File name: Pandora56s1_MaunaLoaHI_20240720_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T232624.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20240720_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20240720 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240720T195440.9Z 8967.829640 319 1 50.35 2 36.16 81.73 151.18 249.82 0.00 1 0.00 1 0 17 7.831e-03 5.961e-03 3.105e-03 1.899e-03 1.555022e-01 1.007756e-03 1.705207e-03 -6.000000e+00 4.721543e-03 225.68 -2.00 3.11 -2.00 315.44 0.00e+00 7.960922e-05 9.232706e-05 1.950989e-05 -6.000000e+00 2.021491e-04 272.05 -2.00 20.00 -2.00 314.97 0.00e+00 1.238 0.000 302.00 328.00 3 5.8236e+00 2.5859e-03 1.0361e-02 -6.0000e+00 1.1700e-02 -7.6787e-03 2.8751e-03 6.9995e-03 -6.0000e+00 1.2704e-02 2.7571e-03 1.6456e-03 3.4907e-03 -6.0000e+00 7.5366e-03 -3.0193e-03 7.2484e-04 9.9406e-04 -6.0000e+00 3.1467e-03 6.3923e-04 -4.9568e-05 6.1413e-05 1.5251e-05 -6.0000e+00 2.4909e-04 -4.6132e-03 0.0000e+00 11 1 0 11 8 0 90.62 21.10 0.44 -0.00461 -0.00499 14 3 1 5 0 3595.930 26.00 20.00 21.10 21.64 19.6 714.08 198 -2755 -1427 -2990 -1629 -86 526 638 -41 -510 53 178 1398 -535 909 469 -390 -323 67 1755 691 596 499 840 1232 172 130 -1555 740 571 1015 975 707 316 -1893 -523 -1228 -211 211 -991 -1106 -1075 -396 -800 -762 -350 -572 -460 -305 343 615 230 1545 1181 973 605 634 -59 167 933 997 1191 844 833 138 -855 -641 -33 1071 502 458 -152 -69 83 -250 137 139 468 442 -538 -651 -1180 -1230 -1554 -591 -1045 -779 -56 -58 -153 -349 319 277 640 1232 612 583 290 -8 -20 -592 -566 166 355 -402 -862 -624 -558 -173 413 207 -186 -227 112 183 646 325 732 42 -104 -523 75 299 157 480 732 491 964 1125 569 49 -487 161 113 -265 -225 -316 89 57 -388 255 -573 -534 55 -835 -426 -861 -422 -21 133 173 -12 -157 16 55 456 -193 354 196 -167 -141 30 783 315 272 231 400 606 87 65 -748 330 245 440 440 334 151 -889 -240 -605 -116 131 -701 -842 -843 -316 -644 -610 -280 -445 -345 -224 247 454 176 1221 974 813 515 545 -51 142 788 864 1073 812 821 136 -802 -561 -28 928 472 456 -159 -72 86 -245 125 117 373 355 -466 -605 -1187 -1305 -1720 -680 -1274 -988 -72 -74 -194 -419 357 291 645 1254 656 674 357 -10 -26 -734 -667 189 408 -488 -1105 -825 -759 -241 592 305 -276 -329 155 239 793 391 904 55 -141 -741 107 414 213 623 912 593 1153 1369 721 64 -650 218 157 -381 -337 -482 138 88 -600 386 -850 -787 SS 20240720T200015.3Z 8967.833511 322 1 51.83 2 34.86 81.93 152.35 249.48 0.00 1 0.00 1 0 17 7.928e-03 6.002e-03 3.010e-03 1.849e-03 1.508707e-01 9.817058e-04 1.643814e-03 -6.000000e+00 4.780208e-03 225.68 -2.00 3.11 -2.00 315.42 0.00e+00 2.892943e-04 8.950605e-05 2.626697e-05 -6.000000e+00 2.046611e-04 272.05 -2.00 20.00 -2.00 314.94 0.00e+00 1.218 0.000 302.00 328.00 3 5.8026e+00 2.5188e-03 1.0108e-02 -6.0000e+00 1.1845e-02 -1.3160e-02 2.8007e-03 6.7686e-03 -6.0000e+00 1.2862e-02 5.9935e-03 1.6026e-03 3.3692e-03 -6.0000e+00 7.6303e-03 -5.3551e-03 7.0437e-04 9.7177e-04 -6.0000e+00 3.1858e-03 6.6751e-04 3.4786e-05 5.9818e-05 1.4585e-05 -6.0000e+00 2.5219e-04 -4.6004e-03 0.0000e+00 10 0 0 10 0 0 96.28 21.10 0.38 -0.00460 -0.00434 15 3 1 5 0 3455.070 26.00 20.01 21.10 21.88 19.6 715.15 -487 -1173 -2374 -1386 -2173 1313 418 1030 1520 -1665 1202 -324 250 32 176 405 -1350 375 -72 1127 548 51 1262 817 939 -28 -481 -1008 252 1425 708 1327 646 -206 -2278 -1458 372 -582 62 -921 -346 -1114 -1115 -576 -1082 -272 -820 -153 -25 56 1237 386 1121 1114 953 740 51 61 266 1548 1150 1709 547 285 162 -903 148 -181 801 938 767 78 -389 330 -153 376 80 162 688 -612 -403 -1235 -1229 -1295 -944 -707 -872 -205 -553 152 -188 146 271 751 708 246 539 353 -267 -285 -847 -304 -76 263 -361 -809 -308 -978 -6 -159 307 -30 -28 459 -150 490 668 760 365 162 -163 9 106 141 482 636 766 1079 961 682 -210 -211 132 97 -42 -336 -233 -252 -155 -171 -4 -341 -588 -139 -353 -720 -395 -576 320 106 282 443 -518 368 -102 83 12 69 169 -586 165 -32 508 251 24 581 390 464 -14 -242 -488 113 615 311 604 304 -98 -1071 -680 180 -321 39 -654 -262 -879 -901 -466 -875 -215 -643 -115 -18 41 909 296 893 911 800 632 44 52 227 1304 999 1543 525 281 160 -851 128 -154 696 870 765 81 -410 339 -150 339 67 129 549 -529 -374 -1246 -1309 -1422 -1086 -856 -1105 -264 -718 192 -225 164 282 755 716 265 619 433 -342 -364 -1049 -359 -87 304 -437 -1033 -405 -1338 -8 -230 453 -45 -40 632 -195 605 806 942 471 221 -230 13 147 191 624 789 925 1278 1176 868 -275 -284 178 134 -60 -497 -353 -391 -243 -264 -6 -506 -869 SS 20240720T201017.7Z 8967.840483 325 1 50.46 2 32.52 82.29 154.44 248.74 0.00 1 0.00 1 0 17 7.424e-03 5.548e-03 2.741e-03 1.725e-03 1.489831e-01 9.159212e-04 1.629407e-03 -6.000000e+00 4.476127e-03 225.68 -2.00 3.11 -2.00 315.31 0.00e+00 2.272740e-04 8.189902e-05 1.576952e-05 -6.000000e+00 1.916358e-04 272.05 -2.00 20.00 -2.00 314.85 0.00e+00 1.185 0.000 302.00 328.00 3 5.6808e+00 2.3475e-03 9.9165e-03 -6.0000e+00 1.1092e-02 -9.0658e-03 2.6084e-03 6.6984e-03 -6.0000e+00 1.2044e-02 1.5970e-03 1.4924e-03 3.3374e-03 -6.0000e+00 7.1448e-03 -2.9041e-03 6.5421e-04 9.6101e-04 -6.0000e+00 2.9832e-03 7.7235e-04 -1.7988e-04 5.5834e-05 1.4631e-05 -6.0000e+00 2.3613e-04 -4.8865e-03 0.0000e+00 11 1 0 11 8 0 52.55 21.13 0.29 -0.00489 -0.00624 16 3 1 5 0 3153.130 26.00 20.02 21.13 22.71 19.5 718.85 -11 -1295 -1964 -2236 -1225 -454 525 1722 216 317 -718 725 1174 1051 643 -152 -462 -195 669 476 774 1240 208 565 413 -214 -759 -684 795 990 1151 1775 883 -1081 -2530 -825 -702 129 -629 -660 -1161 -1188 -486 -913 -621 -442 -972 -310 -204 126 992 846 1139 893 474 1008 690 431 377 518 1162 1090 812 651 -249 -383 -437 -97 924 672 380 113 166 -20 7 -151 451 219 260 78 -853 -1347 -1372 -1290 -843 -692 -266 -89 -345 -331 -189 24 517 606 707 672 454 273 -18 -334 -268 -370 298 369 -439 -558 -518 -480 -398 107 89 -19 -3 187 -108 412 504 647 240 -104 -356 -143 -49 205 378 858 976 786 904 329 53 -386 -135 192 -429 -65 -58 346 -274 -307 -28 -439 -332 -3 -406 -618 -670 -336 -118 139 488 66 100 -229 231 397 391 260 -66 -207 -89 304 221 363 578 99 276 210 -111 -391 -338 362 439 515 821 422 -531 -1214 -390 -349 71 -404 -471 -893 -956 -392 -743 -508 -357 -767 -237 -150 92 743 655 908 741 404 868 602 376 325 446 1021 998 782 643 -248 -361 -386 -83 798 628 381 118 174 -20 7 -138 382 174 208 67 -798 -1346 -1463 -1431 -977 -833 -332 -115 -449 -417 -228 27 538 605 715 719 519 336 -24 -429 -332 -435 337 424 -535 -704 -676 -654 -557 154 131 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