File name: Pandora56s1_MaunaLoaHI_20240711_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240712T103330.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20240711_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20240711 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240711T173904.2Z 8958.735465 79 1 49.63 2 66.97 73.70 133.26 66.74 0.00 1 0.00 1 0 17 2.090e-02 5.675e-03 1.420e-02 2.922e-03 3.075040e-01 1.530665e-03 3.284399e-03 -6.000000e+00 1.259904e-02 225.81 -2.00 3.11 -2.00 318.15 0.00e+00 3.137619e-04 2.720057e-04 8.172485e-05 -6.000000e+00 5.395154e-04 272.08 -2.00 20.00 -2.00 317.62 0.00e+00 2.538 0.000 302.00 328.00 3 5.3769e+00 4.0806e-03 2.0924e-02 -6.0000e+00 3.1228e-02 -9.8935e-03 4.6035e-03 1.3931e-02 -6.0000e+00 3.3914e-02 5.4486e-03 2.9714e-03 6.9603e-03 -6.0000e+00 2.0117e-02 -7.9240e-03 1.5107e-03 2.0125e-03 -6.0000e+00 8.3920e-03 3.4516e-04 -5.2763e-04 9.5807e-05 2.6761e-05 -6.0000e+00 6.6503e-04 3.9122e-03 -1.6227e-04 11 1 0 11 8 0 25.07 20.31 0.42 0.00391 -0.00005 13 3 1 5 0 3816.990 25.39 20.01 20.31 12.50 19.0 671.70 5340 -4536 -4069 -6579 -3100 -4791 -7133 13 -4456 7722 -10054 3998 -6900 4050 -3358 -123 -1264 1376 -1613 -4400 1858 -3257 91 -2056 -693 1729 -2569 1327 2561 1259 793 -1056 3814 -78 -126 196 -2377 -115 -237 -1099 -797 -360 -829 134 -521 489 -524 -1040 1004 346 862 562 1213 2164 419 771 395 920 632 173 884 1317 1201 638 174 -659 -89 486 666 935 320 222 -35 -697 279 -1353 2 72 867 -387 -563 -1509 -1464 -1037 -707 -760 -643 -351 -342 -393 429 -150 883 930 612 773 388 208 254 25 -344 -515 137 552 -445 -621 -432 -457 -375 310 -125 -352 -18 221 361 256 607 159 264 -169 -264 -176 -34 61 170 615 559 1380 1260 400 -94 -642 110 193 -81 -432 -301 189 -455 -47 164 -111 -299 315 -323 -294 -465 -197 -305 -490 1 -357 586 -925 343 -730 442 -451 -18 -193 218 -271 -786 318 -592 17 -400 -140 352 -544 262 479 238 159 -235 866 -19 -30 46 -616 -34 -81 -433 -346 -164 -388 64 -250 231 -248 -486 457 161 420 290 662 1233 249 468 245 566 385 107 551 872 849 480 132 -482 -62 332 479 731 271 195 -31 -606 227 -1029 1 48 595 -294 -474 -1386 -1449 -1070 -765 -867 -763 -428 -418 -471 483 -158 866 896 609 831 455 266 341 34 -442 -631 160 646 -551 -807 -582 -641 -547 473 -200 -572 -29 337 523 354 821 222 386 -259 -411 -273 -52 90 242 844 737 1818 1727 584 -144 -1011 177 319 -139 -777 -552 353 -851 -87 295 -196 -514 SS 20240711T175341.4Z 8958.745618 84 1 49.75 2 63.66 74.49 130.21 69.09 0.00 1 0.00 1 0 17 1.228e-02 5.956e-03 9.298e-03 2.491e-03 2.737099e-01 1.306113e-03 2.930016e-03 -6.000000e+00 7.404106e-03 225.81 -2.00 3.11 -2.00 317.65 0.00e+00 -1.683785e-04 2.021695e-04 8.915729e-05 -6.000000e+00 3.169832e-04 272.08 -2.00 20.00 -2.00 317.12 0.00e+00 2.242 0.000 302.00 328.00 3 5.3566e+00 3.4490e-03 1.8524e-02 -6.0000e+00 1.8352e-02 -1.4789e-02 3.8751e-03 1.2352e-02 -6.0000e+00 1.9928e-02 9.8972e-03 2.3907e-03 6.1625e-03 -6.0000e+00 1.1821e-02 -9.5239e-03 1.1850e-03 1.7685e-03 -6.0000e+00 4.9328e-03 4.4549e-04 -1.7428e-04 8.1602e-05 2.3712e-05 -6.0000e+00 3.9060e-04 3.3649e-03 -8.1632e-05 11 1 0 11 8 0 -27.19 20.38 0.47 0.00336 0.00206 14 3 1 5 0 3553.290 25.47 20.01 20.38 13.04 19.0 674.32 -1427 606 1819 -4379 -4299 -1638 3637 -53 -3581 590 3571 2878 749 -3053 1583 -1024 -278 -732 445 -563 -1990 1583 834 363 -609 1726 1146 -1437 71 445 766 2677 906 -564 -1804 1216 -159 -2473 -205 -887 -3990 -833 -220 -579 -992 -1358 -552 -983 -143 495 1285 1422 1408 1260 674 622 1105 80 275 1286 1308 1307 810 763 -134 -936 55 467 1494 860 774 -592 -76 452 136 203 169 82 -95 -246 -825 -628 -1532 -1577 -432 -723 -196 -216 -493 -105 -170 -292 687 874 1233 606 677 251 -47 -703 -236 -427 178 574 -757 -769 -296 -425 -315 181 -66 -60 -385 -138 471 679 905 516 -16 -165 -708 -183 253 324 236 561 706 951 1085 251 91 -462 -152 -30 4 -244 -255 239 -198 -216 41 -122 -303 -127 57 172 -418 -380 -138 307 -5 -389 65 393 330 97 -469 262 -189 -54 -148 93 -122 -446 345 188 86 -154 439 291 -358 17 103 186 685 249 -161 -507 335 -47 -861 -82 -405 -2041 -436 -118 -315 -541 -740 -294 -520 -74 258 694 808 848 790 440 416 747 54 185 853 892 937 621 617 -109 -733 41 340 1118 707 685 -551 -71 409 117 161 125 57 -69 -195 -718 -595 -1558 -1680 -480 -848 -238 -269 -617 -128 -196 -316 690 856 1247 658 796 319 -63 -945 -304 -524 209 675 -937 -1000 -398 -594 -459 275 -105 -96 -608 -206 664 918 1199 706 -23 -248 -1088 -279 379 472 331 754 917 1239 1461 356 135 -708 -238 -48 7 -421 -449 429 -359 -386 70 -208 -504 SS 20240711T175919.3Z 8958.749529 87 1 51.33 2 62.38 74.78 129.02 69.94 0.00 1 0.00 1 0 17 1.188e-02 5.791e-03 8.043e-03 2.359e-03 2.624481e-01 1.235510e-03 2.819611e-03 -6.000000e+00 7.162711e-03 225.81 -2.00 3.11 -2.00 317.51 0.00e+00 6.735248e-04 1.835479e-04 5.578704e-05 -6.000000e+00 3.066702e-04 272.08 -2.00 20.00 -2.00 316.97 0.00e+00 2.147 0.000 302.00 328.00 3 5.3468e+00 3.2515e-03 1.7754e-02 -6.0000e+00 1.7754e-02 -1.0435e-02 3.6489e-03 1.1869e-02 -6.0000e+00 1.9279e-02 4.1664e-03 2.2241e-03 5.9178e-03 -6.0000e+00 1.1436e-02 -6.1698e-03 1.0919e-03 1.7737e-03 -6.0000e+00 4.7718e-03 4.8367e-04 -2.9268e-04 7.7246e-05 2.3431e-05 -6.0000e+00 3.7793e-04 2.9019e-03 -1.2662e-04 10 0 0 10 0 0 -152.00 20.40 0.30 0.00290 0.00070 15 3 1 5 0 3421.500 25.47 19.99 20.40 13.18 19.0 674.64 -574 -4101 -572 -6557 2861 1603 -1226 1187 -4423 830 -2376 -3286 80 -1146 150 156 -1070 1506 804 -727 860 1803 1354 1452 262 276 -645 -1055 1419 727 749 -1055 1720 -638 -2128 -2181 -1632 -674 -320 -837 1220 -1447 -420 -1490 -783 12 -554 -628 176 437 -394 1528 329 1228 489 1238 484 -43 343 288 1479 930 1373 853 -445 -278 -483 544 878 875 1267 -8 -365 -399 69 -357 -300 -117 350 463 -570 -791 -1425 -1354 -595 -1149 -524 -49 -64 161 -39 109 635 1138 1046 574 480 378 -239 -368 -454 -480 231 461 -828 -969 -596 -553 -246 325 -175 69 -69 107 41 434 826 769 266 -523 -452 -354 174 326 252 609 919 933 1233 192 -174 -343 121 274 -231 -379 -228 84 -272 -193 21 58 -386 -56 -451 -62 -721 264 145 -119 124 -533 99 -299 -437 11 -188 27 31 -226 324 181 -171 202 422 325 364 70 75 -176 -277 346 179 190 -293 495 -192 -631 -645 -518 -241 -133 -396 621 -788 -233 -846 -442 7 -305 -339 94 235 -223 892 206 789 327 841 335 -30 234 197 1028 683 1080 702 -372 -223 -363 400 668 725 1125 -7 -343 -367 60 -286 -224 -83 255 366 -497 -752 -1449 -1440 -660 -1353 -639 -61 -81 195 -46 118 644 1109 1056 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