File name: Pandora56s1_MaunaLoaHI_20220512_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T123218.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20220512_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20220512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220512T161555.8Z 8167.677730 142 1 50.26 2 84.65 72.51 129.49 288.47 0.00 1 0.00 1 0 25 8.223e-01 1.129e-02 3.386e-01 4.553e-03 1.009409e+00 2.817838e-03 9.561904e-03 -6.000000e+00 5.117911e-01 227.42 -2.00 3.11 -2.00 322.22 0.00e+00 8.108338e-03 1.574000e-03 8.193752e-03 -6.000000e+00 2.447712e-02 271.28 -2.00 20.00 -2.00 321.83 0.00e+00 9.453 0.004 302.00 328.00 3 7.1252e-01 1.0604e-02 9.2459e-02 -6.0000e+00 1.2781e+00 3.1901e-01 1.8802e-02 8.9382e-02 -6.0000e+00 1.3929e+00 -4.5386e-01 2.2623e-02 3.8060e-02 -6.0000e+00 8.1542e-01 1.7632e-01 9.9885e-03 1.1622e-02 -6.0000e+00 3.3709e-01 2.8776e-04 -1.3262e-03 1.3493e-04 1.7184e-04 -6.0000e+00 2.6851e-02 5.7531e-03 -1.6813e-04 12 8 8 10 0 0 54.64 20.00 0.38 0.00575 -0.00421 125 25 1 5 0 402.040 25.17 20.01 20.00 10.44 13.8 683.47 -368392 900000 -426320 900000 -135347 900000 900000 -120734 900000 -302853 900000 -258882 -201889 -147755 -154220 900000 -172436 900000 -129818 -32512 900000 301 -86741 -151987 900000 -140439 -58543 -125764 -110878 -56298 -97199 213452 -54860 199889 80782 -12827 17824 -60071 40421 -41618 20339 15735 -2519 72892 -18579 15245 -17827 31773 -3652 -9294 15818 51 33418 4044 26682 10134 7187 12655 301 8371 -7316 7229 12242 8012 13705 5004 20279 5508 10249 6079 4672 9516 3759 6891 -132 2990 -709 1168 4239 -817 2661 -2802 2040 -34 15 578 -555 2065 -2909 2690 334 970 882 -17 429 -1038 555 130 -364 -580 -1191 519 -708 499 -1366 -2871 -806 -1886 -1202 -1584 -727 -869 -580 102 -299 982 129 1009 -225 -158 409 -32 560 55 926 682 1047 2312 602 418 -46 326 108 25 -7 -344 -22 -28 -45 -226 -41 121 -515 -2375 900000 -6527 900000 -600 900000 900000 -535 900000 -1830 900000 -1606 -984 -655 -889 900000 -1834 900000 -1151 -144 900000 1 -577 -2088 900000 -1930 -363 -1561 -1278 -449 -1508 946 -851 886 358 -148 166 -1438 430 -1090 361 321 -66 937 -618 378 -596 774 -128 -389 593 3 1360 244 1387 653 489 811 21 536 -569 542 1016 804 1436 601 2190 746 1487 1048 900 1821 750 1244 -23 460 -109 187 767 -190 719 -936 729 -13 6 255 -258 957 -1410 1192 144 397 362 -8 220 -647 407 102 -319 -524 -1032 400 -543 362 -1039 -2339 -628 -1624 -1159 -1770 -923 -1217 -849 148 -430 1361 181 1454 -343 -245 615 -46 758 71 1161 833 1267 2931 889 721 -90 711 257 59 -17 -919 -59 -78 -121 -589 -98 294 -1195 SS 20220512T162718.8Z 8167.685635 145 1 50.07 2 82.09 73.37 131.94 290.06 0.00 1 0.00 1 0 25 4.020e-01 4.912e-03 1.880e-01 1.290e-03 7.876277e-01 7.291363e-04 7.700511e-03 -6.000000e+00 2.437689e-01 227.42 -2.00 3.11 -2.00 321.39 0.00e+00 3.391063e-03 3.433998e-04 2.900660e-03 -6.000000e+00 1.034399e-02 271.28 -2.00 20.00 -2.00 320.98 0.00e+00 6.827 0.001 302.00 328.00 3 5.1675e-01 2.3890e-03 5.8635e-02 -6.0000e+00 6.0662e-01 2.9218e-02 3.5986e-03 4.4816e-02 -6.0000e+00 6.5816e-01 -4.5673e-02 4.2139e-03 2.1804e-02 -6.0000e+00 3.8975e-01 6.5108e-03 1.9891e-03 7.9481e-03 -6.0000e+00 1.6192e-01 2.0193e-03 -8.8708e-04 3.8015e-05 9.7173e-05 -6.0000e+00 1.2798e-02 4.8508e-03 -1.5034e-04 10 0 0 10 0 0 50.12 20.01 0.32 0.00485 -0.00182 353 70 1 5 0 141.810 25.17 20.00 20.01 11.19 13.8 687.14 -168363 7929 -166582 -67291 -173138 -98608 -189272 -148965 -19564 -133250 -110432 -97368 -28597 -62701 -71398 7066 -28184 -27843 -32551 -15874 -28360 -31301 -17194 -40067 -7616 -27000 -27673 -25332 -34129 -10823 -24530 -1805 -18426 -12840 -13295 -4707 -627 -10339 -3470 -6495 -4558 -1280 -3084 -3608 -5250 1984 -1671 3496 505 1310 4916 2552 3164 2351 2357 719 428 319 -482 267 1005 3007 1976 1306 1261 447 1290 1141 2079 1439 312 803 -105 -6 -185 -82 357 -372 709 -426 47 -996 -1123 -1626 -1291 -824 -690 2 -354 385 518 628 864 419 975 670 900 535 -30 -95 -245 68 256 550 -819 -1155 -869 -915 -183 -8 -291 -373 -192 189 289 893 602 768 -73 -604 -551 -281 147 -186 227 65 740 1223 533 209 -104 -185 -130 177 -195 -375 -27 -55 -153 -169 95 268 131 -480 10 -615 -93 -675 -186 -969 -581 -25 -565 -422 -396 -77 -316 -509 28 -190 -214 -289 -128 -270 -318 -162 -503 -78 -358 -381 -344 -511 -150 -461 -33 -467 -335 -354 -118 -17 -363 -135 -312 -246 -73 -191 -234 -357 130 -119 250 40 114 464 271 373 307 331 108 67 50 -74 41 157 508 384 289 300 110 320 299 597 458 111 297 -39 -2 -61 -25 101 -109 232 -162 21 -517 -630 -986 -832 -560 -490 1 -256 268 340 390 539 266 687 551 837 572 -34 -110 -272 71 242 505 -792 -1185 -942 -1041 -228 -12 -442 -596 -314 302 457 1355 913 1200 -118 -1001 -906 -456 228 -278 324 92 1025 1751 833 362 -197 -379 -277 400 -461 -934 -67 -140 -384 -419 221 598 282 SS 20220512T164138.4Z 8167.695583 150 1 49.94 2 78.84 74.41 134.99 292.23 0.00 1 0.00 1 0 25 1.310e-01 5.076e-03 2.207e-02 5.415e-04 6.030776e-01 2.946960e-04 6.124727e-03 -6.000000e+00 7.944260e-02 227.42 -2.00 3.11 -2.00 320.37 0.00e+00 2.074923e-03 1.044649e-04 8.759936e-04 -6.000000e+00 3.370894e-03 271.28 -2.00 20.00 -2.00 319.92 0.00e+00 5.005 0.001 302.00 328.00 3 3.6455e-01 8.5935e-04 4.1855e-02 -6.0000e+00 1.9769e-01 7.1353e-03 1.0819e-03 2.9064e-02 -6.0000e+00 2.1448e-01 -1.5907e-02 1.0811e-03 1.4553e-02 -6.0000e+00 1.2701e-01 -3.0682e-03 5.4956e-04 5.0238e-03 -6.0000e+00 5.2771e-02 8.1625e-03 -7.5882e-04 1.6654e-05 6.1321e-05 -6.0000e+00 4.1702e-03 4.3864e-03 -1.4767e-04 10 0 0 10 0 0 39.44 20.06 0.33 0.00439 -0.00132 714 141 1 5 0 69.930 25.17 20.01 20.06 12.09 13.8 692.00 -57330 -22551 -38942 -54701 -40040 -57883 -33631 -45677 -37679 -37815 -36973 -24902 -26499 -9439 -17348 -10483 -9236 -8194 -5001 -8661 -2169 -7968 -2965 -6820 -7913 -4308 -10768 -5339 -9077 -2829 -2524 -2596 -470 -4362 -2996 -3982 -2568 -2058 -1862 -1115 -2797 -1410 -2093 -927 -567 -652 329 -166 914 607 1322 1736 1481 1520 589 934 -277 -181 -128 396 1195 1132 1820 985 522 259 1046 1032 1345 1252 188 297 -312 7 8 -183 685 383 688 19 -329 -944 -1517 -1195 -976 -709 -644 -173 -306 -145 339 624 971 1096 1131 873 746 464 -219 -286 -288 -193 361 474 -620 -1221 -915 -679 -223 -11 -195 -263 -171 171 330 796 840 559 73 -561 -594 -253 -43 78 246 396 722 1367 686 185 -43 -223 -29 86 -197 -321 -143 -2 -232 -182 10 189 98 -385 -124 -269 -439 -266 -462 -227 -393 -336 -369 -391 -268 -358 -136 -333 -223 -220 -214 -137 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