File name: Pandora56s1_MaunaLoaHI_20220118_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T130307.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20220118_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20220118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220118T172856.3Z 8053.728430 245 1 50.04 2 84.41 114.00 87.05 293.11 0.00 1 0.00 1 0 25 5.977e-01 6.761e-03 2.978e-01 3.340e-03 8.986688e-01 1.990494e-03 8.540285e-03 -6.000000e+00 3.607344e-01 222.26 -2.00 3.11 -2.00 321.98 0.00e+00 6.314751e-03 1.053617e-03 4.317334e-03 -6.000000e+00 1.767933e-02 269.16 -2.00 20.00 -2.00 321.60 0.00e+00 9.139 0.003 302.00 328.00 3 6.6309e-01 7.1352e-03 7.5389e-02 -6.0000e+00 8.9153e-01 8.3787e-02 1.2563e-02 5.9817e-02 -6.0000e+00 9.7526e-01 -1.5784e-01 1.5583e-02 2.9302e-02 -6.0000e+00 5.7481e-01 5.7236e-02 7.0387e-03 1.0712e-02 -6.0000e+00 2.4479e-01 4.3993e-04 -1.1756e-03 1.0228e-04 1.4371e-04 -6.0000e+00 1.9485e-02 7.4036e-03 -1.6575e-04 11 8 0 10 0 0 -2.79 20.05 0.37 0.00740 -0.00143 167 33 1 5 0 299.580 25.17 19.99 20.05 8.62 12.8 682.11 900000 900000 -311706 900000 -285565 900000 -214260 -202461 900000 -273904 900000 -127151 900000 900000 -48770 -70067 -95128 900000 -63917 900000 -53432 -67655 -96791 -111014 10101 -122341 39730 -71340 -44859 -40895 -88383 22738 -49539 32845 -52181 7808 23893 -23425 12087 -26214 -1199 -4619 -4590 4043 -4385 21918 -8556 21367 -4676 6809 1430 -898 12420 -4500 8415 6639 6771 -2299 -4414 2642 -3724 6459 3382 3334 2403 -1039 6505 294 6463 1954 3749 1007 -291 5121 -2036 2834 -1862 -540 2130 -760 991 -2451 -1064 -2243 -717 -50 -1189 394 -791 666 -409 774 1288 -3 1322 409 1200 184 416 -459 -295 -44 -10 597 -1678 -1083 -1057 -1715 -224 -612 611 -541 -233 -248 -380 1144 561 1301 -106 -172 -208 40 186 -582 461 61 719 1453 -223 456 -141 70 -63 151 -377 -301 28 -190 -31 -131 170 314 -43 900000 900000 -1566 900000 -1097 900000 -696 -658 900000 -1457 900000 -413 900000 900000 -159 -251 -526 900000 -332 900000 -278 -418 -849 -1227 36 -1591 129 -649 -335 -346 -1384 163 -791 278 -956 89 256 -436 212 -736 -30 -132 -141 119 -146 589 -331 663 -207 302 76 -56 767 -364 647 547 574 -213 -410 226 -354 618 387 438 349 -163 980 50 1169 421 874 252 -73 1144 -445 537 -354 -107 471 -209 320 -953 -456 -1050 -352 -24 -595 199 -403 353 -207 370 609 -1 760 257 886 159 395 -449 -274 -37 -8 437 -1301 -882 -916 -1627 -234 -734 820 -801 -356 -379 -563 1625 803 1910 -165 -274 -325 60 264 -802 606 78 908 1920 -340 794 -280 140 -136 349 -936 -785 74 -512 -83 -336 406 700 -93 SS 20220118T174036.2Z 8053.736530 248 1 50.05 2 81.91 115.11 89.50 293.98 0.00 1 0.00 1 0 25 3.061e-01 4.978e-03 8.050e-02 1.072e-03 7.032724e-01 5.921849e-04 7.001279e-03 -6.000000e+00 1.819461e-01 222.26 -2.00 3.11 -2.00 321.12 0.00e+00 3.030180e-03 2.543718e-04 1.922082e-03 -6.000000e+00 7.806626e-03 269.16 -2.00 20.00 -2.00 320.72 0.00e+00 6.699 0.001 302.00 328.00 3 4.5291e-01 1.8298e-03 5.3021e-02 -6.0000e+00 4.4784e-01 6.5482e-03 2.5946e-03 3.6326e-02 -6.0000e+00 4.8785e-01 -3.3485e-02 2.9790e-03 1.8491e-02 -6.0000e+00 2.8966e-01 4.0029e-03 1.4523e-03 6.7023e-03 -6.0000e+00 1.2135e-01 2.6353e-03 -9.5883e-04 3.2529e-05 8.4367e-05 -6.0000e+00 9.7284e-03 6.7719e-03 -1.6548e-04 10 0 0 10 0 0 -1.50 20.05 0.32 0.00677 -0.00043 432 85 1 5 0 115.840 25.17 20.00 20.05 9.55 12.9 687.40 -130168 -100531 -117021 -51854 -124353 -107497 -80431 -106459 -98220 -73696 -71368 -65544 -58913 -41036 -46676 -29183 -33575 -30567 -15293 -5116 -19231 -29580 -11997 -17099 -13625 -11665 -29358 -15377 -25746 -6666 -7279 -6384 -2240 -7470 -3476 -6720 -5144 -3665 -1537 -1997 -3353 -1486 -2238 -2558 -1203 -390 321 1910 2254 1920 2983 1867 2240 2292 712 1244 254 69 -467 525 1381 1088 2274 597 894 441 1544 1218 1958 1150 851 219 -135 -142 -274 -410 406 -196 673 89 -174 -1234 -1420 -1289 -1091 -724 -551 -16 -438 -38 129 851 927 706 1019 804 919 518 -72 -168 -281 -89 439 376 -731 -1270 -896 -742 -235 -177 -163 -329 -101 198 382 840 726 610 46 -643 -567 -265 85 10 166 365 726 1308 676 149 -137 -158 8 152 -279 -344 -152 -38 -226 -104 101 236 186 -558 -378 -563 -130 -624 -461 -286 -556 -534 -347 -366 -377 -406 -309 -473 -302 -421 -419 -197 -63 -283 -498 -179 -293 -245 -218 -672 -307 -587 -139 -183 -191 -74 -281 -127 -259 -196 -163 -81 -126 -245 -116 -187 -222 -106 -35 30 182 228 212 363 258 342 382 129 235 50 13 -90 100 270 234 548 164 260 130 455 376 660 441 360 98 -60 -60 -106 -144 134 -66 251 39 -90 -676 -861 -837 -754 -529 -421 -12 -342 -28 91 565 597 472 751 685 905 582 -89 -210 -334 -96 436 365 -750 -1386 -1032 -916 -292 -246 -250 -539 -167 322 592 1247 1074 933 74 -1075 -943 -427 130 15 237 501 972 1802 1035 259 -263 -304 17 328 -641 -833 -377 -96 -567 -251 231 508 386 SS 20220118T175550.0Z 8053.747106 253 1 49.94 2 78.68 116.64 92.66 295.18 0.00 1 0.00 1 0 25 7.820e-02 5.239e-03 1.274e-02 4.707e-04 5.367210e-01 2.483946e-04 5.551003e-03 -6.000000e+00 4.648812e-02 222.26 -2.00 3.11 -2.00 320.07 0.00e+00 1.508065e-03 8.049849e-05 5.909129e-04 -6.000000e+00 1.994594e-03 269.16 -2.00 20.00 -2.00 319.64 0.00e+00 4.941 0.001 302.00 328.00 3 3.1738e-01 7.0897e-04 3.8657e-02 -6.0000e+00 1.1443e-01 -1.1854e-02 8.6336e-04 2.4808e-02 -6.0000e+00 1.2465e-01 -9.4137e-03 8.1632e-04 1.2622e-02 -6.0000e+00 7.4009e-02 -3.5518e-03 4.2441e-04 4.0780e-03 -6.0000e+00 3.1005e-02 9.9686e-03 -8.2922e-04 1.4751e-05 5.3837e-05 -6.0000e+00 2.4856e-03 6.4526e-03 -1.6874e-04 10 0 0 10 0 0 3.10 20.06 0.33 0.00645 0.00022 834 165 1 5 0 59.870 25.17 19.99 20.06 11.01 12.9 694.53 -27111 -23261 -23031 -22275 -35564 -25188 -31331 -19155 -24031 -20785 -20727 -22966 -14057 -14433 -5711 -5577 -5391 -3028 -5728 -703 -4668 -858 -3263 -2638 -4267 -5241 -4141 -6324 -3945 -2365 -1201 -52 -2139 -1117 -3722 -1763 -2434 -648 -1282 -1756 -1504 -2230 -1354 -1167 -762 -253 -353 350 78 1228 1419 1380 1602 1166 1077 477 479 -499 -109 417 795 1612 1466 1113 310 286 866 725 1586 982 196 127 -111 -45 -138 98 432 744 533 87 -412 -1080 -1367 -1472 -841 -894 -555 -288 -400 -9 222 768 876 1307 1277 835 851 269 -157 -396 -373 -188 273 443 -781 -1140 -880 -701 -156 -41 -33 -340 -109 153 346 824 730 667 -93 -479 -621 -292 2 19 334 341 859 1310 696 231 -74 -171 -95 111 -201 -361 -113 -57 -160 -202 27 82 106 -250 -236 -246 -232 -403 -257 -365 -222 -328 -298 -320 -410 -278 -354 -156 -178 -192 -115 -219 -27 -191 -35 -141 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