File name: Pandora56s1_MaunaLoaHI_20231012_L2Fit_fwvt1c9d20210409p1-8.txt File generation date: 20250131T223632.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20231012_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20231012 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1715 1864 Nominal wavelengths inside fitting window [nm]: 492.1202 492.2407 492.3612 492.4817 492.6021 492.7225 492.8430 492.9634 493.0838 493.2041 493.3245 493.4448 493.5651 493.6854 493.8057 493.9260 494.0463 494.1665 494.2867 494.4069 494.5271 494.6473 494.7674 494.8876 495.0077 495.1278 495.2479 495.3679 495.4880 495.6080 495.7281 495.8481 495.9680 496.0880 496.2080 496.3279 496.4478 496.5677 496.6876 496.8075 496.9273 497.0472 497.1670 497.2868 497.4066 497.5263 497.6461 497.7658 497.8855 498.0052 498.1249 498.2446 498.3642 498.4839 498.6035 498.7231 498.8426 498.9622 499.0818 499.2013 499.3208 499.4403 499.5598 499.6792 499.7987 499.9181 500.0375 500.1569 500.2763 500.3957 500.5150 500.6343 500.7537 500.8730 500.9922 501.1115 501.2307 501.3500 501.4692 501.5884 501.7075 501.8267 501.9458 502.0650 502.1841 502.3032 502.4222 502.5413 502.6603 502.7794 502.8984 503.0174 503.1363 503.2553 503.3742 503.4932 503.6121 503.7310 503.8498 503.9687 504.0875 504.2063 504.3251 504.4439 504.5627 504.6815 504.8002 504.9189 505.0376 505.1563 505.2750 505.3936 505.5122 505.6309 505.7495 505.8680 505.9866 506.1052 506.2237 506.3422 506.4607 506.5792 506.6976 506.8161 506.9345 507.0529 507.1713 507.2897 507.4081 507.5264 507.6447 507.7630 507.8813 507.9996 508.1179 508.2361 508.3543 508.4725 508.5907 508.7089 508.8271 508.9452 509.0633 509.1814 509.2995 509.4176 509.5357 509.6537 509.7717 509.8897 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231012T171906.8Z 8685.721606 104 1 50.95 2 76.21 103.25 54.35 100.08 0.00 1 0.00 1 0 22 2.950e-03 2.940e-03 1.054e-03 1.052e-03 9.862568e+02 5.984179e+01 8.398326e+01 -6.000000e+00 1.620848e+02 271.16 -2.00 20.00 -2.00 505.25 0.00e+00 2.084060e-04 2.841646e-05 1.314020e-05 -6.000000e+00 8.152976e-05 271.16 -2.00 20.00 -2.00 500.37 0.00e+00 2.872666e-01 2.122183e-02 5.145334e-03 -6.000000e+00 5.992702e-02 225.04 -2.00 3.11 -2.00 501.97 0.00e+00 4.109 0.000 489.00 513.00 1 7.2248e+00 1.6230e-03 3.6309e-03 -6.0000e+00 4.5805e-03 8.0158e-03 4.1828e-04 2.4688e-04 -6.0000e+00 1.1884e-03 9.7527e-04 7.6732e-03 1.1523e-04 1.3131e-05 -6.0000e+00 3.3220e-04 -3.2270e-03 4.8101e-06 10 0 0 10 0 0 -37.19 20.21 2.63 -0.00323 0.05000 13 3 1 4 0 3918.650 25.28 20.01 20.21 15.88 18.0 693.66 -569 -237 -29 163 187 543 479 545 108 157 88 -411 -455 -221 -270 -594 27 63 149 -40 209 259 157 210 364 63 456 -228 -456 -235 -416 -188 305 541 -53 -159 192 158 -341 -15 373 73 241 160 324 199 187 339 -54 -565 -304 -798 -769 -229 -81 -52 -133 25 -379 32 91 283 -38 401 169 -115 269 -129 -125 -221 52 -199 -109 138 130 -403 -270 33 -195 59 -468 315 -366 -207 -110 -222 -194 -8 -149 -307 196 226 482 68 236 487 8 -388 193 -762 -454 -369 -278 -174 -367 -163 -171 -294 -17 92 127 158 327 65 157 375 385 269 357 350 200 -142 175 270 117 445 103 -81 136 295 -325 211 27 -300 -371 -9 110 -241 242 -176 322 141 290 207 -59 232 -360 -179 -590 -149 -559 -236 -29 168 196 575 510 579 115 164 91 -424 -465 -224 -274 -610 28 66 158 -43 222 276 167 224 388 67 479 -237 -466 -237 -420 -191 314 565 -57 -168 202 164 -353 -16 386 76 252 168 341 209 194 348 -55 -563 -298 -777 -747 -224 -81 -53 -136 26 -389 33 93 290 -38 407 171 -114 266 -127 -122 -214 51 -193 -106 135 128 -394 -260 32 -186 56 -448 301 -354 -201 -107 -218 -191 -8 -147 -304 194 226 481 68 234 477 7 -370 181 -714 -427 -352 -269 -171 -364 -161 -167 -287 -16 90 125 157 327 66 159 378 389 271 357 346 196 -139 170 263 114 434 101 -79 132 285 -313 201 25 -282 -349 -8 105 -234 236 -173 317 140 287 205 -58 228 -349 -171 -563 -141 SQ 20231012T172918.3Z 8685.728684 107 1 49.93 2 73.88 104.25 52.05 101.29 0.00 1 0.00 1 0 22 2.717e-03 2.708e-03 1.032e-03 1.029e-03 7.649298e+02 5.791413e+01 6.031623e+01 -6.000000e+00 1.492826e+02 271.16 -2.00 20.00 -2.00 505.25 0.00e+00 2.726960e-04 2.779466e-05 1.578146e-05 -6.000000e+00 7.509043e-05 271.16 -2.00 20.00 -2.00 500.38 0.00e+00 2.202110e-01 2.074014e-02 5.104568e-03 -6.000000e+00 5.519450e-02 225.04 -2.00 3.11 -2.00 501.98 0.00e+00 3.547 0.000 489.00 513.00 1 7.2272e+00 1.5859e-03 3.1509e-03 -6.0000e+00 4.2187e-03 5.6075e-03 4.0922e-04 2.1162e-04 -6.0000e+00 1.0946e-03 1.0262e-03 7.4572e-03 1.1299e-04 1.0597e-05 -6.0000e+00 3.0596e-04 -1.0939e-04 -1.5426e-05 10 0 0 10 0 0 -27.59 20.27 2.66 -0.00011 0.05162 13 3 1 4 0 3840.040 25.39 20.00 20.27 16.66 18.0 696.87 -357 -32 -29 -101 290 308 392 499 45 344 -88 -457 -282 -304 -438 -331 280 244 50 -16 2 201 11 240 232 88 460 -231 -456 11 -406 -218 227 626 -102 -68 165 -61 -22 -92 241 132 324 -9 239 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-208 -16 26 6 -222 100 -177 29 51 99 85 32 86 -246 -249 -286 -202 SQ 20231012T173952.3Z 8685.736022 111 1 50.78 2 71.47 105.34 49.67 102.61 0.00 1 0.00 1 0 22 2.740e-03 2.735e-03 1.001e-03 9.983e-04 7.590420e+02 5.613132e+01 6.279181e+01 -6.000000e+00 1.505425e+02 271.16 -2.00 20.00 -2.00 505.25 0.00e+00 2.791932e-04 2.697283e-05 1.754281e-05 -6.000000e+00 7.573610e-05 271.16 -2.00 20.00 -2.00 500.37 0.00e+00 1.399510e-01 2.015656e-02 4.326756e-03 -6.000000e+00 5.568903e-02 225.04 -2.00 3.11 -2.00 501.97 0.00e+00 3.112 0.000 489.00 513.00 1 7.2163e+00 1.5419e-03 2.7741e-03 -6.0000e+00 4.2561e-03 4.2768e-03 3.9796e-04 1.8574e-04 -6.0000e+00 1.1051e-03 1.0838e-03 8.5995e-03 1.0992e-04 1.1752e-05 -6.0000e+00 3.0856e-04 4.1720e-03 -8.6295e-05 10 0 0 10 0 0 -18.73 20.33 2.70 0.00417 0.06382 14 3 1 4 0 3626.600 25.39 20.00 20.33 17.33 18.1 700.52 -253 -278 179 -98 258 374 312 393 286 138 1 -322 -424 -74 -491 -543 369 308 263 -157 48 207 87 241 253 276 426 -211 -463 -274 -368 -410 235 470 -75 -148 207 45 -95 208 292 -54 147 -76 314 378 197 470 3 -486 -454 -671 -719 4 -151 -115 -41 -1 77 -103 125 395 8 267 -42 57 -90 -75 -337 -261 111 -453 48 43 -110 -323 -198 -175 -251 12 -225 -89 -436 -28 -78 -299 -2 -171 -45 -216 205 201 227 121 147 535 17 -315 -75 -549 -581 -514 -196 -260 -527 -260 120 7 -48 195 5 50 271 184 375 379 472 136 303 372 40 99 131 172 180 383 278 -15 184 381 -92 18 -47 114 -31 283 -199 -229 143 -56 29 42 195 -92 91 1 -247 -329 -499 -3 -252 -273 181 -102 274 389 327 413 297 142 1 -335 -436 -75 -504 -565 374 319 277 -167 51 220 93 257 270 293 446 -218 -466 -280 -377 -410 241 492 -80 -157 217 47 -98 214 301 -57 155 -80 333 400 206 482 3 -479 -437 -662 -686 4 -150 -117 -42 -1 80 -107 130 408 8 274 -42 57 -89 -73 -327 -251 106 -439 47 42 -108 -315 -190 -166 -237 11 -214 -85 -422 -27 -76 -297 -2 -170 -45 -209 200 199 226 120 145 515 17 -304 -71 -516 -549 -496 -186 -255 -522 -257 117 7 -47 189 5 50 273 187 382 388 483 139 306 370 40 97 127 167 176 374 272 -15 179 367 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