File name: Pandora56s1_MaunaLoaHI_20210703_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T184739.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20210703_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20210703 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210703T184353.2Z 7854.780476 248 1 51.13 2 51.77 75.73 18.13 238.52 0.00 1 0.00 1 0 17 8.931e-03 5.807e-03 3.167e-03 1.495e-03 2.050281e-01 7.916304e-04 2.232484e-03 -6.000000e+00 5.397982e-03 226.06 -2.00 3.11 -2.00 316.36 0.00e+00 2.997777e-04 8.855570e-05 1.136231e-04 -6.000000e+00 2.306229e-04 272.18 -2.00 20.00 -2.00 315.84 0.00e+00 1.613 0.000 302.00 328.00 3 5.1067e+00 2.0512e-03 1.3588e-02 -6.0000e+00 1.3388e-02 -1.8274e-02 2.2833e-03 9.2347e-03 -6.0000e+00 1.4527e-02 3.1833e-04 1.3276e-03 4.6003e-03 -6.0000e+00 8.6163e-03 -4.7603e-03 6.1260e-04 1.3114e-03 -6.0000e+00 3.6003e-03 9.4532e-04 -5.1781e-04 4.8673e-05 1.8556e-05 -6.0000e+00 2.8403e-04 -1.3454e-02 0.0000e+00 10 0 0 10 0 0 99.60 21.15 0.42 -0.01345 -0.01734 21 4 1 5 0 2434.290 26.11 20.02 21.15 17.02 10.5 706.85 -305 -1152 -2516 -3735 -2722 -2312 146 746 878 -1177 -1608 -622 729 432 1235 -41 -375 18 809 700 1248 1153 1678 958 538 247 -351 -1141 730 472 1054 353 976 -1333 -2161 -1390 -1320 -1087 220 -444 -1147 -1038 -524 -865 -443 -83 -700 -577 -43 18 840 852 1279 1288 900 1256 1201 419 127 293 783 1291 1517 1589 63 -504 -394 -739 373 828 625 513 177 131 200 -193 -447 -800 -722 -791 -955 -1406 -1514 -1382 -946 -546 -182 145 111 -57 -246 -371 -461 -332 26 286 485 776 295 -104 -154 -595 -826 70 -314 -817 -429 -324 -52 670 514 601 475 651 -38 78 156 452 -58 211 -188 -77 219 206 450 486 362 444 800 300 -158 -542 -478 -168 -438 -338 -122 313 219 -163 131 -180 -452 -57 -233 -523 -745 -492 -397 25 140 179 -256 -355 -139 174 115 364 -13 -127 6 262 233 419 389 571 340 200 95 -134 -419 273 171 389 139 364 -519 -823 -570 -524 -491 115 -269 -768 -731 -377 -632 -321 -59 -495 -396 -29 12 568 607 955 1005 728 945 915 322 96 222 604 1048 1314 1443 58 -442 -320 -581 299 725 597 517 181 131 187 -166 -380 -642 -585 -696 -855 -1390 -1607 -1548 -1122 -635 -223 184 141 -71 -287 -430 -491 -335 27 316 587 946 383 -136 -193 -700 -1002 84 -374 -1040 -570 -450 -76 1014 755 897 691 956 -52 100 194 574 -79 303 -282 -116 322 293 607 622 443 579 992 395 -219 -780 -702 -253 -692 -522 -194 509 360 -266 207 -277 -682 SS 20210703T185022.1Z 7854.784978 252 1 49.79 2 50.29 75.96 19.42 241.32 0.00 1 0.00 1 0 17 8.257e-03 6.165e-03 1.991e-03 9.945e-04 1.989446e-01 5.253291e-04 2.171273e-03 -6.000000e+00 4.992828e-03 226.06 -2.00 3.11 -2.00 316.22 0.00e+00 3.387870e-04 5.677623e-05 1.233279e-04 -6.000000e+00 2.132119e-04 272.18 -2.00 20.00 -2.00 315.72 0.00e+00 1.562 0.000 302.00 328.00 3 4.4121e+00 1.3597e-03 1.3168e-02 -6.0000e+00 1.2384e-02 -3.1439e-02 1.5156e-03 8.9504e-03 -6.0000e+00 1.3435e-02 -9.7216e-04 8.7510e-04 4.4552e-03 -6.0000e+00 7.9684e-03 -2.5867e-03 3.9806e-04 1.2661e-03 -6.0000e+00 3.3317e-03 1.9840e-03 -1.1301e-03 3.2208e-05 1.8463e-05 -6.0000e+00 2.6258e-04 -1.7344e-02 0.0000e+00 10 0 0 10 0 0 99.91 21.21 0.38 -0.01734 -0.02584 50 10 1 5 0 995.630 26.11 20.02 21.21 17.29 10.5 708.22 -1381 -541 -1337 -1474 -1464 -443 321 452 796 -706 -664 -888 -351 244 246 394 -274 793 763 529 1025 775 1271 568 713 1225 -76 -724 -563 564 257 768 277 -770 -3073 -2916 -2336 -1360 -440 -503 -974 -677 -666 -510 -786 -228 -308 -346 -88 -76 1033 681 1339 1302 1158 1176 970 467 19 314 581 1239 1613 1374 649 -700 -356 -884 418 1168 564 584 178 427 118 -380 -504 -1311 -1054 -1225 -972 -1471 -1504 -1383 -703 -577 -104 271 115 201 -113 -469 -1050 -847 -99 152 542 647 470 287 -250 -605 -663 126 -261 -840 -614 -373 -10 491 889 792 651 468 -127 17 -38 22 39 -40 -43 -24 299 335 438 531 147 329 398 349 -103 -565 -601 -484 -267 -126 -117 239 261 99 149 -87 -582 -286 -120 -302 -317 -288 -82 60 92 177 -167 -158 -216 -91 70 72 124 -91 269 267 190 372 283 467 218 285 500 -31 -286 -209 200 93 291 111 -319 -1266 -1179 -994 -652 -245 -296 -634 -463 -469 -362 -560 -160 -212 -232 -57 -49 677 472 970 986 906 938 785 380 16 252 476 1064 1475 1323 632 -654 -307 -736 353 1070 525 573 177 415 118 -348 -419 -1028 -828 -1043 -914 -1411 -1550 -1506 -807 -707 -125 336 144 246 -140 -535 -1104 -841 -99 163 635 829 596 368 -309 -754 -785 149 -327 -1046 -802 -508 -15 728 1373 1162 1000 678 -171 21 -50 30 51 -56 -63 -36 433 469 582 670 192 420 523 449 -140 -796 -864 -716 -412 -191 -183 383 424 159 234 -133 -933 SS 20210703T185533.9Z 7854.788586 255 1 49.53 2 49.10 76.15 20.48 243.34 0.00 1 0.00 1 0 17 7.678e-03 5.936e-03 1.155e-03 6.060e-04 1.928518e-01 3.214910e-04 2.110101e-03 -6.000000e+00 4.643104e-03 226.06 -2.00 3.11 -2.00 315.97 0.00e+00 2.809140e-04 3.293155e-05 1.091695e-04 -6.000000e+00 1.982551e-04 272.18 -2.00 20.00 -2.00 315.48 0.00e+00 1.525 0.000 302.00 328.00 3 3.5510e+00 8.2980e-04 1.2808e-02 -6.0000e+00 1.1516e-02 -3.3733e-02 9.2299e-04 8.6735e-03 -6.0000e+00 1.2493e-02 -4.5596e-04 5.3168e-04 4.3193e-03 -6.0000e+00 7.4100e-03 -2.5880e-03 2.4133e-04 1.2266e-03 -6.0000e+00 3.0987e-03 4.8636e-03 -1.2663e-03 1.9577e-05 1.8044e-05 -6.0000e+00 2.4416e-04 -1.8193e-02 0.0000e+00 11 1 0 11 8 0 99.90 21.25 0.32 -0.01819 -0.02771 120 24 1 5 0 412.670 26.11 20.01 21.25 17.47 10.5 708.76 458 -740 -991 -1854 -1564 -261 -101 846 1003 -35 -1380 -458 10 317 507 186 -433 3 378 778 859 442 1105 885 801 771 293 -1005 -380 114 184 279 349 -794 -2806 -2249 -2056 -1355 -588 -630 -1152 -831 -522 -511 -422 -65 -373 -108 -185 235 785 972 1050 1373 1044 1140 843 459 34 420 675 1396 1362 1375 481 -689 -495 -694 308 1178 609 518 265 377 338 -209 -600 -977 -681 -957 -1034 -1301 -1439 -1432 -772 -538 -184 367 82 67 -178 -381 -841 -786 -19 233 628 734 469 4 -272 -669 -670 -30 -218 -805 -583 -397 -129 386 849 693 623 479 140 -34 10 196 135 22 -169 -31 267 226 526 458 204 418 546 281 -51 -365 -658 -389 -350 -248 -162 208 270 116 96 -105 -556 94 -165 -225 -404 -342 -53 -21 190 245 -8 -332 -111 3 91 162 64 -158 1 144 304 340 176 443 368 347 344 130 -433 -153 44 72 115 151 -355 -1243 -972 -938 -698 -323 -399 -807 -612 -394 -391 -322 -49 -276 -77 -129 161 551 716 814 1108 804 895 672 367 27 332 543 1176 1227 1300 460 -631 -420 -565 255 1054 599 539 281 389 329 -187 -530 -809 -564 -792 -948 -1314 -1564 -1527 -868 -645 -233 480 101 87 -217 -427 -932 -824 -20 262 717 917 583 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