File name: Pandora56s1_MaunaLoaHI_20220629_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T210444.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20220629_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20220629 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220629T203433.5Z 8215.857332 6 1 50.00 2 26.18 76.87 35.26 71.14 0.00 1 0.00 1 0 17 7.169e-03 5.964e-03 1.110e-04 8.225e-05 1.383339e-01 4.433192e-05 1.525850e-03 -6.000000e+00 4.327713e-03 226.17 -2.00 3.11 -2.00 314.46 0.00e+00 1.167023e-04 3.379025e-06 1.137607e-05 -6.000000e+00 1.851667e-04 272.22 -2.00 20.00 -2.00 314.06 0.00e+00 1.114 0.000 302.00 328.00 3 1.0839e-01 1.1280e-04 9.2905e-03 -6.0000e+00 1.0735e-02 -1.8099e-02 1.2487e-04 6.2474e-03 -6.0000e+00 1.1655e-02 3.9825e-03 7.1497e-05 3.1084e-03 -6.0000e+00 6.9122e-03 -3.2398e-03 3.0555e-05 8.8212e-04 -6.0000e+00 2.8814e-03 2.1781e-01 -1.0966e-04 2.6442e-06 1.4474e-05 -6.0000e+00 2.2808e-04 -1.7168e-04 0.0000e+00 10 0 0 10 0 0 33.14 21.34 0.37 -0.00017 -0.00100 3742 739 1 5 0 13.360 26.21 20.03 21.34 22.63 14.3 737.58 -295 -1258 -1825 -2235 -1492 196 981 1387 1148 -179 -391 265 501 429 301 -97 -389 241 423 372 558 572 1113 721 648 394 -201 -414 441 1251 1360 1351 711 -667 -1511 -603 -432 -381 -110 -920 -1339 -1143 -1068 -947 -864 -562 -839 -489 -119 338 933 797 994 918 654 682 528 276 288 762 926 1141 948 351 -314 -646 -1 198 980 943 60 44 -180 80 36 24 393 490 687 60 -565 -1244 -1485 -1311 -884 -834 -640 -306 -465 -247 -111 227 457 897 1163 791 677 288 -181 -371 -369 -245 87 468 -321 -815 -658 -597 -235 7 27 -190 -117 68 180 586 617 667 272 -140 -359 -188 40 188 542 682 834 1243 809 374 -7 -192 -147 93 -151 -263 -180 -117 -200 -246 -151 -193 -339 -109 -495 -717 -898 -541 67 342 524 469 -70 -167 114 209 196 150 -52 -213 134 239 214 325 332 650 436 375 233 -117 -247 244 660 723 746 410 -391 -860 -336 -257 -239 -80 -717 -1138 -1012 -965 -859 -778 -498 -723 -404 -94 264 742 664 864 828 606 640 467 244 270 711 828 1075 950 367 -325 -624 -1 180 913 898 63 49 -186 85 36 23 348 406 573 54 -530 -1279 -1632 -1421 -1015 -1021 -777 -384 -585 -300 -134 249 487 902 1186 868 761 353 -220 -451 -454 -282 96 523 -385 -983 -831 -784 -321 9 37 -264 -157 90 218 701 723 805 350 -181 -487 -256 54 241 698 832 970 1415 953 464 -9 -240 -186 121 -207 -357 -253 -168 -291 -354 -211 -263 -482 SS 20220629T203949.3Z 8215.860988 9 1 50.06 2 24.97 76.71 34.11 70.99 0.00 1 0.00 1 0 17 7.149e-03 5.974e-03 1.113e-04 8.304e-05 1.369147e-01 4.478344e-05 1.511206e-03 -6.000000e+00 4.315755e-03 226.17 -2.00 3.11 -2.00 314.42 0.00e+00 9.688608e-05 3.386019e-06 1.055208e-05 -6.000000e+00 1.846549e-04 272.22 -2.00 20.00 -2.00 314.03 0.00e+00 1.103 0.000 302.00 328.00 3 1.4084e-01 1.1391e-04 9.1972e-03 -6.0000e+00 1.0705e-02 -1.7408e-02 1.2609e-04 6.1841e-03 -6.0000e+00 1.1623e-02 3.7786e-03 7.2192e-05 3.0771e-03 -6.0000e+00 6.8931e-03 -3.1725e-03 3.0803e-05 8.7182e-04 -6.0000e+00 2.8735e-03 2.1296e-01 -1.0971e-04 2.6709e-06 1.4453e-05 -6.0000e+00 2.2745e-04 -1.8480e-04 0.0000e+00 10 0 0 10 0 0 87.65 21.37 0.37 -0.00018 -0.00101 3618 715 1 5 0 13.820 26.21 20.00 21.37 22.74 14.2 736.98 -281 -1264 -1798 -2197 -1492 219 925 1411 1056 -124 -390 329 543 426 283 -134 -356 239 429 385 567 586 1100 742 675 454 -204 -423 448 1217 1376 1320 739 -657 -1511 -606 -435 -367 -121 -904 -1352 -1160 -1050 -968 -855 -576 -835 -506 -128 342 924 803 994 935 681 678 530 269 290 754 928 1142 949 356 -304 -640 4 204 977 949 61 40 -160 83 57 32 385 496 663 74 -573 -1234 -1477 -1318 -875 -823 -641 -299 -464 -242 -107 211 453 904 1148 798 680 273 -161 -373 -371 -269 95 463 -327 -822 -658 -592 -247 9 22 -194 -99 55 189 571 623 666 277 -128 -371 -197 30 201 564 695 832 1234 810 359 3 -203 -138 103 -152 -257 -197 -114 -188 -247 -160 -194 -342 -106 -505 -717 -896 -549 76 327 540 438 -49 -168 143 229 197 143 -72 -197 134 245 224 333 343 648 418 394 271 -120 -256 250 648 737 735 429 -388 -865 -340 -261 -232 -89 -709 -1156 -1033 -954 -883 -775 -513 -724 -421 -102 269 739 672 868 847 633 597 471 239 273 707 833 1080 954 372 -315 -620 4 185 912 905 64 43 -165 89 57 29 342 412 554 67 -537 -1270 -1625 -1430 -1005 -1009 -779 -374 -585 -295 -129 231 482 910 1171 876 764 335 -197 -453 -457 -310 105 517 -393 -992 -830 -778 -337 12 31 -270 -133 72 228 682 729 802 357 -166 -502 -268 40 258 726 848 965 1404 954 445 4 -253 -174 134 -208 -348 -275 -164 -272 -355 -224 -264 -484 SS 20220629T204505.3Z 8215.864644 12 1 50.11 2 23.76 76.52 32.96 70.82 0.00 1 0.00 1 0 17 7.156e-03 5.966e-03 1.083e-04 8.096e-05 1.356824e-01 4.362787e-05 1.498555e-03 -6.000000e+00 4.320299e-03 226.17 -2.00 3.11 -2.00 314.42 0.00e+00 1.264554e-04 3.311974e-06 1.140444e-05 -6.000000e+00 1.848515e-04 272.22 -2.00 20.00 -2.00 314.03 0.00e+00 1.092 0.000 302.00 328.00 3 9.7965e-02 1.1099e-04 9.1146e-03 -6.0000e+00 1.0717e-02 -1.7325e-02 1.2285e-04 6.1332e-03 -6.0000e+00 1.1635e-02 3.8902e-03 7.0303e-05 3.0497e-03 -6.0000e+00 6.9004e-03 -3.0826e-03 3.0011e-05 8.6521e-04 -6.0000e+00 2.8764e-03 2.2426e-01 -1.2607e-04 2.6006e-06 1.4369e-05 -6.0000e+00 2.2769e-04 -6.4878e-05 0.0000e+00 10 0 0 10 0 0 50.55 21.38 0.37 -0.00006 -0.00101 3793 750 1 5 0 13.180 26.21 20.00 21.38 22.78 14.3 737.40 -277 -1243 -1811 -2231 -1476 248 972 1414 1100 -185 -433 285 519 426 282 -143 -383 251 424 396 575 615 1116 723 626 418 -216 -423 423 1241 1397 1343 716 -629 -1501 -599 -418 -364 -134 -928 -1347 -1161 -1079 -974 -857 -573 -853 -499 -112 318 926 789 965 931 664 675 535 255 280 744 898 1136 933 344 -316 -647 -12 194 977 949 70 44 -159 79 32 26 399 502 668 48 -554 -1231 -1488 -1315 -871 -824 -639 -297 -458 -233 -99 210 452 915 1139 794 672 276 -171 -369 -365 -255 103 458 -326 -812 -649 -594 -234 8 29 -193 -107 48 186 582 632 660 269 -127 -368 -197 31 190 547 700 829 1241 806 367 5 -195 -144 115 -162 -266 -194 -124 -180 -240 -161 -201 -344 -105 -503 -731 -921 -550 86 347 547 461 -74 -173 114 221 199 144 -78 -215 142 244 233 340 363 663 410 368 251 -128 -257 238 665 753 752 419 -374 -865 -338 -252 -232 -99 -732 -1158 -1039 -920 -834 -780 -513 -744 -417 -90 251 743 663 845 847 619 595 477 227 247 700 809 1078 940 361 -329 -629 -11 177 914 907 73 48 -165 84 32 24 354 418 559 44 -521 -1269 -1639 -1428 -1001 -1011 -777 -372 -578 -285 -120 231 482 921 1162 871 756 338 -208 -448 -449 -294 113 513 -392 -980 -819 -781 -319 10 41 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