File name: Pandora56s1_MaunaLoaHI_20230917_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T000224.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20230917_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20230917 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230917T190457.1Z 8660.795106 114 1 49.04 2 49.99 104.21 81.18 103.94 0.00 1 0.00 1 0 17 8.100e-03 5.975e-03 4.105e-03 2.151e-03 1.813615e-01 1.132994e-03 1.973178e-03 -6.000000e+00 4.874701e-03 225.33 -2.00 3.11 -2.00 316.03 0.00e+00 -3.299178e-05 1.178190e-04 2.939687e-05 -6.000000e+00 2.088689e-04 271.81 -2.00 20.00 -2.00 315.53 0.00e+00 1.553 0.000 302.00 328.00 3 5.7550e+00 2.9222e-03 1.2537e-02 -6.0000e+00 1.2070e-02 -7.7605e-03 3.2591e-03 8.1401e-03 -6.0000e+00 1.3113e-02 2.4126e-03 1.8762e-03 4.0588e-03 -6.0000e+00 7.7799e-03 -3.9832e-03 8.4741e-04 1.1574e-03 -6.0000e+00 3.2481e-03 5.3826e-04 -7.9601e-05 6.9875e-05 1.6998e-05 -6.0000e+00 2.5764e-04 5.5662e-03 -4.5259e-05 10 0 0 10 0 0 13.18 21.10 0.30 0.00557 0.00497 13 3 1 5 0 3771.520 26.00 20.00 21.10 21.95 18.3 724.12 -773 -834 -1417 -2076 -2278 480 -935 489 804 -2046 1443 -1799 2036 84 201 380 -323 1015 -311 1249 71 527 663 528 818 -46 -182 -91 36 1983 494 837 -65 -533 -1783 -1282 -705 -5 1271 -993 -72 -1759 -1078 -633 -1236 -114 -914 -539 -473 69 1332 905 298 897 1007 471 516 211 76 970 932 1484 1002 514 204 -533 -615 -84 1170 1002 213 271 182 149 -74 135 46 168 335 -752 -181 -1486 -1589 -1316 -701 -992 -571 53 -381 54 78 349 289 968 646 531 1002 262 15 -331 -421 -388 -22 809 -838 -981 -940 -535 192 160 14 -293 175 -7 86 138 550 769 43 -198 -364 -16 238 67 447 543 856 1239 940 73 97 -147 -245 367 -102 -222 -311 73 180 -264 -129 -428 -409 -171 -195 -334 -462 -471 93 -190 107 188 -511 354 -460 540 25 66 132 -117 373 -119 481 28 207 265 219 347 -20 -79 -38 14 742 192 339 -27 -228 -746 -537 -311 -3 719 -639 -50 -1285 -801 -471 -922 -83 -655 -377 -321 47 912 655 225 700 807 381 422 172 62 787 768 1286 918 487 191 -479 -526 -69 987 917 208 278 185 149 -70 120 38 131 265 -636 -167 -1493 -1688 -1452 -808 -1196 -714 68 -493 69 93 389 303 962 660 578 1161 326 19 -429 -526 -464 -25 942 -1030 -1266 -1257 -736 270 234 21 -445 258 -9 115 175 687 976 58 -277 -528 -23 337 93 593 692 1051 1515 1179 97 132 -204 -346 524 -151 -343 -492 118 290 -426 -202 -661 -627 SS 20230917T191037.9Z 8660.799050 117 1 51.22 2 48.70 104.97 79.93 104.47 0.00 1 0.00 1 0 17 8.088e-03 5.672e-03 3.888e-03 2.080e-03 1.755208e-01 1.096907e-03 1.913836e-03 -6.000000e+00 4.867380e-03 225.33 -2.00 3.11 -2.00 315.97 0.00e+00 1.514119e-04 1.122477e-04 2.427914e-05 -6.000000e+00 2.085538e-04 271.81 -2.00 20.00 -2.00 315.47 0.00e+00 1.513 0.000 302.00 328.00 3 5.7479e+00 2.8277e-03 1.2181e-02 -6.0000e+00 1.2052e-02 -1.2665e-02 3.1521e-03 7.8863e-03 -6.0000e+00 1.3093e-02 3.1167e-03 1.8131e-03 3.9320e-03 -6.0000e+00 7.7682e-03 -3.2243e-03 8.1581e-04 1.1252e-03 -6.0000e+00 3.2431e-03 5.6231e-04 -9.2483e-05 6.7515e-05 1.6573e-05 -6.0000e+00 2.5725e-04 6.3840e-03 -1.2398e-05 10 0 0 10 0 0 5.12 21.12 0.26 0.00638 0.00569 14 3 1 5 0 3658.420 26.00 20.02 21.12 22.18 18.3 725.79 -271 -261 -2348 -2199 -3442 -1950 -1064 1208 1663 -92 222 535 -20 247 253 -9 -1022 515 813 428 262 51 812 1562 647 -130 -24 -462 -266 1629 1038 2309 650 -222 -1152 -619 -857 -488 595 -908 -1302 -1557 -553 -1015 -320 -633 -63 -323 -98 -26 529 921 1057 460 731 540 177 425 252 620 1089 1363 734 1044 -448 -777 -62 -327 1100 614 229 26 -40 181 72 -91 355 62 936 -148 -519 -1405 -1370 -1099 -804 -668 -386 -367 -615 27 54 327 547 1038 971 859 551 248 33 -178 -591 -481 -48 146 -583 -631 -502 -991 -110 359 114 -183 -287 48 -39 791 458 870 -106 -6 -299 -233 252 123 515 725 750 1004 671 542 -21 -469 136 -132 -258 9 185 -30 -127 -126 -149 -334 -520 -61 -63 -577 -506 -744 -397 -223 270 401 -23 57 138 -5 76 85 -3 -381 194 313 169 105 20 328 650 282 -58 -11 -194 -106 618 404 931 275 -95 -489 -259 -380 -244 340 -593 -918 -1138 -409 -760 -237 -471 -45 -226 -67 -18 370 665 799 359 585 441 146 350 205 503 904 1179 671 992 -428 -705 -53 -271 922 560 224 27 -41 181 69 -80 291 48 729 -125 -480 -1396 -1436 -1212 -929 -803 -483 -474 -799 34 65 365 566 1033 988 930 640 312 43 -232 -738 -575 -55 171 -714 -811 -667 -1366 -157 529 172 -277 -425 67 -52 990 571 1098 -142 -9 -433 -338 357 170 680 920 919 1227 841 707 -29 -648 190 -189 -381 14 292 -49 -206 -201 -235 -513 -792 SS 20230917T191614.8Z 8660.802949 120 1 50.61 2 47.42 105.76 78.69 105.02 0.00 1 0.00 1 0 17 7.897e-03 5.815e-03 3.702e-03 2.027e-03 1.708797e-01 1.069605e-03 1.856187e-03 -6.000000e+00 4.753579e-03 225.33 -2.00 3.11 -2.00 315.87 0.00e+00 5.390709e-05 1.073116e-04 2.892010e-05 -6.000000e+00 2.036517e-04 271.81 -2.00 20.00 -2.00 315.38 0.00e+00 1.476 0.000 302.00 328.00 3 5.7347e+00 2.7541e-03 1.1861e-02 -6.0000e+00 1.1770e-02 -1.3821e-02 3.0686e-03 7.6545e-03 -6.0000e+00 1.2786e-02 5.0534e-03 1.7631e-03 3.8168e-03 -6.0000e+00 7.5862e-03 -5.3363e-03 7.9067e-04 1.0891e-03 -6.0000e+00 3.1679e-03 5.8862e-04 4.7493e-05 6.5731e-05 1.6107e-05 -6.0000e+00 2.5118e-04 4.5531e-03 -3.2902e-05 10 0 0 10 0 0 46.54 21.14 0.31 0.00455 0.00491 14 3 1 5 0 3614.920 26.00 20.01 21.14 22.35 18.3 726.43 -1462 -273 -1308 -1309 -1278 805 1399 477 1608 -2382 -512 257 34 658 276 136 -2260 -224 1016 -480 81 1573 1642 445 647 277 7 62 -326 1054 1105 1521 822 -401 -2089 -249 125 -749 388 -1612 -1357 -811 -1095 -145 -494 -654 -580 -417 -441 -200 1819 410 268 729 813 847 231 535 123 933 1486 1358 1141 262 -256 -1022 -136 228 789 1071 341 171 -320 183 211 -190 204 251 1046 -371 -779 -1086 -1477 -1002 -1043 -836 -441 136 -335 -376 -26 -1 798 578 1253 521 502 297 -505 7 -277 -301 -214 409 -464 -1048 -569 -627 6 333 10 -136 -276 393 -35 470 265 451 410 -80 -309 -240 337 214 445 717 443 854 1016 278 -28 -307 90 89 -22 -327 3 351 -178 -349 -220 -74 -626 -349 -68 -330 -309 -279 165 296 111 402 -634 -136 69 10 206 96 50 -877 -87 401 -196 34 639 676 192 290 125 3 27 -134 412 439 630 354 -176 -912 -106 56 -383 227 -1071 -968 -602 -824 -110 -375 -491 -424 -298 -306 -137 1276 303 205 579 661 692 192 442 101 768 1235 1195 1059 252 -245 -933 -116 188 672 985 335 174 -330 184 202 -171 168 196 821 -317 -720 -1087 -1568 -1105 -1196 -1010 -554 176 -432 -475 -32 -2 832 576 1267 565 582 368 -657 10 -345 -359 -246 476 -567 -1353 -758 -863 9 485 14 -206 -410 552 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