File name: Pandora56s1_MaunaLoaHI_20210428_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T142020.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20210428_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20210428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20210429T000009.9Z 7789.000114 7 1 49.78 2 24.48 262.11 178.04 234.37 0.00 1 0.00 1 0 17 8.494e-03 6.410e-03 4.144e-03 2.600e-03 1.370365e-01 1.384627e-03 1.505382e-03 -6.000000e+00 5.146945e-03 227.15 -2.00 3.11 -2.00 315.35 0.00e+00 1.505471e-04 1.233115e-04 1.483992e-05 -6.000000e+00 2.181611e-04 270.82 -2.00 20.00 -2.00 314.90 0.00e+00 1.099 0.000 302.00 328.00 3 5.8707e+00 3.5627e-03 9.2101e-03 -6.0000e+00 1.2802e-02 1.4721e-02 3.9556e-03 6.2255e-03 -6.0000e+00 1.3892e-02 4.8411e-03 2.2595e-03 3.0914e-03 -6.0000e+00 8.2259e-03 -3.6401e-03 9.8461e-04 8.8021e-04 -6.0000e+00 3.4191e-03 6.8574e-04 1.6899e-04 8.4407e-05 1.3591e-05 -6.0000e+00 2.7027e-04 5.1137e-03 -2.5035e-05 11 8 0 10 0 0 99.99 21.14 0.68 0.00511 0.00638 67 13 1 5 0 742.820 26.00 19.93 21.14 20.92 9.7 947.57 -1047 -2877 -1213 -2348 -1325 -181 665 1312 679 370 683 840 898 728 327 -259 -804 90 687 218 292 975 1215 1049 620 521 -286 -289 437 1103 2068 2253 1891 -214 -1911 -735 320 -563 -130 -873 -2026 -899 -1461 -1130 -897 -554 -1594 -302 -252 -70 947 654 1392 1173 649 999 431 428 -147 1177 1129 1029 1077 365 44 -1046 39 349 955 691 64 338 0 589 -194 -78 -20 841 620 -140 -444 -1404 -1590 -1091 -778 -658 -563 -292 -434 -32 -306 77 504 795 1384 449 844 366 -116 -149 -578 -119 -191 602 -553 -1089 -417 -888 130 271 -81 26 -31 29 17 305 296 738 18 -58 -433 -267 301 223 923 394 941 1354 865 449 -91 -239 -116 192 -132 -184 -291 -15 -64 -324 38 -172 -560 -320 -939 -386 -705 -363 -47 176 375 211 119 217 270 307 273 132 -111 -357 40 312 101 137 453 569 508 311 267 -145 -140 196 473 885 999 872 -101 -895 -337 153 -310 -82 -621 -1580 -723 -1206 -934 -734 -445 -1257 -229 -185 -50 692 501 1105 967 550 856 375 370 -127 1000 985 949 1036 366 43 -987 33 291 819 641 64 352 0 607 -189 -70 -17 645 481 -116 -407 -1394 -1683 -1211 -901 -813 -723 -386 -576 -42 -372 87 521 776 1365 472 964 449 -151 -192 -712 -139 -214 681 -674 -1396 -556 -1221 184 400 -122 39 -46 40 22 367 349 893 24 -79 -615 -382 418 299 1184 482 1107 1559 1031 562 -118 -316 -155 263 -187 -275 -443 -23 -100 -504 58 -256 -824 SU 20210429T000145.9Z 7789.001226 9 1 9.82 2 24.86 262.35 178.32 227.32 0.00 1 0.00 1 0 25 7.734e-03 6.611e-03 5.365e-04 4.367e-04 1.353809e-01 2.380793e-04 1.497031e-03 -6.000000e+00 4.686477e-03 227.15 -2.00 3.11 -2.00 313.88 0.00e+00 1.602099e-04 1.614679e-05 1.686148e-05 -6.000000e+00 1.986435e-04 270.82 -2.00 20.00 -2.00 313.54 0.00e+00 1.102 0.000 302.00 328.00 3 1.9921e+00 6.0484e-04 9.1639e-03 -6.0000e+00 1.1657e-02 1.0525e-03 6.6743e-04 6.1437e-03 -6.0000e+00 1.2649e-02 2.6789e-03 3.8287e-04 3.0508e-03 -6.0000e+00 7.4900e-03 -2.8573e-03 1.6112e-04 8.6949e-04 -6.0000e+00 3.1132e-03 3.3411e-02 4.8124e-05 1.3947e-05 1.4609e-05 -6.0000e+00 2.4610e-04 4.9912e-03 -2.9497e-05 12 9 1 12 1 1 99.93 21.13 0.34 0.00499 0.00535 103 107 1 5 0 92.780 26.00 20.02 21.13 20.82 9.7 946.30 -402 -1366 -1871 -2403 -1347 524 1343 1553 1107 -341 -474 459 511 506 350 -208 -267 284 441 425 519 633 1283 693 467 301 -413 -471 607 1487 1620 1462 874 -793 -1388 -207 -156 -229 -119 -1097 -1576 -1255 -1219 -1092 -835 -711 -925 -574 -151 426 924 779 954 833 568 646 506 192 295 680 948 1141 882 208 -430 -701 121 346 1121 995 -60 -31 -255 81 14 5 594 674 889 43 -654 -1297 -1617 -1347 -834 -838 -691 -332 -598 -330 -115 265 545 1110 1271 842 624 279 -241 -489 -338 -165 288 583 -298 -944 -720 -661 -306 36 -65 -285 -157 94 260 702 755 680 309 -161 -443 -247 75 189 663 677 827 1397 889 306 -10 -223 -120 220 -141 -300 -271 -111 -262 -320 -152 -216 -368 -187 -675 -921 -1109 -599 218 572 717 517 -167 -231 223 264 269 203 -128 -159 172 271 267 328 399 812 455 317 209 -283 -305 385 898 984 923 542 -501 -900 -131 -100 -158 -90 -910 -1358 -1124 -1114 -1001 -759 -636 -805 -503 -127 351 776 685 874 754 528 607 480 182 277 636 908 1099 903 213 -435 -691 114 312 1037 962 -63 -33 -273 84 14 5 547 581 769 40 -651 -1348 -1719 -1505 -944 -972 -845 -402 -729 -405 -137 299 583 1121 1301 887 719 336 -294 -594 -408 -186 324 665 -350 -1139 -908 -834 -400 47 -88 -387 -205 119 313 817 860 798 372 -208 -573 -321 95 241 796 803 974 1609 1015 368 -12 -276 -151 282 -183 -393 -368 -153 -367 -445 -205 -284 -495 SU 20210429T000351.7Z 7789.002682 11 1 51.47 2 25.35 262.67 178.62 214.11 0.00 1 0.00 1 0 25 7.751e-03 6.406e-03 1.088e-04 8.164e-05 1.353136e-01 4.408314e-05 1.487472e-03 -6.000000e+00 4.696855e-03 227.15 -2.00 3.11 -2.00 314.38 0.00e+00 1.182183e-04 3.284267e-06 1.289770e-05 -6.000000e+00 1.990886e-04 270.82 -2.00 20.00 -2.00 314.00 0.00e+00 1.106 0.000 302.00 328.00 3 7.0407e-02 1.1242e-04 9.1747e-03 -6.0000e+00 1.1683e-02 -1.2678e-02 1.2438e-04 6.1281e-03 -6.0000e+00 1.2677e-02 4.0375e-03 7.1147e-05 3.0423e-03 -6.0000e+00 7.5066e-03 -3.4437e-03 3.0249e-05 8.6265e-04 -6.0000e+00 3.1200e-03 2.2861e-01 -1.2847e-05 2.6156e-06 1.4158e-05 -6.0000e+00 2.4665e-04 4.9976e-03 -3.8943e-05 11 8 0 10 0 0 97.44 21.12 0.37 0.00500 0.00490 3808 752 1 5 0 12.950 26.00 20.01 21.12 20.77 9.8 946.47 -364 -1461 -1986 -2512 -1410 473 1155 1551 1056 -316 -486 476 674 474 326 -260 -429 258 461 449 524 616 1242 807 670 423 -335 -510 535 1441 1563 1466 856 -797 -1511 -309 -271 -212 -77 -1039 -1497 -1209 -1109 -1001 -840 -588 -911 -533 -186 386 1007 760 965 909 612 676 525 188 286 781 985 1171 915 281 -505 -719 72 325 1189 970 -31 -30 -221 68 31 75 511 665 898 133 -604 -1291 -1578 -1302 -828 -859 -674 -342 -501 -293 -113 253 501 1095 1278 806 669 265 -295 -482 -380 -216 248 643 -321 -883 -682 -633 -245 21 -6 -261 -163 64 226 702 732 711 301 -169 -454 -228 37 200 610 721 865 1386 861 314 -40 -235 -121 180 -107 -305 -214 -107 -228 -278 -145 -202 -314 -139 -592 -802 -1038 -524 164 412 599 442 -127 -212 208 286 221 166 -141 -239 146 265 263 310 363 735 495 393 253 -198 -309 300 768 838 817 497 -472 -867 -173 -162 -134 -57 -817 -1283 -1079 -1008 -914 -761 -524 -791 -443 -149 303 803 635 841 822 568 636 499 179 268 730 881 1104 918 293 -523 -694 68 294 1103 920 -33 -33 -243 72 31 74 450 548 744 120 -563 -1321 -1725 -1403 -944 -1046 -814 -425 -627 -355 -136 276 530 1090 1291 876 746 322 -357 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