File name: Pandora56s1_MaunaLoaHI_20221007_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T214806.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20221007_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20221007 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221007T164238.9Z 8315.696284 180 1 50.21 2 84.30 98.09 124.11 271.43 0.00 1 0.00 1 0 25 7.319e-01 9.209e-03 2.704e-01 3.056e-03 8.830855e-01 1.836564e-03 8.321981e-03 -6.000000e+00 4.493104e-01 225.10 -2.00 3.11 -2.00 321.97 0.00e+00 6.595341e-03 9.950078e-04 4.007611e-03 -6.000000e+00 2.135267e-02 271.29 -2.00 20.00 -2.00 321.58 0.00e+00 8.987 0.003 302.00 328.00 3 6.4454e-01 6.6752e-03 7.4560e-02 -6.0000e+00 1.1163e+00 1.0534e-01 1.1373e-02 5.9319e-02 -6.0000e+00 1.2179e+00 -1.8324e-01 1.3782e-02 2.7565e-02 -6.0000e+00 7.1669e-01 6.6707e-02 6.2233e-03 1.0985e-02 -6.0000e+00 2.9923e-01 4.8318e-04 -6.0238e-04 9.4488e-05 1.3702e-04 -6.0000e+00 2.4078e-02 5.0587e-03 0.0000e+00 11 9 0 11 8 0 -15.78 20.00 0.40 0.00506 0.00053 175 35 1 5 0 286.860 25.17 20.00 20.00 11.12 14.7 675.03 -417389 900000 -216826 900000 900000 -310866 900000 -277855 900000 -212789 -52704 900000 -229817 900000 -165451 900000 -124160 900000 127249 -102933 900000 -96494 900000 -82396 -5252 83237 -97509 19210 -111054 195727 -14544 18276 50696 -23383 84519 -30965 62426 -21099 -1219 25088 -18165 954 -14373 27160 -8240 14379 7191 2567 25485 -7391 18964 2132 15866 10346 1265 6034 -3108 7159 -2227 5937 8685 152 12118 979 10173 762 6750 4761 3511 3533 -392 5046 893 2535 2272 -2266 3082 -3598 1878 -916 1572 -672 -2302 -709 -2361 1137 -1127 -317 -140 -1180 489 -1371 954 -430 1048 625 -381 848 -610 851 -672 -197 728 -305 -743 -2267 -990 -1361 -319 -106 -521 -380 -604 394 40 1268 866 193 90 -887 -217 -311 663 373 240 341 505 1903 336 579 -46 -187 272 -149 -157 -461 68 31 -147 42 -250 395 -248 -5643 900000 -645 900000 900000 -1933 900000 -1503 900000 -748 -157 900000 -1864 900000 -1297 900000 -974 900000 378 -891 900000 -835 900000 -713 -25 248 -1160 80 -1651 582 -134 152 362 -348 478 -519 501 -422 -24 461 -589 28 -529 690 -310 451 257 103 896 -404 908 138 1004 764 110 527 -306 635 -213 518 770 16 1337 138 1428 122 1051 810 676 774 -98 1251 228 598 490 -466 576 -755 429 -259 517 -262 -934 -305 -1102 543 -575 -164 -72 -595 230 -625 460 -205 562 398 -289 733 -588 825 -628 -166 555 -228 -579 -1895 -870 -1305 -338 -127 -712 -563 -928 595 58 1792 1234 286 139 -1422 -341 -467 941 511 318 439 642 2518 511 1010 -83 -373 583 -344 -385 -1197 181 83 -391 107 -598 878 -534 SS 20221007T165432.9Z 8315.704547 183 1 50.13 2 81.53 99.14 126.78 272.51 0.00 1 0.00 1 0 25 2.034e-01 4.936e-03 9.012e-02 9.504e-04 6.764136e-01 5.230927e-04 6.736586e-03 -6.000000e+00 1.222406e-01 225.10 -2.00 3.11 -2.00 321.00 0.00e+00 2.920357e-03 2.250936e-04 1.477630e-03 -6.000000e+00 5.234247e-03 271.29 -2.00 20.00 -2.00 320.57 0.00e+00 6.426 0.001 302.00 328.00 3 4.5301e-01 1.6440e-03 5.1084e-02 -6.0000e+00 3.0257e-01 -6.2022e-03 2.2536e-03 3.4487e-02 -6.0000e+00 3.2887e-01 -1.9666e-02 2.4854e-03 1.7332e-02 -6.0000e+00 1.9510e-01 -1.7091e-03 1.2132e-03 6.6152e-03 -6.0000e+00 8.1373e-02 3.1351e-03 -4.5383e-04 2.9177e-05 8.0712e-05 -6.0000e+00 6.4723e-03 4.9491e-03 0.0000e+00 10 0 0 10 0 0 -3.34 20.02 0.33 0.00495 0.00154 467 92 1 5 0 107.330 25.17 19.99 20.02 11.59 14.8 677.86 -82467 -63416 -49777 -43580 -7876 -6756 -92807 -33994 -77053 -75385 -75378 -68062 -47786 -58776 -15548 -18114 -15633 -19379 -15540 -12511 -17799 -7545 -9689 -3891 -5298 -15724 -15810 -12912 -14768 -11614 -7284 -4371 -8128 -5103 -10185 -3467 -6104 -1399 -2083 -3275 -1591 -4604 -1290 -1687 368 963 1057 764 472 2604 898 2073 2366 1648 2022 -99 -243 -158 129 529 631 2315 1081 1535 685 632 1248 831 1534 1034 212 25 -259 -233 -97 21 -373 233 160 -171 -231 -895 -1521 -1320 -690 -806 -549 -75 -261 15 336 953 939 970 971 631 810 416 -21 -179 -235 -56 241 487 -905 -1310 -967 -773 -181 -32 -15 -286 -29 187 455 858 822 584 -160 -659 -639 -310 -33 -80 235 220 752 1269 695 236 -113 -76 -120 60 -346 -342 -130 -11 -167 -177 121 157 238 -275 -206 -152 -125 -15 -13 -464 -107 -421 -447 -496 -492 -359 -637 -138 -200 -194 -280 -236 -196 -305 -120 -167 -69 -103 -360 -371 -294 -352 -296 -211 -133 -296 -193 -409 -133 -267 -69 -126 -238 -129 -419 -120 -164 36 96 109 82 54 317 124 315 396 303 395 -21 -52 -34 27 111 137 541 289 454 217 201 396 276 556 425 89 11 -113 -105 -40 8 -133 84 64 -80 -116 -516 -973 -904 -501 -621 -442 -61 -215 12 251 665 636 677 748 560 829 448 -24 -212 -265 -63 248 492 -970 -1492 -1073 -919 -233 -46 -23 -482 -49 309 717 1295 1237 910 -264 -1126 -1088 -510 -53 -121 344 310 1032 1790 1087 414 -203 -148 -247 131 -802 -777 -303 -27 -394 -404 280 342 501 SS 20221007T170709.5Z 8315.713305 188 1 50.08 2 78.60 100.28 129.60 273.71 0.00 1 0.00 1 0 25 7.706e-02 5.256e-03 1.305e-02 4.697e-04 5.353088e-01 2.503047e-04 5.485162e-03 -6.000000e+00 4.630217e-02 225.10 -2.00 3.11 -2.00 320.09 0.00e+00 1.511162e-03 8.206004e-05 5.326149e-04 -6.000000e+00 1.982573e-03 271.29 -2.00 20.00 -2.00 319.62 0.00e+00 4.905 0.001 302.00 328.00 3 3.3754e-01 7.2031e-04 3.8771e-02 -6.0000e+00 1.1461e-01 -1.9007e-02 8.7713e-04 2.5019e-02 -6.0000e+00 1.2457e-01 -3.0866e-03 8.1931e-04 1.2602e-02 -6.0000e+00 7.3898e-02 -6.0851e-03 4.2321e-04 4.1805e-03 -6.0000e+00 3.0824e-02 9.8971e-03 -3.1034e-04 1.4820e-05 5.2740e-05 -6.0000e+00 2.4514e-03 4.6221e-03 0.0000e+00 10 0 0 10 0 0 -6.98 20.05 0.31 0.00462 0.00229 837 165 1 5 0 59.820 25.17 20.00 20.05 12.44 14.8 682.14 -33225 -17938 -28223 -23534 -28689 -29220 -20361 -22251 -21425 -24860 -20145 -20809 -14200 -11480 -9282 -5520 -7132 -3038 -4140 -2336 -3710 -4203 -3567 -4316 -2633 -3952 -5089 -4894 -4455 -3188 -1510 -249 -1263 -2211 -3422 -2881 -1385 -1665 -879 -1944 -2260 -1950 -1379 -1191 -894 75 -544 494 456 1019 1403 1227 1758 1292 952 812 197 -131 -395 617 846 1655 1549 1016 469 266 990 783 1255 984 85 232 -184 137 -236 79 429 561 496 -142 -480 -1086 -1500 -1353 -916 -814 -621 -194 -334 31 363 731 889 1254 1250 813 845 315 -166 -351 -340 -253 156 374 -838 -1174 -884 -641 -159 -36 -20 -245 -33 234 326 811 734 579 -80 -570 -664 -310 -19 -28 335 395 821 1388 730 255 -81 -116 -78 80 -225 -349 -125 -55 -166 -217 7 115 110 -317 -168 -309 -241 -296 -303 -208 -261 -279 -363 -303 -356 -276 -268 -258 -172 -253 -113 -152 -89 -148 -172 -152 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