File name: Pandora56s1_MaunaLoaHI_20231223_L2Fit_fwvt1c0d20200803p1-8.txt File generation date: 20240224T001722.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20231223_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20231223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1714 1864 Nominal wavelengths inside fitting window [nm]: 492.0429 492.1635 492.2841 492.4047 492.5253 492.6458 492.7664 492.8869 493.0074 493.1279 493.2484 493.3688 493.4893 493.6097 493.7301 493.8505 493.9708 494.0912 494.2115 494.3319 494.4522 494.5724 494.6927 494.8130 494.9332 495.0534 495.1736 495.2938 495.4140 495.5341 495.6543 495.7744 495.8945 496.0146 496.1347 496.2547 496.3747 496.4948 496.6148 496.7348 496.8547 496.9747 497.0946 497.2145 497.3344 497.4543 497.5742 497.6940 497.8139 497.9337 498.0535 498.1733 498.2931 498.4128 498.5325 498.6523 498.7720 498.8916 499.0113 499.1310 499.2506 499.3702 499.4898 499.6094 499.7290 499.8485 499.9681 500.0876 500.2071 500.3266 500.4460 500.5655 500.6849 500.8043 500.9237 501.0431 501.1625 501.2818 501.4011 501.5205 501.6398 501.7590 501.8783 501.9975 502.1168 502.2360 502.3552 502.4744 502.5935 502.7127 502.8318 502.9509 503.0700 503.1891 503.3082 503.4272 503.5462 503.6652 503.7842 503.9032 504.0222 504.1411 504.2600 504.3789 504.4978 504.6167 504.7356 504.8544 504.9732 505.0921 505.2108 505.3296 505.4484 505.5671 505.6858 505.8045 505.9232 506.0419 506.1606 506.2792 506.3978 506.5164 506.6350 506.7536 506.8721 506.9907 507.1092 507.2277 507.3462 507.4647 507.5831 507.7015 507.8200 507.9384 508.0568 508.1751 508.2935 508.4118 508.5301 508.6484 508.7667 508.8850 509.0032 509.1214 509.2397 509.3579 509.4760 509.5942 509.7124 509.8305 509.9486 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231223T212927.5Z 8757.895457 135 1 50.02 2 44.75 162.91 131.58 35.30 0.00 1 0.00 1 0 15 2.277e-03 2.278e-03 2.506e-04 2.502e-04 2.241506e+02 1.356654e+01 1.261503e+01 -6.000000e+00 1.242320e+02 269.45 -2.00 20.00 -2.00 505.26 0.00e+00 2.111585e-04 6.728557e-06 1.416579e-05 -6.000000e+00 6.264279e-05 269.45 -2.00 20.00 -2.00 500.44 0.00e+00 -9.043602e-02 5.003045e-03 3.550094e-03 -6.000000e+00 4.592403e-02 222.59 -2.00 3.11 -2.00 502.04 0.00e+00 1.406 0.000 489.00 513.00 1 4.8138e+00 3.8277e-04 1.3004e-03 -6.0000e+00 3.5142e-03 -7.4194e-03 9.8382e-05 8.9557e-05 -6.0000e+00 9.0254e-04 1.4157e-02 1.2370e-03 2.7551e-05 6.0511e-06 -6.0000e+00 2.5568e-04 -7.5030e-03 -7.7371e-05 10 0 0 10 0 0 93.17 18.71 2.59 -0.00750 0.00108 156 31 1 4 0 320.620 22.19 20.25 18.71 19.17 20.5 715.71 -260 -328 -109 39 -109 259 480 465 407 274 289 166 -129 -293 -142 -283 -366 -66 112 -103 -91 110 59 102 334 231 247 355 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200 -2 17 177 176 244 379 475 405 248 296 160 104 369 300 37 153 240 120 201 303 -56 3 30 -143 -28 233 80 -171 -48 31 -16 85 204 104 56 -40 -275 -383 -257 -188 SQ 20231223T213502.4Z 8757.899333 138 1 50.00 2 44.38 164.66 130.83 36.62 0.00 1 0.00 1 0 15 2.242e-03 2.245e-03 2.400e-04 2.396e-04 2.107013e+02 1.295706e+01 1.264913e+01 -6.000000e+00 1.223363e+02 269.45 -2.00 20.00 -2.00 505.26 0.00e+00 1.921909e-04 6.440283e-06 1.292552e-05 -6.000000e+00 6.168001e-05 269.45 -2.00 20.00 -2.00 500.47 0.00e+00 -8.185274e-02 4.775954e-03 3.141235e-03 -6.000000e+00 4.519970e-02 222.59 -2.00 3.11 -2.00 502.06 0.00e+00 1.397 0.000 489.00 513.00 1 4.7304e+00 3.6533e-04 1.2797e-03 -6.0000e+00 3.4591e-03 -7.7876e-03 9.3843e-05 8.5316e-05 -6.0000e+00 8.8777e-04 1.5396e-02 1.4349e-03 2.6395e-05 5.5858e-06 -6.0000e+00 2.5179e-04 -3.5033e-03 -5.4193e-05 10 0 0 10 0 0 93.51 19.70 2.60 -0.00350 0.00645 167 33 1 4 0 299.350 24.35 20.07 19.70 20.59 19.9 717.92 -211 -310 -86 -18 -108 271 515 487 351 309 285 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-121 -231 -230 -294 -432 -321 33 -35 -390 -313 -126 -159 69 250 -6 25 125 155 224 386 448 355 287 264 86 61 366 320 4 208 164 92 243 206 -98 -4 -4 -159 33 283 55 -206 -35 44 -10 113 203 128 43 -67 -256 -336 -195 -191 SQ 20231223T214033.8Z 8757.903169 141 1 50.24 2 44.05 166.42 130.06 37.88 0.00 1 0.00 1 0 15 2.170e-03 2.170e-03 2.292e-04 2.289e-04 2.314617e+02 1.240235e+01 1.182845e+01 -6.000000e+00 1.184033e+02 269.45 -2.00 20.00 -2.00 505.26 0.00e+00 1.901556e-04 6.158249e-06 1.227022e-05 -6.000000e+00 5.969253e-05 269.45 -2.00 20.00 -2.00 500.46 0.00e+00 -5.759749e-02 4.571029e-03 3.601293e-03 -6.000000e+00 4.373262e-02 222.59 -2.00 3.11 -2.00 502.06 0.00e+00 1.390 0.000 489.00 513.00 1 4.6472e+00 3.4990e-04 1.2774e-03 -6.0000e+00 3.3470e-03 -7.8829e-03 8.9693e-05 9.0884e-05 -6.0000e+00 8.5867e-04 1.6712e-02 1.7013e-03 2.5194e-05 5.1808e-06 -6.0000e+00 2.4372e-04 5.4636e-04 -5.2723e-05 10 0 0 10 0 0 99.75 20.38 2.61 0.00055 0.01235 174 34 1 4 0 288.720 25.17 20.03 20.38 21.55 19.4 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