File name: Pandora56s1_MaunaLoaHI_20211121_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T195418.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20211121_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20211121 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211121T170402.7Z 7995.711142 245 1 50.54 2 84.35 113.62 71.33 290.96 0.00 1 0.00 1 0 25 7.706e-01 1.591e-02 4.697e-01 1.074e-02 8.780234e-01 6.341941e-03 8.270673e-03 -6.000000e+00 4.708016e-01 223.65 -2.00 3.11 -2.00 322.04 0.00e+00 6.530076e-03 3.345319e-03 3.586907e-03 -6.000000e+00 2.090948e-02 270.08 -2.00 20.00 -2.00 321.64 0.00e+00 9.059 0.003 302.00 328.00 3 2.5432e+00 2.2637e-02 7.3870e-02 -6.0000e+00 1.1707e+00 2.7283e-01 3.6051e-02 5.7727e-02 -6.0000e+00 1.2787e+00 -4.4347e-01 4.1636e-02 2.6838e-02 -6.0000e+00 7.5144e-01 1.7843e-01 1.9026e-02 1.0828e-02 -6.0000e+00 3.0950e-01 6.8897e-05 -7.3408e-04 3.2844e-04 1.3967e-04 -6.0000e+00 2.4962e-02 -3.5585e-04 0.0000e+00 12 8 8 10 0 0 98.79 20.16 0.53 -0.00036 -0.00587 31 6 1 5 0 1630.020 25.28 20.00 20.16 9.93 11.7 679.62 -244651 -276208 -180948 -192625 -278151 -168496 -204196 900000 900000 -211242 -230258 900000 35765 30128 -99866 -156665 900000 900000 276314 -46666 -53821 53516 162237 184260 -133387 -41942 -153314 2267 -134571 -43612 79368 -50838 153781 25522 1130 -16709 -37934 102207 62793 125698 -19948 18168 63014 -28906 21872 25362 40131 -6369 39712 43309 18004 33100 31865 15419 -5613 11103 337 -5895 7252 1771 24541 16827 13384 16637 4616 15757 104 8664 -8404 7837 22911 10546 3458 -4858 3581 -2395 4380 -757 -1233 5994 3360 -1191 1498 -1231 -1157 -480 176 3415 2788 154 -945 3942 688 -3324 292 -1047 209 -3470 -2789 -1486 263 662 752 778 -1139 -2370 -1739 -1608 -739 340 -1304 -1091 -704 -214 795 -161 1354 1706 1007 -182 -1002 916 -683 293 -71 1693 1110 2361 1346 -1368 1271 -351 219 330 -194 -18 107 263 -536 -865 575 -371 -175 -2559 -2889 -1893 -2015 -2953 -1762 -2136 900000 900000 -2210 -2408 900000 374 315 -1045 -2647 900000 900000 2890 -488 -563 560 1697 1927 -3284 -446 -4885 24 -3746 -579 830 -1097 1608 331 19 -330 -1011 1069 876 1315 -828 570 1360 -1572 747 866 1240 -329 1428 1663 991 1774 1928 1188 -571 999 35 -639 671 171 1978 1595 1508 2070 694 2222 17 1415 -1808 1625 4489 2440 847 -1215 749 -482 798 -151 -279 1515 1039 -440 601 -547 -548 -238 91 1750 1433 79 -462 1746 312 -1662 160 -677 158 -3136 -2718 -1462 246 561 579 588 -895 -1994 -1547 -1553 -790 404 -1781 -1596 -1063 -319 1143 -231 1915 2487 1522 -286 -1562 1362 -987 404 -95 2157 1428 3152 2021 -2394 2442 -741 495 785 -495 -48 295 731 -1488 -2316 1420 -874 -393 SS 20211121T171601.0Z 7995.719456 248 1 50.04 2 81.78 114.76 73.88 291.61 0.00 1 0.00 1 0 25 2.965e-01 5.158e-03 1.439e-01 1.597e-03 6.997508e-01 8.871187e-04 6.941925e-03 -6.000000e+00 1.773105e-01 223.65 -2.00 3.11 -2.00 321.12 0.00e+00 2.673220e-03 3.846106e-04 2.057103e-03 -6.000000e+00 7.593000e-03 270.08 -2.00 20.00 -2.00 320.71 0.00e+00 6.602 0.001 302.00 328.00 3 1.2496e+00 2.7542e-03 5.2890e-02 -6.0000e+00 4.3764e-01 -1.8682e-02 3.9215e-03 3.6859e-02 -6.0000e+00 4.7612e-01 -7.9501e-03 4.5038e-03 1.8560e-02 -6.0000e+00 2.8256e-01 -6.2543e-03 2.1895e-03 6.7598e-03 -6.0000e+00 1.1819e-01 1.2585e-03 -4.9595e-04 4.8602e-05 8.2779e-05 -6.0000e+00 9.4252e-03 -9.7182e-04 0.0000e+00 10 0 0 10 0 0 86.84 20.18 0.33 -0.00097 -0.00470 227 45 1 5 0 220.370 25.28 20.02 20.18 9.66 11.8 678.39 -111370 -136413 -70407 -139143 -54516 -104378 -51198 -70135 -101052 -32454 -114252 -56606 -91458 -27824 1538 -17531 6856 -42308 8514 -30934 -1496 -8358 1177 -12034 -30993 -10194 -22025 -8862 -15134 -16794 -6109 -13778 -647 -12506 2027 -1450 -7656 -2214 -3862 -607 -5243 -1691 -3511 -1857 3956 -4467 1210 -796 1199 1149 2330 1964 1018 2347 687 1064 -58 -976 913 -178 1369 712 2713 1210 514 1856 -108 1743 1385 1155 275 263 50 -808 535 -657 556 -56 98 193 -485 -488 -1474 -899 -809 -904 -370 -466 240 -12 597 710 790 1362 929 1066 456 308 -135 -337 148 -230 449 390 -687 -1386 -869 -809 -426 -84 -252 -76 -297 234 630 631 836 501 -9 -711 -733 -312 -163 120 355 284 751 1412 863 181 100 -231 40 133 -302 -230 -239 -26 -164 -126 100 115 180 -364 -680 -197 -780 -127 -406 -128 -240 -535 -96 -854 -282 -826 -173 9 -153 54 -619 82 -472 -18 -109 15 -189 -642 -183 -456 -161 -302 -377 -147 -390 -19 -437 62 -47 -292 -95 -205 -37 -383 -130 -292 -158 325 -412 109 -77 121 126 281 267 155 386 123 199 -11 -193 174 -34 267 153 646 327 149 538 -32 532 466 440 116 116 22 -342 206 -233 183 -19 37 84 -229 -264 -891 -580 -556 -661 -282 -365 186 -9 422 473 510 902 683 901 449 345 -166 -420 175 -249 445 380 -704 -1514 -1000 -999 -575 -115 -386 -124 -494 379 972 937 1232 764 -14 -1187 -1221 -502 -251 178 505 389 1005 1937 1313 311 191 -476 81 286 -690 -553 -592 -66 -410 -305 228 247 374 SS 20211121T173034.4Z 7995.729564 253 1 49.90 2 78.68 116.23 76.97 292.45 0.00 1 0.00 1 0 25 8.807e-02 5.233e-03 1.482e-02 5.026e-04 5.442763e-01 2.679721e-04 5.599136e-03 -6.000000e+00 5.267154e-02 223.65 -2.00 3.11 -2.00 320.14 0.00e+00 1.417872e-03 8.859377e-05 6.220965e-04 -6.000000e+00 2.255473e-03 270.08 -2.00 20.00 -2.00 319.70 0.00e+00 4.941 0.001 302.00 328.00 3 4.4989e-01 7.6634e-04 3.9080e-02 -6.0000e+00 1.3000e-01 -2.3984e-02 9.3997e-04 2.5381e-02 -6.0000e+00 1.4143e-01 -2.3243e-03 8.9719e-04 1.2899e-02 -6.0000e+00 8.3935e-02 -6.1216e-03 4.6397e-04 4.2629e-03 -6.0000e+00 3.5110e-02 8.6293e-03 -2.9861e-04 1.5787e-05 5.4360e-05 -6.0000e+00 2.7996e-03 -1.3606e-03 0.0000e+00 10 0 0 10 0 0 76.99 20.21 0.33 -0.00136 -0.00360 781 154 1 5 0 63.880 25.28 20.00 20.21 11.06 12.0 687.98 -25612 -33370 -26916 -33248 -32534 -29767 -32750 -21730 -31100 -21880 -22609 -22011 -14984 -17334 -6214 -6786 -5972 -3753 -4588 -3268 -5397 -3099 -6366 -4284 -5605 -4595 -5289 -6260 -2731 -2734 -1442 -1343 -753 -1989 -3473 -1449 -2508 -1067 -1260 -1920 -2196 -2066 -987 -974 -730 -397 -631 -5 331 1356 1251 1377 1455 1023 823 485 73 -189 -148 488 1024 1602 1299 1200 541 579 1078 735 1522 1146 436 100 -66 -74 -86 105 452 726 575 83 -399 -1152 -1451 -1445 -913 -858 -559 -316 -309 51 195 882 867 1258 1174 840 783 242 -199 -331 -282 -204 167 459 -757 -1134 -912 -668 -157 -6 -64 -234 -63 190 365 794 757 549 -112 -521 -701 -312 -60 17 331 398 841 1391 799 298 -52 -175 -53 191 -212 -313 -128 -40 -188 -210 -29 56 113 -203 -329 -264 -342 -317 -282 -344 -230 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