File name: Pandora56s1_MaunaLoaHI_20221116_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T220657.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20221116_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20221116 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221116T170004.3Z 8355.708383 248 1 50.02 2 84.49 112.24 5.24 250.65 0.00 1 0.00 1 0 25 7.423e-01 8.036e-03 3.417e-01 3.975e-03 9.858674e-01 2.419180e-03 9.209931e-03 -6.000000e+00 4.526361e-01 223.84 -2.00 3.11 -2.00 322.16 0.00e+00 4.911251e-03 1.340771e-03 6.129741e-03 -6.000000e+00 2.136516e-02 270.19 -2.00 20.00 -2.00 321.78 0.00e+00 9.231 0.003 302.00 328.00 3 8.0151e-01 9.0281e-03 8.3247e-02 -6.0000e+00 1.1236e+00 1.2744e-01 1.6636e-02 7.3800e-02 -6.0000e+00 1.2269e+00 -2.2652e-01 2.0556e-02 3.5075e-02 -6.0000e+00 7.2261e-01 8.4174e-02 9.0837e-03 1.1326e-02 -6.0000e+00 3.0212e-01 3.2890e-04 -6.3484e-04 1.1841e-04 1.7043e-04 -6.0000e+00 2.4344e-02 6.0942e-03 0.0000e+00 11 8 0 10 0 0 26.80 19.68 0.44 0.00609 0.00132 145 29 1 5 0 344.890 24.86 20.01 19.68 6.51 14.9 651.76 -244003 900000 -392906 900000 -242659 -240327 900000 -79721 900000 -294375 900000 -254092 900000 900000 -55871 900000 -182514 900000 -180723 -118058 -120295 -122610 900000 -116110 13465 -130290 -101648 44486 -100565 36155 -112744 23965 -98440 30893 -45272 9030 15188 -65370 19796 -32356 -25683 -4829 -21176 51343 -15617 -180 7717 -598 13844 -14025 38489 -1452 20002 -2533 9681 5009 4604 9043 2446 16965 2631 4865 7164 3137 7548 209 9622 2144 5963 6373 -85 4660 -615 5032 -1561 1987 3929 -417 2443 -2621 1475 -3122 -517 -740 -254 1198 -1686 1635 -1995 919 775 -361 837 -1504 1109 -48 1263 775 -323 157 -231 178 447 -77 -1249 -1831 -1164 -2031 -208 -267 -748 -692 -139 145 222 687 511 667 -288 -775 -118 49 477 -18 422 14 995 2045 223 410 -177 -29 248 -57 -34 -560 157 58 52 -284 -233 488 -215 -944 900000 -2487 900000 -939 -930 900000 -308 900000 -1139 900000 -983 900000 900000 -216 900000 -1412 900000 -1780 -731 -791 -854 900000 -898 52 -1361 -826 172 -895 140 -1745 121 -1835 191 -613 73 129 -1356 237 -717 -614 -114 -573 775 -434 -5 209 -17 389 -592 1221 -72 907 -160 589 338 322 604 170 1008 188 380 637 336 855 27 1178 307 927 1127 -18 964 -132 954 -287 320 600 -71 471 -647 421 -1089 -197 -306 -111 546 -825 791 -995 430 344 -156 358 -713 592 -31 876 628 -292 145 -202 140 317 -58 -897 -1397 -940 -1809 -205 -304 -977 -991 -207 215 321 968 724 977 -443 -1217 -180 71 651 -24 536 17 1218 2638 336 716 -355 -65 544 -135 -87 -1499 427 158 140 -739 -564 1087 -500 SS 20221116T171155.4Z 8355.716613 251 1 50.10 2 81.91 113.36 7.91 257.80 0.00 1 0.00 1 0 25 3.931e-01 5.105e-03 1.246e-01 1.181e-03 7.682696e-01 6.602541e-04 7.453803e-03 -6.000000e+00 2.350394e-01 223.84 -2.00 3.11 -2.00 321.33 0.00e+00 3.543918e-03 3.034909e-04 2.295137e-03 -6.000000e+00 1.006814e-02 270.19 -2.00 20.00 -2.00 320.93 0.00e+00 6.697 0.001 302.00 328.00 3 5.5903e-01 2.1075e-03 5.5955e-02 -6.0000e+00 5.8034e-01 9.2908e-03 3.1656e-03 4.1417e-02 -6.0000e+00 6.3147e-01 -3.4572e-02 3.7423e-03 2.1074e-02 -6.0000e+00 3.7473e-01 2.8928e-03 1.7841e-03 8.1761e-03 -6.0000e+00 1.5652e-01 2.1754e-03 -4.0736e-04 3.5198e-05 9.6528e-05 -6.0000e+00 1.2500e-02 5.7005e-03 0.0000e+00 10 0 0 10 0 0 9.37 19.69 0.34 0.00570 0.00264 397 78 1 5 0 126.180 24.86 20.01 19.69 7.21 14.9 655.61 -163731 -90045 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254 88 -134 -3 140 199 323 490 524 335 520 289 234 447 362 167 2 61 -196 -146 -159 86 149 241 -143 -183 -642 -882 -809 -421 -587 -302 -222 -197 33 182 343 772 811 678 593 691 472 -134 -186 -26 122 383 300 -1056 -1380 -1170 -961 -289 -77 -327 -374 88 336 744 1219 1180 809 -334 -1068 -1131 -290 -182 -51 203 210 1191 2007 864 176 -109 -256 136 368 -758 -812 -315 -269 -537 -443 395 486 557 SS 20221116T172642.1Z 8355.726877 256 1 50.06 2 78.73 114.83 11.30 262.25 0.00 1 0.00 1 0 25 1.296e-01 5.438e-03 1.891e-02 5.142e-04 5.886467e-01 2.751401e-04 6.004959e-03 -6.000000e+00 7.748194e-02 223.84 -2.00 3.11 -2.00 320.33 0.00e+00 1.776350e-03 9.739088e-05 8.617537e-04 -6.000000e+00 3.318989e-03 270.19 -2.00 20.00 -2.00 319.90 0.00e+00 4.961 0.001 302.00 328.00 3 4.2026e-01 8.0398e-04 4.0727e-02 -6.0000e+00 1.9131e-01 -1.4656e-02 1.0060e-03 2.7884e-02 -6.0000e+00 2.0817e-01 -9.8127e-03 1.0004e-03 1.4063e-02 -6.0000e+00 1.2353e-01 -3.3508e-03 5.1138e-04 4.8088e-03 -6.0000e+00 5.1600e-02 8.2543e-03 -2.5984e-04 1.5941e-05 6.1304e-05 -6.0000e+00 4.1207e-03 5.5855e-03 0.0000e+00 10 0 0 10 0 0 17.75 19.71 0.32 0.00559 0.00363 772 153 1 5 0 64.840 24.86 20.00 19.71 8.22 15.0 661.02 -56309 -28573 -50226 -40562 -52267 -37755 -32561 -50798 -21436 -51015 -32712 -28408 -29195 -9324 -17396 -6345 -8783 -1295 -5401 -3607 -2938 -6422 -2195 -8869 -4580 -8771 -7803 -5621 -7244 -1730 -5534 -284 -3150 -3734 -1728 -4505 -1084 -3423 -1201 -1889 -2868 -868 -1949 198 -805 458 -187 316 1037 575 1903 1141 1887 998 976 1051 -47 -98 -500 587 712 1529 1668 723 637 359 1146 913 1334 1188 24 78 -418 142 -119 15 718 472 943 -277 -356 -1192 -1449 -1206 -1043 -780 -703 -240 -356 -65 377 801 1084 1079 1291 776 774 356 -237 -242 -376 -33 337 442 -796 -1257 -771 -796 -65 -23 -89 -240 -75 277 414 881 761 553 -150 -710 -674 -409 -47 -14 321 412 838 1509 659 263 -112 -148 20 138 -252 -376 -109 -104 -237 -183 7 197 151 -424 -188 -436 -315 -438 -275 -243 -515 -182 -634 -369 -353 -451 -148 -369 -142 -228 -34 -161 -112 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