File name: Pandora56s1_MaunaLoaHI_20210630_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T184713.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20210630_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20210630 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210630T185313.2Z 7851.786959 279 1 51.70 2 49.49 75.79 54.28 246.53 0.00 1 0.00 1 0 17 8.074e-03 5.332e-03 3.687e-03 1.832e-03 1.917834e-01 9.677806e-04 2.080336e-03 -6.000000e+00 4.879477e-03 226.15 -2.00 3.11 -2.00 316.19 0.00e+00 1.622194e-04 1.039197e-04 6.896824e-05 -6.000000e+00 2.085436e-04 272.21 -2.00 20.00 -2.00 315.68 0.00e+00 1.537 0.000 302.00 328.00 3 5.4945e+00 2.5036e-03 1.2823e-02 -6.0000e+00 1.2104e-02 -6.1946e-03 2.7902e-03 8.6215e-03 -6.0000e+00 1.3135e-02 1.6344e-03 1.6109e-03 4.2913e-03 -6.0000e+00 7.7903e-03 -4.2971e-03 7.3404e-04 1.2208e-03 -6.0000e+00 3.2527e-03 6.8662e-04 -3.1311e-04 5.9559e-05 1.7596e-05 -6.0000e+00 2.5680e-04 -9.6686e-03 0.0000e+00 10 0 0 10 0 0 96.09 22.03 0.38 -0.00967 -0.01202 16 3 1 5 0 3230.470 26.73 20.00 22.03 21.25 10.4 723.61 -1034 -2672 -590 -2087 -1300 -822 -1899 1003 2407 -67 -801 -1362 104 638 1561 781 -1708 552 623 637 62 625 1610 62 -69 -496 192 -1079 -244 -315 1518 -199 1549 -170 -2633 -1492 -1184 -1043 821 -388 -673 -626 -447 -424 -313 317 -903 -535 -212 176 819 895 1227 1049 627 546 472 535 165 461 603 1291 1058 796 157 -295 -80 -496 412 836 762 212 104 -54 -133 -49 -467 -596 -185 -640 -641 -1228 -1302 -1860 -1020 -825 -292 460 -347 396 -190 173 -3 62 454 447 633 378 287 -135 -142 -858 -771 197 -323 -590 -459 -502 -246 444 507 412 484 261 37 -85 48 313 165 136 -61 -72 97 227 314 532 488 508 527 342 -179 -200 -390 155 -292 -393 -77 267 329 -135 -47 -357 -495 -207 -582 -129 -437 -247 -148 -358 200 516 -15 -186 -325 26 179 472 256 -598 194 225 236 23 235 608 24 -28 -208 79 -436 -92 -115 554 -78 625 -71 -1087 -602 -508 -502 447 -241 -452 -442 -323 -308 -227 226 -637 -365 -142 117 557 630 905 808 491 436 381 431 132 367 491 1104 953 740 148 -264 -67 -410 343 760 731 215 106 -54 -127 -43 -381 -466 -146 -539 -589 -1224 -1371 -2047 -1166 -990 -362 587 -448 501 -230 194 -3 63 464 485 741 470 373 -176 -179 -1036 -899 230 -396 -760 -611 -688 -351 652 764 629 717 373 50 -108 60 404 219 190 -88 -106 139 317 424 690 605 629 664 448 -243 -280 -558 224 -438 -611 -124 431 537 -218 -74 -554 -764 SS 20210630T185847.2Z 7851.790824 282 1 50.02 2 48.21 75.97 55.45 247.36 0.00 1 0.00 1 0 17 7.893e-03 6.003e-03 2.198e-03 1.155e-03 1.866980e-01 6.121626e-04 2.033712e-03 -6.000000e+00 4.773135e-03 226.15 -2.00 3.11 -2.00 316.06 0.00e+00 3.570055e-04 6.362659e-05 9.981454e-05 -6.000000e+00 2.038301e-04 272.21 -2.00 20.00 -2.00 315.56 0.00e+00 1.498 0.000 302.00 328.00 3 4.7751e+00 1.5801e-03 1.2490e-02 -6.0000e+00 1.1841e-02 -3.0361e-02 1.7604e-03 8.3867e-03 -6.0000e+00 1.2846e-02 1.7815e-03 1.0139e-03 4.1753e-03 -6.0000e+00 7.6187e-03 -2.9399e-03 4.5692e-04 1.1923e-03 -6.0000e+00 3.1843e-03 1.4682e-03 -9.8397e-04 3.7577e-05 1.7464e-05 -6.0000e+00 2.5101e-04 -1.5816e-02 0.0000e+00 10 0 0 10 0 0 98.65 22.10 0.43 -0.01582 -0.02321 31 6 1 5 0 1613.040 26.83 20.01 22.10 21.01 10.4 722.94 -815 -973 327 -1620 -1336 -1332 1161 861 395 -368 -779 -440 -537 -282 820 4 -346 107 1195 747 202 979 1441 1353 589 439 -2 -628 -330 -215 231 550 179 -1142 -2868 -2374 -2107 -1305 -399 -177 -1149 -635 -586 -408 -504 64 -441 -361 -172 -184 628 783 1248 1404 1050 966 889 257 53 179 456 1094 1522 1292 534 -491 -378 -799 152 1043 695 558 254 450 304 -105 -436 -1268 -1047 -1141 -1144 -1298 -1598 -1322 -918 -486 -84 361 336 166 -26 -449 -959 -880 -132 407 624 555 425 249 -261 -781 -877 -45 -315 -850 -536 -381 -32 553 852 662 663 498 -42 -247 -225 173 21 136 -130 216 240 235 424 440 8 274 429 324 176 -452 -471 -264 -421 -189 -211 385 243 113 115 -253 -631 -183 -235 79 -377 -283 -268 234 189 95 -93 -199 -114 -149 -87 252 1 -121 39 436 281 78 373 553 537 246 188 -1 -258 -127 -80 86 215 74 -487 -1206 -976 -916 -640 -227 -115 -764 -443 -419 -295 -363 45 -309 -245 -113 -131 455 545 909 1066 824 772 721 210 43 144 374 942 1393 1243 517 -455 -323 -659 128 948 691 586 250 467 299 -95 -357 -980 -811 -956 -1060 -1323 -1619 -1411 -1036 -583 -106 472 442 214 -31 -501 -984 -924 -140 424 712 692 564 333 -336 -945 -1011 -52 -385 -1110 -733 -504 -44 796 1274 1008 982 695 -55 -321 -285 223 29 184 -184 307 335 317 585 576 10 336 542 432 246 -609 -647 -373 -622 -293 -339 631 378 186 185 -395 -969 SS 20210630T191813.5Z 7851.804323 292 1 49.86 2 43.76 76.54 59.60 250.07 0.00 1 0.00 1 0 17 6.975e-03 5.420e-03 3.751e-04 2.331e-04 1.703318e-01 1.244573e-04 1.872198e-03 -6.000000e+00 4.216180e-03 226.15 -2.00 3.11 -2.00 315.32 0.00e+00 1.331757e-04 1.115812e-05 4.184994e-05 -6.000000e+00 1.801450e-04 272.21 -2.00 20.00 -2.00 314.85 0.00e+00 1.383 0.000 302.00 328.00 3 1.8950e+00 3.1958e-04 1.1490e-02 -6.0000e+00 1.0459e-02 -2.2614e-02 3.5453e-04 7.6921e-03 -6.0000e+00 1.1349e-02 3.3132e-03 2.0290e-04 3.8308e-03 -6.0000e+00 6.7308e-03 -3.6338e-03 8.9300e-05 1.0879e-03 -6.0000e+00 2.8113e-03 2.8951e-02 -7.1806e-04 7.5077e-06 1.6929e-05 -6.0000e+00 2.2183e-04 -1.1745e-02 0.0000e+00 10 0 0 10 0 0 98.93 22.19 0.37 -0.01175 -0.01714 599 118 1 5 0 83.220 26.83 20.00 22.19 20.80 10.5 722.93 -92 -966 -1356 -2185 -1994 -111 429 1188 1153 -7 -743 -151 349 396 454 96 -401 269 444 478 689 434 1098 818 907 673 -1 -523 -23 672 774 922 658 -673 -2239 -1472 -1031 -839 -230 -768 -1226 -973 -828 -727 -660 -269 -621 -465 -202 65 873 840 1098 1083 820 792 720 297 162 604 828 1237 1240 848 140 -661 -234 -216 649 1103 350 294 30 272 203 -79 -45 -195 19 -288 -669 -1170 -1488 -1381 -904 -689 -481 -97 -239 -108 -171 -82 -148 177 741 638 646 473 121 -193 -314 -461 -359 223 -220 -831 -682 -538 -226 184 368 225 192 225 108 254 337 410 196 -3 -266 -138 144 256 539 645 538 936 776 387 49 -258 -328 -83 -157 -201 -189 -2 19 -132 -83 -202 -509 -26 -293 -415 -636 -529 -27 108 324 342 -2 -235 -48 118 148 187 43 -170 116 196 216 315 199 507 391 451 344 -1 -254 -11 317 369 421 315 -331 -1083 -696 -516 -477 -152 -541 -949 -790 -688 -609 -550 -221 -500 -361 -152 48 658 665 909 934 678 666 612 253 137 507 711 1115 1191 854 141 -632 -206 -182 558 1033 359 297 31 271 205 -73 -41 -164 16 -264 -630 -1213 -1547 -1513 -1047 -798 -587 -122 -304 -133 -211 -93 -153 185 782 674 747 562 152 -244 -381 -559 -415 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