File name: Pandora56s1_MaunaLoaHI_20231215_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240224T000134.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20231215_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20231215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231215T194311.6Z 8749.821662 321 1 50.99 2 56.98 136.88 90.60 116.57 0.00 1 0.00 1 0 17 9.001e-03 6.028e-03 5.344e-03 2.358e-03 2.044128e-01 1.228640e-03 2.233381e-03 -6.000000e+00 5.364542e-03 222.73 -2.00 3.11 -2.00 316.55 0.00e+00 1.168542e-04 1.436658e-04 3.916775e-05 -6.000000e+00 2.300352e-04 269.56 -2.00 20.00 -2.00 316.08 0.00e+00 1.829 0.000 302.00 328.00 3 5.7539e+00 3.1723e-03 1.4384e-02 -6.0000e+00 1.3216e-02 -1.1704e-02 3.5503e-03 9.0949e-03 -6.0000e+00 1.4388e-02 7.1437e-03 2.0745e-03 4.5752e-03 -6.0000e+00 8.5419e-03 -6.2639e-03 9.6884e-04 1.3260e-03 -6.0000e+00 3.5789e-03 4.3786e-04 -3.3375e-04 7.6935e-05 1.9019e-05 -6.0000e+00 2.8609e-04 2.9549e-03 -1.1252e-04 11 1 0 11 8 0 39.00 20.85 0.29 0.00295 0.00045 13 3 1 5 0 3922.130 25.79 20.02 20.85 19.96 18.5 710.43 -133 -1804 -3401 -2915 -2406 139 -847 493 418 -1039 -405 -706 1798 205 2302 -1224 -362 439 72 1968 423 1063 -238 407 348 128 -498 -1423 156 648 1802 685 592 -695 -1253 -923 -1559 555 9 -1035 474 -1934 -582 -772 -993 -203 -1583 -426 -427 698 1883 1172 922 1065 702 554 1030 -212 213 1050 993 1668 630 749 -363 -573 -474 167 886 672 617 -7 161 -29 325 408 415 -64 -45 -606 -472 -1766 -1294 -1684 -692 -975 -189 125 -709 42 -196 118 396 797 964 597 572 493 173 -379 -515 -842 167 346 -451 -562 -519 -903 -316 236 200 -87 50 160 146 480 699 570 110 -201 -335 12 70 166 226 653 957 960 946 623 161 -494 -154 243 -580 -145 -199 40 76 -342 -57 -379 -204 -22 -330 -635 -518 -390 21 -137 85 79 -206 -81 -145 391 51 610 -362 -111 138 23 640 142 355 -82 145 127 48 -189 -517 53 215 606 243 221 -267 -468 -341 -623 246 5 -610 297 -1286 -392 -525 -675 -137 -1062 -275 -269 439 1210 790 656 780 532 428 801 -166 165 804 781 1365 550 682 -333 -501 -391 132 726 599 590 -7 161 -28 299 350 328 -49 -35 -502 -427 -1753 -1353 -1844 -788 -1174 -236 161 -911 53 -233 131 412 790 979 649 669 623 227 -497 -651 -1023 193 406 -554 -725 -694 -1253 -456 353 307 -135 76 232 197 620 883 742 151 -287 -496 17 102 235 307 848 1198 1189 1216 839 226 -710 -224 361 -900 -233 -327 67 128 -566 -93 -605 -319 SS 20231215T194536.9Z 8749.823344 323 1 49.84 2 56.59 137.36 90.11 116.76 0.00 1 0.00 1 0 25 9.597e-03 5.754e-03 5.278e-03 2.367e-03 2.032102e-01 1.231969e-03 2.200177e-03 -6.000000e+00 5.723711e-03 222.73 -2.00 3.11 -2.00 316.51 0.00e+00 3.953281e-04 1.429057e-04 4.033970e-05 -6.000000e+00 2.452563e-04 269.56 -2.00 20.00 -2.00 316.04 0.00e+00 1.811 0.000 302.00 328.00 3 5.7510e+00 3.1792e-03 1.4238e-02 -6.0000e+00 1.4102e-02 -7.7522e-03 3.5590e-03 9.0108e-03 -6.0000e+00 1.5348e-02 3.5371e-03 2.0748e-03 4.5219e-03 -6.0000e+00 9.1116e-03 -4.0150e-03 9.6575e-04 1.3545e-03 -6.0000e+00 3.8208e-03 4.4424e-04 6.2361e-04 7.7195e-05 1.8820e-05 -6.0000e+00 3.0496e-04 5.7403e-04 2.4217e-05 11 1 0 11 8 0 7.34 20.86 0.32 0.00057 0.00526 13 3 1 5 0 3833.300 25.79 20.01 20.86 20.10 18.5 710.81 -941 -2224 -3145 -2762 -3609 -1064 2076 -829 2050 -2599 71 -1234 -115 560 53 797 -1580 967 729 1074 592 1212 131 1025 809 -979 18 -1052 587 1086 1293 2189 717 -1843 -2588 -351 -807 238 191 -1230 644 -1141 -1118 -494 -815 -490 -593 284 44 510 189 1261 1465 1028 934 497 164 674 263 528 1255 942 559 449 -779 -455 -627 -131 842 1122 583 541 -392 -435 291 185 18 228 426 -603 -621 -1301 -1256 -1023 -799 -705 -327 54 -363 -169 -218 240 564 671 595 399 261 505 4 -207 -603 -197 333 355 -838 -1226 -63 -785 33 321 130 -316 -359 200 38 466 645 592 -18 -128 -372 -112 373 127 460 954 978 767 1062 588 16 -421 -29 147 -306 -240 39 -10 -135 -303 156 -641 -320 -166 -419 -608 -501 -606 -169 332 -147 384 -531 14 -258 -26 140 15 235 -497 306 238 357 201 409 45 366 301 -375 7 -384 199 361 441 782 270 -721 -987 -131 -322 106 99 -729 404 -765 -760 -336 -562 -334 -396 182 28 323 124 852 1040 755 707 385 129 525 204 407 986 777 489 411 -718 -398 -518 -104 691 995 558 536 -395 -425 271 160 15 172 328 -505 -563 -1284 -1312 -1113 -911 -847 -408 69 -464 -211 -259 266 585 673 605 434 306 637 6 -274 -761 -237 384 416 -1031 -1588 -85 -1085 47 478 200 -488 -545 288 52 600 812 769 -25 -183 -550 -165 537 179 620 1231 1219 959 1358 790 22 -602 -42 218 -471 -385 63 -16 -226 -505 251 -1021 -503 SS 20231215T195300.8Z 8749.828481 333 1 51.75 2 55.42 138.85 88.61 117.35 0.00 1 0.00 1 0 17 1.020e-02 6.038e-03 4.843e-03 2.249e-03 1.998603e-01 1.172664e-03 2.181434e-03 -6.000000e+00 6.081084e-03 222.73 -2.00 3.11 -2.00 316.40 0.00e+00 -2.041304e-04 1.322835e-04 4.929566e-05 -6.000000e+00 2.607314e-04 269.56 -2.00 20.00 -2.00 315.93 0.00e+00 1.757 0.000 302.00 328.00 3 5.7525e+00 3.0212e-03 1.3913e-02 -6.0000e+00 1.4982e-02 -7.5832e-03 3.3802e-03 8.8808e-03 -6.0000e+00 1.6309e-02 5.1074e-03 1.9672e-03 4.4661e-03 -6.0000e+00 9.6824e-03 -4.9692e-03 9.1055e-04 1.3042e-03 -6.0000e+00 4.0572e-03 4.6172e-04 -2.5115e-04 7.3125e-05 1.8719e-05 -6.0000e+00 3.2422e-04 3.2371e-03 -6.0534e-05 11 1 0 11 8 0 34.06 20.90 0.53 0.00324 0.00135 13 3 1 5 0 3980.620 25.90 20.01 20.90 20.27 18.4 710.85 1162 -2793 -2378 -3320 -3335 -407 -616 3581 257 -1049 -3649 -68 64 236 1565 -373 -1303 -1152 610 865 1188 604 326 1517 1185 760 -565 -681 -234 1343 1539 720 2755 -2053 -1090 -1142 -291 400 -218 -1402 355 -1367 -1120 -1264 -350 -267 -300 -427 341 -34 661 212 1197 1070 521 907 437 488 -185 748 1178 1290 1186 307 58 -842 -424 461 1091 1091 782 -42 -319 76 518 68 438 289 -104 -9 -919 -1396 -1896 -1471 -1020 -688 -358 21 -686 -343 -104 113 186 1071 1053 423 876 319 -172 -206 -624 -334 429 348 -264 -852 -500 -625 16 153 -283 136 21 70 133 32 888 279 142 -7 -506 248 433 86 174 579 871 973 870 13 30 -74 369 320 -334 -173 -288 104 -282 -241 3 -296 -496 208 -556 -473 -627 -585 -67 -105 642 52 -224 -805 -15 15 61 443 -116 -420 -382 204 296 411 211 116 555 454 300 -223 -256 -83 457 535 266 1050 -820 -423 -440 -119 185 -116 -852 229 -930 -778 -886 -245 -185 -203 -281 220 -22 438 147 864 797 402 710 348 387 -146 584 939 1075 1044 285 53 -747 -352 368 900 976 753 -43 -324 75 481 59 349 221 -81 -7 -839 -1387 -2003 -1616 -1173 -831 -449 27 -886 -433 -123 126 195 1062 1069 461 1021 399 -225 -269 -790 -404 496 409 -324 -1103 -669 -865 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