File name: Pandora56s1_MaunaLoaHI_20240222_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T224721.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20240222_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20240222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240222T193328.2Z 8818.814910 66 1 48.57 2 53.82 119.37 131.58 323.20 0.00 1 0.00 1 0 17 8.134e-03 5.698e-03 4.233e-03 2.091e-03 1.931105e-01 1.093061e-03 2.094527e-03 -6.000000e+00 4.862071e-03 223.41 -2.00 3.11 -2.00 316.21 0.00e+00 2.012591e-04 1.179155e-04 4.213961e-05 -6.000000e+00 2.077632e-04 269.41 -2.00 20.00 -2.00 315.75 0.00e+00 1.690 0.000 302.00 328.00 3 5.6833e+00 2.8141e-03 1.3405e-02 -6.0000e+00 1.1997e-02 -3.7008e-03 3.1441e-03 8.5635e-03 -6.0000e+00 1.3053e-02 -1.0929e-03 1.8196e-03 4.2953e-03 -6.0000e+00 7.7451e-03 -3.7217e-03 8.3348e-04 1.2436e-03 -6.0000e+00 3.2411e-03 5.2181e-04 -1.4875e-04 6.7995e-05 1.7876e-05 -6.0000e+00 2.5854e-04 -4.3884e-03 0.0000e+00 11 1 0 11 8 0 75.11 21.04 0.48 -0.00439 -0.00551 13 3 1 5 0 3735.960 26.00 20.03 21.04 22.78 18.4 721.91 1116 -2380 -2517 -2188 -1506 218 -1047 905 -45 -546 -1514 -22 731 1237 707 -204 664 280 1477 81 859 1346 154 1309 -761 -323 -837 -1447 736 541 1349 647 -384 -754 -2335 287 -1807 448 -404 -293 -369 -1192 -398 -1243 -570 -422 -669 -829 -120 282 618 1314 837 970 420 955 1257 284 361 978 694 1091 882 768 -287 -482 -624 -48 1014 1196 712 223 102 107 10 202 230 121 111 -247 -751 -1619 -1450 -1372 -838 -870 -675 -183 -125 -136 6 28 160 1072 664 427 448 513 46 -542 -455 -685 415 522 -672 -626 -815 -403 -87 194 162 -116 -115 152 247 309 291 700 324 87 -94 -251 197 228 470 774 472 1053 890 130 -42 -381 -199 41 -381 -158 -113 273 49 -350 20 -315 -453 222 -514 -546 -454 -284 39 -195 180 -10 -125 -351 -5 183 344 215 -67 226 98 527 30 320 500 59 512 -310 -134 -346 -581 272 195 492 250 -157 -314 -956 113 -781 213 -223 -182 -246 -840 -285 -905 -411 -301 -467 -562 -80 187 420 919 618 746 328 756 1002 228 287 783 562 932 793 722 -271 -428 -524 -40 841 1086 683 225 104 106 9 177 186 94 87 -209 -693 -1624 -1529 -1502 -955 -1042 -852 -233 -161 -171 8 31 166 1069 680 465 528 638 60 -707 -574 -822 477 608 -829 -806 -1087 -551 -123 285 245 -177 -172 216 329 397 366 904 438 123 -137 -367 282 319 632 1000 585 1301 1123 171 -57 -537 -286 59 -573 -246 -182 441 80 -568 32 -489 -701 SS 20240222T193904.6Z 8818.818803 69 1 51.81 2 52.67 120.33 132.34 324.55 0.00 1 0.00 1 0 17 7.923e-03 5.498e-03 3.814e-03 1.923e-03 1.863564e-01 1.006019e-03 2.030942e-03 -6.000000e+00 4.736077e-03 223.41 -2.00 3.11 -2.00 316.15 0.00e+00 3.328524e-04 1.070916e-04 3.962175e-05 -6.000000e+00 2.023753e-04 269.41 -2.00 20.00 -2.00 315.69 0.00e+00 1.646 0.000 302.00 328.00 3 5.6010e+00 2.5883e-03 1.3016e-02 -6.0000e+00 1.1686e-02 -1.0354e-02 2.8908e-03 8.2913e-03 -6.0000e+00 1.2715e-02 1.5623e-03 1.6716e-03 4.1584e-03 -6.0000e+00 7.5443e-03 -4.7972e-03 7.6283e-04 1.2168e-03 -6.0000e+00 3.1571e-03 5.9058e-04 1.1112e-05 6.2489e-05 1.7454e-05 -6.0000e+00 2.5184e-04 -4.5476e-03 0.0000e+00 10 0 0 10 0 0 93.93 21.09 0.27 -0.00455 -0.00446 15 3 1 5 0 3453.820 26.00 20.00 21.09 22.49 18.3 718.67 682 -1806 -879 -2820 -2816 50 -2050 1881 -333 -600 -18 -1294 227 -253 992 -29 -912 1127 -59 -47 722 966 71 1262 1049 -309 655 -1286 -717 941 475 771 724 67 -1721 -1349 -104 237 -131 -481 -860 -1216 -431 -803 -1045 -466 -674 -151 137 331 965 608 989 1132 901 953 1400 -65 30 768 1324 1262 1053 821 -229 -491 -376 -418 701 455 770 -31 -318 9 -52 123 -368 -364 536 -128 -1073 -1179 -1290 -1367 -765 -794 -303 -39 -308 -281 -388 471 -19 834 142 754 743 452 24 -232 -467 -627 -194 276 -553 -583 -534 -706 22 383 272 -35 118 163 356 505 97 500 57 -9 -430 41 567 -13 770 259 944 885 729 54 38 -200 -293 -63 -199 -293 -173 106 163 -215 46 -410 -440 139 -403 -195 -600 -555 9 -397 382 -75 -141 -4 -314 59 -72 309 -10 -320 397 -22 -18 272 364 27 498 431 -132 273 -519 -274 343 178 303 298 28 -710 -550 -44 113 -73 -303 -586 -861 -310 -585 -761 -334 -478 -103 91 221 660 433 729 868 712 765 1132 -52 24 615 1084 1081 953 767 -215 -439 -319 -343 590 411 744 -31 -324 9 -49 109 -301 -284 420 -107 -991 -1164 -1349 -1492 -873 -956 -379 -51 -395 -353 -467 526 -20 832 146 820 867 564 31 -303 -589 -751 -224 321 -680 -754 -717 -970 31 564 413 -54 175 232 477 639 122 637 77 -13 -626 59 805 -18 1033 331 1174 1087 918 71 52 -278 -416 -91 -298 -458 -276 171 266 -347 72 -640 -680 SS 20240222T194439.5Z 8818.822679 72 1 50.12 2 51.54 121.32 133.07 325.93 0.00 1 0.00 1 0 17 7.795e-03 5.458e-03 3.470e-03 1.780e-03 1.833767e-01 9.313433e-04 1.996176e-03 -6.000000e+00 4.659844e-03 223.41 -2.00 3.11 -2.00 316.10 0.00e+00 2.145935e-04 9.791322e-05 6.902745e-05 -6.000000e+00 1.991095e-04 269.41 -2.00 20.00 -2.00 315.64 0.00e+00 1.605 0.000 302.00 328.00 3 5.4432e+00 2.3945e-03 1.2730e-02 -6.0000e+00 1.1498e-02 -1.3838e-02 2.6746e-03 8.1328e-03 -6.0000e+00 1.2510e-02 -8.1170e-04 1.5443e-03 4.0807e-03 -6.0000e+00 7.4228e-03 -3.0063e-03 7.0286e-04 1.1800e-03 -6.0000e+00 3.1064e-03 7.1453e-04 -9.8322e-05 5.7925e-05 1.7104e-05 -6.0000e+00 2.4777e-04 -4.9077e-03 0.0000e+00 10 0 0 10 0 0 93.65 21.13 0.39 -0.00491 -0.00565 17 3 1 5 0 2947.820 26.00 20.02 21.13 22.42 18.3 719.54 -259 -925 -2161 -2730 -728 1250 193 2349 1097 -1438 -1945 640 -127 -3 1089 52 -266 -25 205 -305 348 1076 573 974 49 958 -661 -703 344 785 760 -130 1376 -490 -1936 -407 -1382 246 -570 -960 -70 -579 -1211 -1216 -993 -1007 -477 -621 140 665 1239 1084 955 1063 916 680 444 457 261 367 1312 1340 1088 798 127 -475 -455 -473 295 1404 321 325 77 293 251 -264 169 118 -136 -233 -723 -1441 -1579 -1409 -470 -758 -237 -287 -332 -349 -101 -225 -21 717 513 782 477 223 107 -194 -439 -810 -76 77 -146 -821 -429 -532 -107 189 225 314 104 222 155 321 388 645 273 -1 -153 -63 22 360 431 919 653 684 527 222 -159 -621 -236 -65 -226 -250 -89 209 -75 0 47 -249 -498 -55 -211 -500 -597 -145 236 38 488 250 -350 -478 156 -34 -1 346 18 -94 -9 76 -117 134 412 223 392 21 410 -284 -287 132 291 287 -52 569 -206 -809 -166 -600 119 -321 -606 -48 -411 -888 -899 -730 -732 -341 -430 94 445 850 773 708 820 727 544 360 369 209 297 1066 1152 988 750 119 -426 -383 -389 249 1272 312 328 78 293 238 -232 137 92 -107 -196 -665 -1428 -1657 -1539 -535 -913 -297 -367 -427 -441 -120 -251 -22 717 525 840 557 280 140 -254 -555 -973 -88 90 -179 -1054 -570 -730 -151 277 338 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