File name: Pandora135s1_ManhattanNY-CCNY_20241108_L2Fit_fout2c16d20211023p1-8.txt File generation date: 20241109T044632.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20241108_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20241108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 234 376 Nominal wavelengths inside fitting window [nm]: 305.0700 305.2108 305.3516 305.4924 305.6332 305.7739 305.9147 306.0554 306.1961 306.3368 306.4775 306.6182 306.7589 306.8995 307.0402 307.1808 307.3215 307.4621 307.6027 307.7433 307.8839 308.0245 308.1650 308.3056 308.4461 308.5867 308.7272 308.8677 309.0082 309.1487 309.2892 309.4296 309.5701 309.7105 309.8510 309.9914 310.1318 310.2722 310.4126 310.5530 310.6933 310.8337 310.9740 311.1144 311.2547 311.3950 311.5353 311.6756 311.8159 311.9561 312.0964 312.2366 312.3769 312.5171 312.6573 312.7975 312.9377 313.0778 313.2180 313.3582 313.4983 313.6384 313.7786 313.9187 314.0588 314.1989 314.3389 314.4790 314.6191 314.7591 314.8991 315.0392 315.1792 315.3192 315.4591 315.5991 315.7391 315.8790 316.0190 316.1589 316.2988 316.4387 316.5786 316.7185 316.8584 316.9983 317.1381 317.2780 317.4178 317.5576 317.6974 317.8372 317.9770 318.1168 318.2565 318.3963 318.5360 318.6757 318.8155 318.9552 319.0949 319.2345 319.3742 319.5139 319.6535 319.7932 319.9328 320.0724 320.2120 320.3516 320.4912 320.6307 320.7703 320.9098 321.0494 321.1889 321.3284 321.4679 321.6074 321.7469 321.8864 322.0258 322.1653 322.3047 322.4441 322.5835 322.7229 322.8623 323.0017 323.1410 323.2804 323.4197 323.5591 323.6984 323.8377 323.9770 324.1163 324.2556 324.3948 324.5341 324.6733 324.8125 324.9517 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241108T120927.2Z 9078.506565 50 1 46.88 2 84.95 117.36 152.28 57.78 0.00 1 0.00 1 0 25 1.123e+00 5.585e-02 4.154e-01 2.320e-02 9.823468e-01 1.495823e-02 1.089226e-02 -6.000000e+00 6.850345e-01 223.77 -2.00 3.51 -2.00 322.37 0.00e+00 6.375563e-03 9.307954e-03 4.926908e-03 -6.000000e+00 4.822090e-02 281.17 -2.00 20.00 -2.00 321.93 0.00e+00 9.757 0.017 302.00 328.00 3 1.2515e-01 6.1603e-02 1.1488e-01 -6.0000e+00 1.7188e+00 2.2711e+00 6.8787e-02 6.2366e-02 -6.0000e+00 1.9077e+00 -2.8379e+00 3.9913e-02 2.7014e-02 -6.0000e+00 1.1301e+00 1.1276e+00 2.2834e-02 8.0315e-03 -6.0000e+00 4.9780e-01 8.9429e-06 -3.8547e-03 6.8195e-04 1.5210e-04 -6.0000e+00 3.6166e-02 -2.3959e-03 0.0000e+00 12 8 8 10 0 0 66.26 20.35 0.92 -0.00240 -0.03136 40 11 1 5 0 1171.900 25.17 20.01 20.35 17.33 26.0 956.45 900000 900000 900000 900000 900000 78639 343748 900000 900000 249805 900000 900000 290698 900000 194586 900000 900000 900000 900000 900000 900000 900000 -69602 133639 900000 364462 900000 900000 127995 900000 900000 270467 900000 188506 900000 900000 372447 900000 900000 307217 900000 163300 274974 85842 900000 258060 900000 900000 900000 900000 42700 151501 161160 138493 300988 900000 54963 124144 50142 122794 200641 121466 28285 89544 25916 33475 56794 21731 48114 30364 40615 46764 42343 34159 52190 62498 28498 -570 17976 21481 -4907 27087 3582 27433 -3245 6678 7258 5377 850 18734 -3797 10445 4050 -12846 -6359 -10789 -4263 -13909 -5859 -3623 -1329 -984 -2909 -7456 -2697 3291 -7764 309 -3756 3006 -3208 -391 -5650 -4562 3983 -4599 2812 -940 4002 334 7281 4332 7561 6927 2806 -14380 1333 2052 -1027 2008 1494 1926 1268 338 -1752 1297 336 596 -1739 -453 1412 -2691 -384 900000 900000 900000 900000 900000 11736 7715 900000 900000 5606 900000 900000 6524 900000 8045 900000 900000 900000 900000 900000 900000 900000 -22181 5525 900000 8180 900000 900000 3511 900000 900000 6070 900000 4231 900000 900000 8359 900000 900000 6895 900000 4479 6171 4709 900000 5792 900000 900000 900000 900000 3514 4800 4893 5485 6755 900000 4660 5244 4038 4377 4503 4490 2987 5792 3199 4021 5323 2818 5526 4429 5773 6729 6093 4825 5374 5033 2972 -82 2468 3460 -1162 5722 1005 6809 -1084 2115 2371 1824 298 5565 -1245 2965 1208 -4581 -2474 -5287 -2344 -9920 -4339 -2706 -918 -601 -1599 -4146 -1516 1859 -5198 208 -2988 2627 -3476 -459 -7333 -5881 4593 -5636 3237 -1181 5075 454 9024 5218 8390 7549 3110 -18450 1427 2315 -1404 3170 2711 3832 2737 754 -4300 3260 868 1547 -4575 -1122 3322 -6002 -787 SS 20241108T122056.0Z 9078.514537 53 1 46.65 2 83.05 119.34 150.48 61.45 0.00 1 0.00 1 0 17 5.241e-01 2.104e-02 3.192e-01 5.171e-03 8.664662e-01 2.972742e-03 9.464916e-03 -6.000000e+00 2.999561e-01 223.77 -2.00 3.51 -2.00 322.09 0.00e+00 1.041443e-02 1.846582e-03 3.135466e-03 -6.000000e+00 1.475505e-02 281.17 -2.00 20.00 -2.00 321.64 0.00e+00 7.570 0.008 302.00 328.00 3 3.8177e-01 1.2087e-02 9.3063e-02 -6.0000e+00 7.4243e-01 6.2850e-01 1.8384e-02 6.4642e-02 -6.0000e+00 8.1239e-01 -8.4077e-01 1.9549e-02 2.7007e-02 -6.0000e+00 4.8334e-01 3.4540e-01 8.7553e-03 1.3712e-02 -6.0000e+00 2.0862e-01 8.5277e-05 -1.8207e-03 1.4346e-04 1.4917e-04 -6.0000e+00 1.4995e-02 -3.4532e-03 0.0000e+00 12 8 8 10 0 0 8.95 20.35 0.33 -0.00345 -0.01713 156 44 1 5 0 299.000 25.17 20.00 20.35 17.98 25.9 961.29 900000 900000 -73643 900000 -128590 -202979 -185496 900000 -113309 -66628 -22869 900000 198974 900000 62125 -27182 900000 37556 900000 -42078 900000 -20643 -209357 -13348 41184 152544 72847 900000 -64662 59454 -39082 104689 67216 48343 18391 69831 84782 78250 127789 42982 77712 9492 58464 12582 80132 30991 62316 45680 63906 61304 20252 46824 24361 47455 23343 49386 9288 33081 14036 17656 23309 19922 19379 18858 20428 12370 25665 5734 13782 6343 12117 9529 8675 5958 2545 10147 -4963 3405 -2479 5046 -783 3369 -2660 2099 448 218 2369 459 2166 690 2722 -1638 -349 -3801 -2132 -1728 -1071 -4413 -1647 -453 -1158 -124 -1916 -481 -3008 -1292 -3103 -1920 -1370 -619 -248 -514 -244 -1307 21 -925 612 -904 630 -273 1669 1916 1499 1833 916 -651 537 1480 44 1398 280 1204 218 153 -156 -181 458 -42 -171 -318 211 -936 -1263 900000 900000 -371 900000 -941 -2879 -2207 900000 -726 -335 -115 900000 1001 900000 313 -261 900000 241 900000 -655 900000 -246 -16379 -153 283 768 403 900000 -1272 419 -840 738 812 754 370 808 896 1024 1222 1125 1603 378 1648 524 1895 1232 1882 1724 2155 2314 1177 2356 1694 2844 1880 3163 901 2482 1220 1438 1845 1814 2066 2338 2710 1794 3276 939 2327 1329 2639 2210 1985 1300 516 1699 -913 603 -541 1249 -247 1182 -1102 885 204 106 1177 239 1104 344 1248 -741 -153 -1836 -1172 -1132 -760 -3787 -1530 -424 -1026 -97 -1482 -361 -2472 -1018 -2639 -1751 -1397 -725 -331 -750 -365 -1952 30 -1282 844 -1331 967 -437 2562 2781 2087 2475 1211 -847 672 1948 68 2501 526 2436 476 360 -394 -481 1237 -114 -468 -833 509 -2104 -2724 SS 20241108T123140.8Z 9078.521999 56 1 46.70 2 81.29 121.24 148.74 64.59 0.00 1 0.00 1 0 17 5.290e-01 6.326e-03 2.160e-01 2.126e-03 7.609461e-01 1.143691e-03 8.383976e-03 -6.000000e+00 2.976952e-01 223.77 -2.00 3.51 -2.00 321.60 0.00e+00 4.989037e-03 6.198260e-04 1.123363e-03 -6.000000e+00 1.332244e-02 281.16 -2.00 20.00 -2.00 321.09 0.00e+00 6.237 0.004 302.00 328.00 3 3.8737e-01 4.1034e-03 7.3784e-02 -6.0000e+00 7.3330e-01 1.1625e-01 6.2828e-03 4.1994e-02 -6.0000e+00 7.9894e-01 -1.2000e-01 6.9886e-03 2.4021e-02 -6.0000e+00 4.7697e-01 4.1037e-02 3.2194e-03 9.8670e-03 -6.0000e+00 2.0375e-01 3.5422e-04 -9.6613e-04 5.7341e-05 1.0994e-04 -6.0000e+00 1.4356e-02 -3.7212e-03 0.0000e+00 10 0 0 10 0 0 8.87 20.36 0.30 -0.00372 -0.01098 344 97 1 5 0 135.740 25.17 20.01 20.36 18.56 25.9 964.48 -100922 -229178 -127893 -153516 -31806 -227505 -244422 -113945 -180669 -132693 -188995 -86433 -138528 47927 -101683 -12571 -19036 -18674 -8763 -50337 -22453 -59747 33831 -66513 -31185 -54939 -36381 -38474 -51048 -26347 -38972 -6053 -19025 -14505 -23320 -1649 -26594 3551 -9206 -332 1013 -5924 -2464 -6988 3193 1501 8388 -2137 8116 836 1507 3874 5649 6712 3593 7962 -285 2924 -3195 1167 -1397 4795 2872 4416 2571 2144 3758 781 3057 1264 2522 1591 1469 -592 368 -871 -2050 -2688 -650 5 -362 98 -1691 1 -1190 -155 -155 -50 289 875 981 -124 408 -111 -323 -238 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