File name: Pandora135s1_ManhattanNY-CCNY_20241201_L2Fit_fwvt1c16d20211023p1-8.txt File generation date: 20241202T045550.9Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c16p1-8 Local principal investigator: Maria Tzortziou Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 135 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora135_OF_v3d20200205.txt Instrument calibration file used: Pandora135s1_CF_v16d20211023.txt Level 1 file used: Pandora135s1_ManhattanNY-CCNY_20241201_L1_smca1c16d20211023p1-8.txt Full location name: ManhattanNY-CCNY Short location name: ManhattanNY-CCNY Country of location: USA Location latitude [deg]: 40.8153 Location longitude [deg]: -73.9505 Location altitude [m]: 34 Local noon date: 20241201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 15, but with new Reference day in spring 2023. First and last pixel inside fitting window: 1654 1804 Nominal wavelengths inside fitting window [nm]: 492.0072 492.1283 492.2493 492.3704 492.4914 492.6124 492.7334 492.8544 492.9753 493.0963 493.2172 493.3381 493.4590 493.5799 493.7007 493.8216 493.9424 494.0632 494.1840 494.3048 494.4255 494.5463 494.6670 494.7877 494.9084 495.0290 495.1497 495.2703 495.3910 495.5116 495.6321 495.7527 495.8733 495.9938 496.1143 496.2348 496.3553 496.4758 496.5962 496.7167 496.8371 496.9575 497.0779 497.1982 497.3186 497.4389 497.5592 497.6795 497.7998 497.9201 498.0403 498.1605 498.2808 498.4009 498.5211 498.6413 498.7614 498.8816 499.0017 499.1218 499.2418 499.3619 499.4819 499.6020 499.7220 499.8420 499.9619 500.0819 500.2018 500.3218 500.4417 500.5616 500.6814 500.8013 500.9211 501.0409 501.1608 501.2805 501.4003 501.5201 501.6398 501.7595 501.8792 501.9989 502.1186 502.2382 502.3578 502.4775 502.5971 502.7166 502.8362 502.9558 503.0753 503.1948 503.3143 503.4338 503.5532 503.6727 503.7921 503.9115 504.0309 504.1503 504.2696 504.3890 504.5083 504.6276 504.7469 504.8662 504.9854 505.1047 505.2239 505.3431 505.4623 505.5814 505.7006 505.8197 505.9388 506.0579 506.1770 506.2961 506.4151 506.5342 506.6532 506.7722 506.8912 507.0101 507.1291 507.2480 507.3669 507.4858 507.6047 507.7235 507.8424 507.9612 508.0800 508.1988 508.3175 508.4363 508.5550 508.6738 508.7925 508.9111 509.0298 509.1485 509.2671 509.3857 509.5043 509.6229 509.7415 509.8600 509.9785 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241201T121610.5Z 9101.511233 45 1 18.03 2 88.40 121.17 94.41 123.18 0.00 1 0.00 1 0 22 5.261e-03 5.196e-03 1.340e-03 1.333e-03 4.431794e+03 8.206044e+01 2.930404e+02 -6.000000e+00 2.914988e+02 278.56 -2.00 20.00 -2.00 505.43 0.00e+00 6.447402e-03 3.684571e-05 3.467324e-04 -6.000000e+00 1.468915e-04 278.56 -2.00 20.00 -2.00 501.15 0.00e+00 1.676662e+00 2.575824e-02 6.784097e-02 -6.000000e+00 1.045843e-01 223.00 -2.00 3.51 -2.00 502.63 0.00e+00 17.196 0.094 489.00 513.00 1 5.2952e+00 1.9670e-03 2.9715e-02 -6.0000e+00 8.0151e-03 -2.4482e-02 4.9797e-04 1.8709e-03 -6.0000e+00 2.0719e-03 6.8696e-04 -7.8201e-05 1.3681e-04 1.3278e-04 -6.0000e+00 5.5012e-04 4.6231e-02 -5.0566e-04 12 9 9 12 1 1 56.02 19.05 2.18 0.04623 0.04569 7 6 1 4 0 2252.500 23.93 20.00 19.05 2.24 24.6 852.96 900000 -1468 -1083 -525 -49 -236 458 694 900 725 322 342 -314 -699 -486 -537 -625 -288 167 217 328 684 442 273 554 516 497 297 386 -352 -777 -565 -812 131 496 281 281 253 446 -87 47 -128 6 212 444 830 869 523 386 -633 -430 -636 -1059 -1115 -774 -229 95 234 506 326 566 709 396 533 563 489 302 -221 -6 -73 -404 -493 -357 -434 -47 -123 -714 -471 -388 -744 -807 -716 -781 -528 -536 -295 -477 -58 -43 -457 -195 182 292 394 404 431 217 -45 -199 -296 -914 -980 -968 -428 7 -282 -407 -217 -236 -112 -24 22 316 451 665 723 958 877 1047 624 601 169 265 709 333 342 192 592 204 256 342 81 -127 -547 -574 -631 105 -141 -89 95 48 254 214 433 193 19 11 -362 -479 -997 -1126 900000 -1308 -939 -469 -45 -224 421 646 841 675 297 326 -297 -654 -449 -496 -582 -272 161 204 311 647 421 262 535 502 484 289 370 -332 -716 -514 -749 123 481 280 281 251 439 -86 46 -127 6 207 439 828 870 523 382 -622 -431 -624 -1026 -1079 -760 -221 94 236 514 333 578 726 410 553 583 503 306 -223 -6 -71 -394 -479 -347 -428 -46 -123 -710 -460 -373 -714 -775 -689 -757 -514 -526 -291 -474 -57 -43 -452 -193 182 297 406 417 440 218 -44 -192 -280 -895 -959 -922 -419 7 -288 -418 -220 -238 -113 -24 22 322 468 697 765 1021 942 1125 669 637 177 276 736 350 361 204 631 218 275 366 86 -134 -570 -596 -661 111 -146 -94 101 52 275 234 474 212 21 12 -389 -506 -1046 -1187 SQ 20241201T122036.8Z 9101.514315 50 1 46.69 2 87.69 121.91 93.74 123.86 0.00 1 0.00 1 0 22 4.487e-03 4.438e-03 1.320e-04 1.315e-04 4.473861e+03 8.080591e+00 3.055576e+02 -6.000000e+00 2.486478e+02 278.56 -2.00 20.00 -2.00 505.39 0.00e+00 6.353528e-03 3.626084e-06 3.440042e-04 -6.000000e+00 1.253029e-04 278.56 -2.00 20.00 -2.00 501.07 0.00e+00 1.544345e+00 2.543207e-03 6.591021e-02 -6.000000e+00 8.922302e-02 223.00 -2.00 3.51 -2.00 502.55 0.00e+00 15.273 0.066 489.00 513.00 1 2.1162e+00 1.9436e-04 2.5707e-02 -6.0000e+00 6.8378e-03 -3.4994e-02 4.9238e-05 1.6716e-03 -6.0000e+00 1.7677e-03 2.1923e-02 5.4491e-04 1.3460e-05 1.3390e-04 -6.0000e+00 4.6930e-04 4.3089e-03 -2.5751e-04 11 8 0 10 0 0 80.50 19.04 1.63 0.00431 0.00809 721 203 1 4 0 64.740 23.93 20.00 19.04 2.30 24.6 853.70 900000 -1172 -807 -307 -65 199 736 827 796 644 405 278 0 -206 -277 -471 -458 -192 175 274 126 300 379 392 507 570 428 394 214 -369 -672 -671 -604 -30 436 232 52 149 23 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768 888 988 869 687 589 408 288 501 440 262 346 311 197 391 418 135 -78 -258 -500 -322 -24 -186 -186 122 174 163 253 257 222 206 87 -245 -582 -748 -787 SQ 20241201T122344.8Z 9101.516490 54 1 46.72 2 87.19 122.43 93.28 124.34 0.00 1 0.00 1 0 22 3.910e-03 3.870e-03 1.281e-04 1.278e-04 3.921676e+03 7.784157e+00 2.710612e+02 -6.000000e+00 2.166778e+02 278.56 -2.00 20.00 -2.00 505.38 0.00e+00 5.388777e-03 3.521973e-06 2.925240e-04 -6.000000e+00 1.091932e-04 278.56 -2.00 20.00 -2.00 500.99 0.00e+00 1.516251e+00 2.476288e-03 5.654233e-02 -6.000000e+00 7.775364e-02 223.00 -2.00 3.51 -2.00 502.50 0.00e+00 14.007 0.051 489.00 513.00 1 2.2626e+00 1.8937e-04 2.2867e-02 -6.0000e+00 5.9588e-03 -2.8665e-02 4.8039e-05 1.4806e-03 -6.0000e+00 1.5405e-03 2.3029e-02 6.4952e-04 1.3102e-05 1.1361e-04 -6.0000e+00 4.0897e-04 -1.8651e-03 -2.2140e-04 11 8 0 10 0 0 99.14 19.05 1.33 -0.00187 0.00264 706 199 1 4 0 66.160 23.93 20.00 19.05 2.40 24.6 854.30 900000 -968 -662 -272 -86 176 650 750 696 604 353 248 28 -181 -209 -399 -367 -146 186 224 85 228 321 318 466 477 357 352 197 -320 -571 -570 -560 -39 410 196 8 103 39 -159 -148 -55 -11 117 286 406 413 303 154 3 -349 -569 -831 -925 -620 -242 -49 -16 84 167 340 489 490 374 414 311 162 -21 -47 -216 -362 -384 -442 -343 -48 -78 -381 -502 -423 -407 -510 -503 -583 -514 -222 -271 -299 -212 -137 -214 -195 -29 230 346 295 309 139 -114 -171 -364 -709 -867 -741 -306 -64 -266 -274 -259 -338 -157 -1 9 180 429 524 636 735 831 710 576 486 338 261 426 435 241 321 275 143 334 393 106 -58 -202 -425 -235 11 -109 -140 110 132 138 228 235 156 172 74 -220 -482 -660 -670 900000 -862 -602 -245 -80 169 611 715 667 576 334 239 27 -171 -196 -373 -345 -140 182 216 83 222 313 312 460 474 356 349 193 -307 -535 -547 -524 -37 405 198 7 104 39 -159 -147 -55 -11 117 289 414 423 308 156 3 -351 -561 -807 -896 -609 -236 -49 -16 86 172 350 506 493 378 418 323 166 -21 -47 -213 -355 -374 -433 -340 -48 -78 -380 -493 -410 -392 -491 -486 -567 -504 -219 -269 -298 -212 -136 -214 -195 -29 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