.00 328.00 3 3.7495e+00 1.4873e-02 5.8329e-02 -6.0000e+00 6.4750e-01 2.3497e-01 1.8724e-02 2.8195e-02 -6.0000e+00 7.0549e-01 -2.4550e-01 1.6862e-02 1.7905e-02 -6.0000e+00 4.2082e-01 1.0329e-01 8.4104e-03 9.5506e-03 -6.0000e+00 1.7970e-01 3.9889e-05 -1.9770e-03 2.6546e-04 1.1728e-04 -6.0000e+00 1.2762e-02 -3.5776e-04 0.0000e+00 12 9 9 12 1 1 99.97 20.56 0.17 -0.00036 -0.01521 14 6 1 5 0 2057.050 25.39 20.00 20.56 19.63 26.2 972.63 58142 36798 -59671 -57041 900000 -222539 -81135 2386 174178 -111355 18402 -633 -20932 185050 -55114 315825 22366 97839 -579 87810 31892 89268 58466 10388 18662 12947 -2453 27400 -3441 -25590 16039 10668 75540 32262 9770 19543 28210 23752 23838 27282 15333 3476 -5234 2672 15805 22703 13660 7918 13501 16490 -5328 13050 8983 2813 11154 13248 -2593 47 2730 154 12109 9794 2295 4220 2253 661 2966 -2235 -1102 967 -3896 -596 2841 -1315 3226 1435 -3499 -4518 864 -5256 -1907 -16 -1713 -878 -1592 -923 349 -503 -206 878 -1602 1007 -662 -2402 -2691 -1635 -1396 217 47 -204 171 -429 87 -1883 -1214 -1686 -1823 2 -217 1080 551 435 -440 -886 62 -397 -299 -342 925 167 1837 1876 2384 1771 1417 -4019 -523 945 856 168 698 323 649 278 -851 -370 590 229 -1003 574 -113 -1285 -353 518 328 -1216 -1090 900000 -17026 -1705 24 1553 -3698 182 -8 -407 1650 -2338 2816 598 1389 -23 1537 955 1533 1371 394 677 511 -113 916 -156 -1540 741 615 2694 1808 656 1158 1644 1687 2027 2525 1773 483 -834 406 2148 2953 1982 1244 2063 2565 -1122 2524 1961 698 2654 3165 -737 13 711 41 2960 2695 744 1493 850 245 1034 -828 -439 432 -2009 -310 1415 -648 1395 587 -1389 -1803 360 -2640 -1077 -10 -1191 -640 -1205 -741 292 -438 -179 730 -1276 748 -471 -1757 -2175 -1453 -1424 248 57 -249 201 -456 85 -1885 -1300 -1929 -2198 2 -288 1568 881 709 -719 -1435 92 -570 -429 -515 1465 280 3042 3014 3677 2658 2048 -5888 -734 1338 1305 288 1259 617 1283 582 -1864 -850 1375 545 -2420 1322 -248 -2772 -731 SS 20241105T134343.9Z 9075.572036 108 1 3.45 2 69.84 134.71 110.38 111.38 0.00 1 0.00 1 0 17 2.616e-02 6.082e-03 1.490e-02 3.169e-03 3.214225e-01 1.572583e-03 3.855978e-03 -6.000000e+00 1.473519e-02 224.03 -2.00 3.51 -2.00 318.02 0.00e+00 1.089358e-03 2.802758e-04 1.648847e-04 -6.000000e+00 6.598211e-04 281.53 -2.00 20.00 -2.00 317.31 0.00e+00 2.871 0.000 302.00 328.00 3 2.8241e+00 4.1881e-03 3.2767e-02 -6.0000e+00 3.6313e-02 2.9165e-02 4.7590e-03 1.6388e-02 -6.0000e+00 3.9555e-02 -2.6332e-03 3.0604e-03 8.1298e-03 -6.0000e+00 2.3615e-02 -3.3387e-03 1.5806e-03 2.4459e-03 -6.0000e+00 1.0085e-02 1.2439e-03 -5.4306e-04 9.0879e-05 2.6375e-05 -6.0000e+00 7.1000e-04 -3.0593e-03 0.0000e+00 12 1 1 12 1 1 60.53 20.61 0.19 -0.00306 -0.00714 10 42 1 5 0 312.880 25.39 19.99 20.61 19.73 26.1 972.42 -11410 6399 -12076 -642 -13417 -4905 -2545 -2026 -1035 -11190 1142 -7700 10 -3653 3755 -4912 4279 5 1367 1285 -62 2064 -4163 688 -3261 272 -3522 842 -2731 619 889 3170 1456 -842 -3046 -1462 493 -1519 2465 -1037 585 -878 75 -1227 654 727 -802 -432 -1027 1586 299 1740 372 758 339 1552 783 168 1498 -360 2355 664 1823 847 601 17 -176 -126 808 656 83 247 -502 43 -305 382 -1004 72 -669 -358 -1382 -1566 -1533 -1107 -967 -1070 342 -482 249 427 194 -330 582 207 448 295 97 588 -399 348 -1004 -620 -154 -92 -551 -635 -617 -537 270 83 711 308 230 96 222 195 211 534 103 -217 -434 190 228 783 398 165 106 774 157 596 -41 -90 -220 -395 -76 -189 263 168 -23 255 -288 -462 -495 -800 417 -975 -44 -937 -314 -169 -145 -82 -1033 94 -724 1 -445 494 -757 640 1 233 228 -11 369 -811 135 -712 60 -800 174 -554 121 187 725 372 -227 -797 -369 133 -473 890 -437 258 -414 36 -608 319 356 -394 -209 -496 759 154 957 214 460 207 961 499 107 956 -232 1477 458 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