File name: Pandora56s1_MaunaLoaHI_20220705_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T122355.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20220705_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20220705 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220705T180011.4Z 8221.750132 6 1 44.63 2 61.81 74.01 135.61 61.56 0.00 1 0.00 1 0 25 8.627e-03 5.650e-03 3.720e-04 1.399e-04 2.544245e-01 7.365858e-05 2.748674e-03 -6.000000e+00 5.202827e-03 226.01 -2.00 3.11 -2.00 316.82 0.00e+00 8.767956e-05 9.241381e-06 4.591056e-05 -6.000000e+00 2.227363e-04 272.16 -2.00 20.00 -2.00 316.29 0.00e+00 2.108 0.000 302.00 328.00 3 9.5676e-02 1.9183e-04 1.7322e-02 -6.0000e+00 1.2901e-02 -2.3171e-02 2.1451e-04 1.1467e-02 -6.0000e+00 1.4010e-02 3.6542e-03 1.2652e-04 5.7180e-03 -6.0000e+00 8.3097e-03 -3.7933e-03 6.0220e-05 1.6323e-03 -6.0000e+00 3.4639e-03 9.6612e-02 -3.6627e-04 4.5226e-06 2.2435e-05 -6.0000e+00 2.7453e-04 7.3114e-03 -1.0877e-04 10 0 0 10 0 0 -2.98 20.77 0.33 0.00731 0.00456 2273 449 1 5 0 19.630 25.79 20.02 20.77 19.57 14.2 722.29 -1491 -2290 -3239 -3703 -3050 -1378 -411 330 79 -1185 -1287 -324 24 121 139 -159 -446 128 374 135 392 591 1137 801 694 413 -294 -534 423 1171 1399 1294 584 -919 -1625 -713 -466 -239 43 -814 -1219 -1010 -909 -795 -661 -387 -690 -372 -17 437 1046 879 1075 983 698 690 516 225 276 758 989 1292 1078 414 -282 -581 93 311 1064 919 53 -30 -283 -56 -50 -38 440 532 655 5 -577 -1288 -1551 -1354 -915 -847 -660 -335 -482 -239 -61 320 550 1017 1212 858 738 279 -212 -437 -476 -342 76 446 -405 -864 -689 -583 -191 60 29 -214 -88 98 242 681 709 692 205 -252 -480 -244 5 159 512 628 855 1307 849 351 -14 -195 -118 142 -182 -276 -167 -107 -202 -258 -141 -147 -230 -196 -328 -472 -514 -388 -167 -52 45 12 -190 -210 -55 4 25 33 -41 -122 36 109 41 119 181 354 262 238 146 -104 -180 134 364 452 448 216 -352 -609 -264 -186 -101 21 -467 -712 -620 -573 -506 -419 -243 -428 -225 -10 260 645 577 745 715 526 532 404 176 213 583 781 1004 902 366 -251 -491 73 257 852 813 51 -31 -290 -55 -47 -32 362 417 528 4 -536 -1325 -1603 -1478 -1058 -979 -803 -418 -605 -290 -73 353 560 1066 1226 948 902 352 -284 -586 -608 -406 92 541 -494 -1121 -937 -782 -267 88 45 -320 -136 142 344 904 925 931 276 -362 -712 -360 8 219 714 832 1084 1639 1118 494 -20 -283 -175 218 -277 -442 -276 -181 -344 -432 -229 -231 -353 SS 20220705T180533.4Z 8221.753859 9 1 44.50 2 60.59 74.27 134.54 62.59 0.00 1 0.00 1 0 25 8.461e-03 5.685e-03 3.339e-04 1.346e-04 2.448489e-01 7.104130e-05 2.650529e-03 -6.000000e+00 5.102687e-03 226.01 -2.00 3.11 -2.00 316.65 0.00e+00 6.599111e-05 8.517913e-06 4.201548e-05 -6.000000e+00 2.184450e-04 272.16 -2.00 20.00 -2.00 316.12 0.00e+00 2.029 0.000 302.00 328.00 3 8.9531e-02 1.8451e-04 1.6673e-02 -6.0000e+00 1.2653e-02 -2.3554e-02 2.0604e-04 1.1036e-02 -6.0000e+00 1.3740e-02 4.0050e-03 1.2083e-04 5.5007e-03 -6.0000e+00 8.1497e-03 -3.7654e-03 5.6942e-05 1.5689e-03 -6.0000e+00 3.3974e-03 1.0367e-01 -3.4299e-04 4.3612e-06 2.1993e-05 -6.0000e+00 2.6923e-04 7.2068e-03 -1.0177e-04 10 0 0 10 0 0 -9.17 20.82 0.34 0.00721 0.00463 2338 462 1 5 0 19.020 25.79 20.01 20.82 19.72 14.2 722.68 -1522 -2217 -3005 -3630 -2973 -1137 -180 378 342 -937 -1057 -210 135 218 190 -133 -424 168 382 253 477 557 1199 817 717 443 -300 -484 289 1220 1418 1376 578 -855 -1690 -773 -456 -207 53 -817 -1219 -1036 -993 -800 -695 -423 -733 -364 -40 410 1025 829 1028 954 716 716 530 252 278 771 978 1253 1054 421 -293 -593 94 276 1050 915 35 -22 -280 -62 -33 -37 406 515 706 3 -572 -1280 -1546 -1344 -913 -840 -677 -327 -489 -252 -53 312 561 1014 1226 832 728 308 -213 -439 -471 -318 76 436 -403 -876 -683 -583 -170 48 26 -199 -92 102 258 661 683 680 227 -241 -462 -248 24 166 509 617 850 1313 841 358 6 -180 -118 118 -158 -294 -182 -95 -206 -253 -154 -146 -240 -220 -347 -479 -550 -413 -150 -25 57 56 -163 -187 -38 27 49 48 -37 -123 50 118 81 154 181 396 283 261 166 -112 -173 97 399 481 499 224 -342 -662 -299 -174 -91 27 -488 -739 -660 -650 -528 -457 -276 -471 -227 -24 251 651 559 732 713 554 566 425 202 220 607 791 998 902 381 -266 -511 75 232 854 821 35 -21 -271 -62 -31 -32 339 409 575 2 -536 -1326 -1609 -1477 -1063 -977 -829 -412 -619 -307 -61 347 575 1069 1243 920 891 389 -285 -589 -601 -378 92 530 -492 -1139 -930 -782 -238 71 40 -296 -141 146 343 872 886 908 304 -345 -681 -365 34 229 707 815 1073 1638 1100 500 8 -258 -173 179 -238 -466 -298 -158 -347 -420 -248 -227 -366 SS 20220705T181051.2Z 8221.757538 12 1 44.30 2 59.39 74.52 133.49 63.56 0.00 1 0.00 1 0 25 8.187e-03 5.686e-03 3.041e-04 1.305e-04 2.364526e-01 6.886521e-05 2.563505e-03 -6.000000e+00 4.937518e-03 226.01 -2.00 3.11 -2.00 316.48 0.00e+00 6.047518e-05 7.951745e-06 3.938967e-05 -6.000000e+00 2.113744e-04 272.16 -2.00 20.00 -2.00 315.96 0.00e+00 1.957 0.000 302.00 328.00 3 8.3864e-02 1.7860e-04 1.6089e-02 -6.0000e+00 1.2243e-02 -2.2210e-02 1.9930e-04 1.0654e-02 -6.0000e+00 1.3295e-02 3.6955e-03 1.1618e-04 5.3110e-03 -6.0000e+00 7.8859e-03 -3.5778e-03 5.4284e-05 1.5131e-03 -6.0000e+00 3.2874e-03 1.1044e-01 -3.5293e-04 4.2232e-06 2.1430e-05 -6.0000e+00 2.6052e-04 7.1997e-03 -1.0250e-04 10 0 0 10 0 0 4.30 20.86 0.33 0.00720 0.00455 2411 476 1 5 0 18.370 25.79 20.02 20.86 20.05 14.3 725.01 -1278 -2037 -2863 -3439 -2731 -1015 -224 627 362 -915 -896 -149 207 324 176 -157 -383 222 322 247 436 550 1158 854 710 430 -264 -477 365 1185 1409 1300 621 -861 -1693 -711 -432 -211 -39 -795 -1243 -1026 -962 -821 -697 -453 -733 -391 -49 434 1026 816 1011 929 693 710 520 226 292 755 982 1235 1049 407 -268 -588 75 266 1034 940 35 -39 -281 -48 -55 -14 395 509 668 -12 -595 -1274 -1536 -1353 -921 -855 -672 -329 -494 -254 -75 277 539 1006 1204 826 704 295 -224 -448 -435 -313 79 451 -397 -863 -682 -577 -177 57 33 -196 -100 110 264 656 703 667 223 -224 -455 -221 13 183 526 624 832 1323 830 379 10 -198 -117 111 -173 -276 -183 -112 -211 -246 -170 -143 -249 -201 -347 -495 -565 -410 -145 -33 101 64 -171 -170 -29 44 78 47 -46 -118 71 106 83 149 189 404 312 272 170 -104 -179 129 407 500 492 251 -358 -689 -286 -171 -96 -21 -455 -781 -676 -652 -560 -474 -305 -486 -252 -31 273 669 565 737 711 548 573 426 185 236 608 812 1004 916 375 -247 -515 61 211 852 854 35 -38 -276 -48 -53 -12 334 409 550 -10 -561 -1241 -1609 -1496 -1079 -1001 -829 -417 -630 -313 -86 310 555 1063 1224 915 862 372 -300 -599 -555 -372 95 547 -484 -1122 -929 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