File name: Pandora56s1_MaunaLoaHI_20240623_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240624T103237.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20240623_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20240623 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240623T161553.5Z 8940.677703 204 1 50.27 2 84.34 67.15 78.29 235.97 0.00 1 0.00 1 0 25 8.772e-01 9.960e-03 3.191e-01 3.716e-03 9.446347e-01 2.279275e-03 8.834495e-03 -6.000000e+00 5.409326e-01 226.32 -2.00 3.11 -2.00 322.08 0.00e+00 6.309988e-03 1.270358e-03 4.348068e-03 -6.000000e+00 2.666918e-02 272.28 -2.00 20.00 -2.00 321.68 0.00e+00 9.031 0.003 302.00 328.00 3 7.7281e-01 8.5439e-03 7.7915e-02 -6.0000e+00 1.3451e+00 1.3913e-01 1.5104e-02 6.4950e-02 -6.0000e+00 1.4664e+00 -2.3413e-01 1.8255e-02 3.1265e-02 -6.0000e+00 8.6235e-01 8.8804e-02 8.0934e-03 1.1155e-02 -6.0000e+00 3.6008e-01 3.8254e-04 -9.0525e-04 1.1297e-04 1.4829e-04 -6.0000e+00 2.9372e-02 7.0716e-03 -1.2442e-04 12 8 8 10 0 0 -12.53 20.25 0.47 0.00707 0.00027 140 28 1 5 0 359.010 25.39 19.99 20.25 13.71 19.1 678.66 900000 -356484 -218297 900000 -371798 900000 -297382 900000 -245150 -270787 900000 -306231 900000 -244635 900000 -36684 -143251 900000 -177175 900000 -107525 900000 11276 -89717 62011 -139874 900000 -131700 900000 -40931 34644 76589 -60414 333950 -30542 90152 -36078 -22754 20292 -39356 29650 -36795 29488 5776 -2701 44256 -11665 77775 -6749 30433 10280 7994 28876 -3637 19006 -7630 17307 -1209 -200 15827 -8562 13620 1207 12313 4939 7523 5543 1116 10779 -1070 5672 4628 -16 5159 -2211 6593 -3391 4485 -570 2697 3198 -2706 1651 -1978 601 -2382 -304 -160 -2304 2314 -1885 2458 -526 580 1396 -858 1605 -724 335 -477 -651 230 -512 302 -2245 -860 -1886 -1107 -213 -1105 293 -1041 625 -364 286 744 535 1183 -896 216 -283 -13 316 -335 872 -282 1388 1393 690 289 -414 515 -438 321 -379 -321 84 -259 284 -289 243 -77 -119 900000 -2109 -789 900000 -2810 900000 -1173 900000 -886 -1157 900000 -2717 900000 -2251 900000 -133 -989 900000 -2213 900000 -816 900000 41 -681 224 -1839 900000 -1857 900000 -296 150 277 -1026 1207 -431 391 -613 -403 286 -1099 525 -1270 618 161 -77 912 -406 1321 -268 940 446 407 1348 -261 1174 -649 1183 -99 -16 1061 -763 1083 126 1327 630 977 765 174 1707 -218 1189 1025 -4 1053 -442 1096 -598 772 -120 663 939 -982 642 -863 272 -1177 -154 -83 -1212 1125 -905 1080 -238 277 760 -568 1127 -604 305 -448 -583 186 -376 231 -1673 -667 -1574 -999 -214 -1283 382 -1503 924 -543 413 1042 754 1714 -1380 336 -433 -20 438 -449 1115 -355 1702 1805 1025 499 -815 1105 -945 738 -939 -838 225 -699 755 -740 578 -170 -275 SS 20240623T162744.2Z 8940.685928 207 1 50.04 2 81.76 68.00 80.52 237.24 0.00 1 0.00 1 0 25 3.293e-01 5.163e-03 1.498e-01 1.161e-03 7.370300e-01 6.481152e-04 7.281948e-03 -6.000000e+00 1.987999e-01 226.32 -2.00 3.11 -2.00 321.20 0.00e+00 3.468654e-03 2.962528e-04 1.878886e-03 -6.000000e+00 8.504746e-03 272.28 -2.00 20.00 -2.00 320.77 0.00e+00 6.583 0.001 302.00 328.00 3 5.4206e-01 2.0944e-03 5.4508e-02 -6.0000e+00 4.9329e-01 1.7436e-02 2.9962e-03 3.9036e-02 -6.0000e+00 5.3555e-01 -4.1019e-02 3.3877e-03 1.9431e-02 -6.0000e+00 3.1760e-01 6.1742e-03 1.6226e-03 7.5929e-03 -6.0000e+00 1.3233e-01 2.4012e-03 -8.0837e-04 3.4719e-05 9.1007e-05 -6.0000e+00 1.0478e-02 6.5316e-03 -1.3364e-04 10 0 0 10 0 0 -1.56 20.27 0.30 0.00653 0.00046 370 73 1 5 0 135.220 25.39 20.00 20.27 14.16 19.1 681.10 -179817 27929 -132662 -16823 -60167 -136087 -134955 -133545 -54030 -72445 -14063 -85487 -78250 -43756 -59948 -26864 -41830 -13041 -17995 -30363 -17473 -46109 -10296 -30104 -11621 -15709 -25343 -25894 -34874 -6784 -13143 -134 -3266 -9748 -9612 -9039 -4894 -4790 -2240 -3870 -3192 -3665 -3754 43 -1023 2589 877 42 1216 437 2521 1560 4182 2063 1748 1801 -1182 504 -1315 944 1506 2478 2641 1490 1225 428 1795 1800 1703 1429 -31 485 -477 250 -616 -205 -378 -311 617 -138 -133 -840 -1332 -1118 -1223 -653 -822 -62 -71 -194 319 637 682 763 1021 803 867 386 -262 -61 -440 23 451 503 -660 -1409 -860 -848 -196 -93 -107 -350 -158 114 319 1002 816 737 -49 -508 -535 -309 20 -4 155 271 625 1308 606 188 -137 -120 -96 30 -229 -452 -128 -25 -139 -132 103 260 147 -957 32 -571 -23 -123 -601 -642 -711 -147 -262 -32 -474 -523 -272 -563 -222 -469 -124 -198 -402 -212 -767 -127 -494 -172 -258 -471 -487 -742 -122 -304 -3 -87 -301 -300 -287 -165 -192 -107 -223 -208 -263 -286 3 -81 204 73 4 114 45 285 201 582 321 293 316 -220 92 -241 168 277 496 598 383 337 121 505 531 554 528 -12 191 -188 101 -231 -70 -122 -102 225 -60 -62 -451 -795 -715 -834 -470 -621 -48 -54 -144 222 418 436 505 750 683 856 436 -300 -71 -487 25 450 490 -678 -1542 -992 -971 -246 -130 -166 -581 -266 188 504 1518 1234 1151 -81 -866 -909 -505 31 -6 224 378 852 1834 948 333 -251 -237 -202 67 -543 -1056 -307 -61 -336 -309 242 575 314 SS 20240623T164206.7Z 8940.695911 212 1 50.24 2 78.60 68.99 83.28 238.69 0.00 1 0.00 1 0 25 1.014e-01 5.088e-03 1.764e-02 5.196e-04 5.713238e-01 2.803274e-04 5.839449e-03 -6.000000e+00 6.123336e-02 226.32 -2.00 3.11 -2.00 320.24 0.00e+00 1.594811e-03 9.655751e-05 6.254699e-04 -6.000000e+00 2.619574e-03 272.28 -2.00 20.00 -2.00 319.78 0.00e+00 4.907 0.001 302.00 328.00 3 3.9221e-01 8.1243e-04 4.0118e-02 -6.0000e+00 1.5194e-01 -6.3513e-03 1.0076e-03 2.6958e-02 -6.0000e+00 1.6496e-01 -1.1595e-02 9.7179e-04 1.3598e-02 -6.0000e+00 9.7825e-02 -3.3019e-03 4.9713e-04 4.4569e-03 -6.0000e+00 4.0760e-02 8.8096e-03 -7.6205e-04 1.6152e-05 5.6906e-05 -6.0000e+00 3.2275e-03 6.1929e-03 -1.4597e-04 10 0 0 10 0 0 -8.53 20.31 0.32 0.00619 0.00047 731 144 1 5 0 68.530 25.39 20.01 20.31 14.93 19.2 685.00 -38563 -42073 -31267 -30801 -24869 -35686 -37289 -35710 -32826 -26472 -26961 -25375 -18345 -10614 -6964 -9606 -4209 -6208 -4534 -5508 -3499 -2613 -4078 -3993 -6380 -6122 -6799 -8211 -5246 -3637 -311 -1473 -183 -2536 -4657 -2262 -3420 -1583 -1702 -1289 -1532 -2076 -1568 -1710 -473 -526 -279 374 212 1184 1804 1573 1565 1390 961 566 -27 -397 -108 177 1043 1492 1740 1234 495 404 804 814 1357 1227 256 30 -191 -145 -11 -122 393 337 733 56 -369 -996 -1513 -1279 -906 -882 -524 -276 -292 -51 302 644 790 1153 1170 943 850 380 -156 -373 -379 -231 306 434 -713 -1130 -802 -657 -224 18 -124 -257 -92 155 402 809 854 603 48 -512 -652 -254 -68 10 317 375 773 1284 720 125 -69 -204 -120 77 -234 -315 -132 -44 -170 -140 73 130 81 -285 -371 -263 -254 -185 -297 -340 -362 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