File name: Pandora56s1_MaunaLoaHI_20210628_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T141042.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20210628_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20210628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210628T165427.2Z 7849.704482 286 1 50.41 2 76.14 69.89 55.19 231.47 0.00 1 0.00 1 0 25 1.052e-01 7.104e-03 9.715e-02 4.373e-03 4.747285e-01 2.334595e-03 4.889969e-03 -6.000000e+00 6.347393e-02 226.21 -2.00 3.11 -2.00 319.93 0.00e+00 1.478218e-03 7.188926e-04 5.266067e-04 -6.000000e+00 2.716003e-03 272.23 -2.00 20.00 -2.00 319.44 0.00e+00 4.090 0.000 302.00 328.00 3 4.8155e+00 6.6533e-03 3.3329e-02 -6.0000e+00 1.5746e-01 -2.6905e-02 7.9443e-03 2.2291e-02 -6.0000e+00 1.7096e-01 1.4881e-02 6.9636e-03 1.1129e-02 -6.0000e+00 1.0139e-01 -1.3438e-02 3.6143e-03 3.6884e-03 -6.0000e+00 4.2257e-02 1.9208e-04 -4.8077e-04 1.4231e-04 4.5874e-05 -6.0000e+00 3.3466e-03 5.9334e-03 -1.3447e-04 11 9 0 11 8 0 25.86 20.70 0.51 0.00593 0.00232 13 3 1 5 0 3876.340 25.68 20.00 20.70 17.92 10.7 713.43 -72140 29540 26238 -21212 4559 -33751 -28815 -41398 -25408 -25526 -3490 8748 -21125 -856 -4220 -28449 -449 7403 1259 -10469 -10344 2882 -4114 10348 -2745 -15073 -886 -7457 12300 -1842 7178 15479 931 -1571 -6619 3874 -6918 1831 -5858 5179 -1573 -3689 -3482 -2878 1833 2642 2580 2881 469 -2198 203 -1082 958 981 86 183 -315 -881 2187 1697 3341 3143 692 1339 143 -897 -168 1499 1448 1730 624 -1171 815 -90 812 469 -436 1258 214 1977 -785 -982 -1370 -1442 -1089 -993 -262 -692 1142 258 -726 -92 150 942 573 436 649 171 -156 -368 -281 -80 6 562 -285 -1051 -1259 -371 -236 -65 196 -631 -169 540 50 746 995 556 -375 -711 -1222 504 152 41 543 295 855 904 1174 448 124 -464 94 423 -642 195 -52 90 -408 23 95 -478 -73 -1494 260 250 -314 50 -533 -464 -837 -494 -528 -62 154 -590 -24 -145 -1416 -19 313 60 -585 -595 148 -236 550 -178 -1156 -59 -523 708 -126 500 1127 87 -158 -694 370 -806 226 -936 868 -311 -800 -787 -663 408 597 581 655 112 -564 55 -323 304 329 31 67 -119 -335 805 626 1252 1260 313 652 72 -450 -81 721 749 984 388 -776 530 -57 474 253 -220 622 113 1164 -536 -745 -1124 -1262 -1000 -969 -264 -720 1168 261 -695 -82 128 796 514 434 720 210 -204 -486 -353 -94 6 615 -331 -1290 -1615 -501 -337 -99 318 -1064 -283 867 77 1092 1437 832 -590 -1160 -2033 810 240 63 797 420 1172 1254 1725 716 212 -834 173 807 -1294 405 -110 194 -890 48 196 -948 -142 SS 20210628T165651.6Z 7849.706152 288 1 51.55 2 75.61 70.04 55.62 231.91 0.00 1 0.00 1 0 25 7.567e-02 6.598e-03 8.506e-02 4.075e-03 4.617491e-01 2.170202e-03 4.774277e-03 -6.000000e+00 4.569120e-02 226.21 -2.00 3.11 -2.00 319.80 0.00e+00 4.045143e-04 6.410143e-04 2.413636e-04 -6.000000e+00 1.954710e-03 272.23 -2.00 20.00 -2.00 319.30 0.00e+00 3.947 0.000 302.00 328.00 3 4.8041e+00 6.1458e-03 3.2147e-02 -6.0000e+00 1.1335e-01 -1.9668e-02 7.2741e-03 2.1227e-02 -6.0000e+00 1.2305e-01 5.7947e-03 6.1960e-03 1.0770e-02 -6.0000e+00 7.2978e-02 -1.0133e-02 3.2293e-03 3.2064e-03 -6.0000e+00 3.0425e-02 2.1507e-04 -2.8356e-04 1.3274e-04 4.3115e-05 -6.0000e+00 2.4078e-03 5.3400e-03 -6.6209e-05 11 8 0 10 0 0 37.70 20.71 0.29 0.00534 0.00321 14 3 1 5 0 3681.030 25.68 20.02 20.71 18.11 10.7 714.75 799 36390 -25108 -6379 -2324 -29637 24862 16873 13075 -38457 7716 -3051 -16600 776 -19172 11681 -2632 6766 87 -6545 8573 -21563 6508 -17021 -6122 -5466 -2986 557 7470 6635 8356 -989 -6851 -8027 -875 1884 -4246 -2349 874 -1291 -4344 2618 -4609 3138 213 -1892 2241 -2507 3077 -1352 2252 93 -582 1365 281 1268 759 -216 -610 1943 1567 2318 3264 1007 1465 455 569 866 712 1928 182 33 -576 -43 -382 344 851 210 -123 -407 -847 -909 -1420 -1035 -833 -777 -1036 -246 -791 -26 534 560 1595 244 1890 745 590 51 -133 -121 -338 -119 -762 301 -802 -1336 -577 -892 341 259 -106 121 -212 423 201 621 57 644 -89 -642 -704 -380 457 -359 486 644 933 1140 373 537 -30 -346 535 -31 -41 -123 -180 -8 -25 -277 -260 122 -189 10 362 -471 -97 -32 -532 286 233 209 -1082 149 -72 -518 25 -867 450 -127 326 5 -396 465 -1591 383 -1343 -464 -431 -232 41 505 469 641 -93 -753 -936 -94 199 -522 -327 141 -250 -957 584 -1138 741 52 -479 547 -638 756 -363 636 29 -197 484 106 491 302 -87 -242 749 625 988 1495 509 759 232 282 431 381 1134 118 23 -394 -28 -235 191 441 107 -67 -249 -586 -697 -1191 -910 -779 -763 -1073 -260 -841 -27 515 509 1354 209 1697 746 661 62 -175 -160 -426 -140 -856 334 -934 -1659 -740 -1202 487 396 -173 203 -353 678 308 907 83 958 -138 -1042 -1161 -615 720 -549 713 913 1276 1572 548 849 -51 -613 978 -58 -82 -254 -380 -18 -53 -584 -531 240 -365 SS 20210628T165913.2Z 7849.707792 290 1 48.84 2 75.09 70.19 56.05 232.34 0.00 1 0.00 1 0 25 7.704e-02 7.352e-03 6.920e-02 3.900e-03 4.474827e-01 2.071941e-03 4.632006e-03 -6.000000e+00 4.651053e-02 226.21 -2.00 3.11 -2.00 319.69 0.00e+00 6.265682e-04 5.918044e-04 4.243704e-04 -6.000000e+00 1.989967e-03 272.23 -2.00 20.00 -2.00 319.19 0.00e+00 3.817 0.000 302.00 328.00 3 4.7975e+00 5.8332e-03 3.1154e-02 -6.0000e+00 1.1538e-01 -2.6628e-02 6.8557e-03 2.0706e-02 -6.0000e+00 1.2527e-01 7.7137e-03 5.7180e-03 1.0386e-02 -6.0000e+00 7.4291e-02 -8.2658e-03 2.9892e-03 3.1401e-03 -6.0000e+00 3.0967e-02 2.3831e-04 -4.1652e-04 1.2710e-04 4.0982e-05 -6.0000e+00 2.4516e-03 5.7472e-03 -9.4025e-05 11 8 0 10 0 0 33.86 20.73 0.41 0.00575 0.00262 14 3 1 5 0 3488.000 25.68 20.03 20.73 18.37 10.7 715.66 -24879 -46533 11725 -13311 -3801 -14960 13730 8606 32020 4134 -28123 22707 17875 3137 -14603 -5272 7659 -13619 15255 -5709 1674 4882 -8988 4752 -15094 10450 -2576 3703 5930 4100 5013 -16924 3227 -6536 1349 4296 445 1538 -2451 1266 -3119 402 -4492 -1728 1211 163 -564 410 1262 230 876 1276 -528 2972 -171 1237 1059 -146 -919 336 1701 1352 2612 442 828 1262 -1163 129 -85 1308 517 421 -204 -69 522 -1406 1514 68 613 -488 -2120 -114 -1477 -1354 -1011 -923 12 -469 150 214 243 554 611 1714 1396 1233 363 745 -116 -4 -596 -464 393 729 -569 -1841 -984 -764 -248 567 -467 -360 -705 -117 650 241 1258 247 395 -398 -723 -345 -29 764 220 334 727 1643 627 -48 179 -543 658 -255 108 -368 -52 250 -518 -177 15 51 -150 -450 -1173 174 -247 -61 -265 198 146 479 87 -853 468 448 108 -702 -264 375 -877 792 -378 106 304 -670 330 -1368 767 -217 285 437 322 425 -2009 345 -806 152 476 56 221 -438 255 -724 97 -1179 -451 310 43 -148 108 334 64 261 412 -188 1089 -67 496 434 -61 -379 138 710 602 1260 232 445 666 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