File name: Pandora56s1_MaunaLoaHI_20240805_L2Fit_fout2c0d20200803p1-8.txt File generation date: 20240806T103618.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c0p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v7d20200803.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20240805_L1_smca1c0d20200803p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20240805 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0619 305.2024 305.3429 305.4835 305.6240 305.7645 305.9049 306.0454 306.1859 306.3263 306.4668 306.6072 306.7476 306.8880 307.0284 307.1688 307.3092 307.4496 307.5899 307.7303 307.8706 308.0109 308.1512 308.2916 308.4318 308.5721 308.7124 308.8527 308.9929 309.1331 309.2734 309.4136 309.5538 309.6940 309.8342 309.9744 310.1145 310.2547 310.3948 310.5350 310.6751 310.8152 310.9553 311.0954 311.2354 311.3755 311.5156 311.6556 311.7956 311.9357 312.0757 312.2157 312.3557 312.4957 312.6356 312.7756 312.9155 313.0555 313.1954 313.3353 313.4752 313.6151 313.7550 313.8949 314.0347 314.1746 314.3144 314.4542 314.5941 314.7339 314.8737 315.0134 315.1532 315.2930 315.4327 315.5725 315.7122 315.8519 315.9916 316.1313 316.2710 316.4107 316.5503 316.6900 316.8296 316.9692 317.1089 317.2485 317.3881 317.5277 317.6672 317.8068 317.9463 318.0859 318.2254 318.3649 318.5044 318.6439 318.7834 318.9229 319.0624 319.2018 319.3412 319.4807 319.6201 319.7595 319.8989 320.0383 320.1777 320.3170 320.4564 320.5957 320.7350 320.8744 321.0137 321.1530 321.2922 321.4315 321.5708 321.7100 321.8493 321.9885 322.1277 322.2669 322.4061 322.5453 322.6845 322.8236 322.9628 323.1019 323.2410 323.3801 323.5193 323.6583 323.7974 323.9365 324.0756 324.2146 324.3536 324.4927 324.6317 324.7707 324.9097 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240805T174652.4Z 8983.740884 218 1 51.71 2 66.49 79.74 81.96 77.03 0.00 1 0.00 1 0 17 1.601e-02 5.366e-03 1.161e-02 2.790e-03 2.880625e-01 1.460482e-03 3.080134e-03 -6.000000e+00 9.643588e-03 225.58 -2.00 3.11 -2.00 317.88 0.00e+00 -2.367538e-04 2.399315e-04 2.169028e-04 -6.000000e+00 4.132769e-04 272.07 -2.00 20.00 -2.00 317.34 0.00e+00 2.489 0.000 302.00 328.00 3 5.4110e+00 3.8679e-03 2.0060e-02 -6.0000e+00 2.3890e-02 -3.3734e-03 4.3538e-03 1.3035e-02 -6.0000e+00 2.5949e-02 5.6917e-04 2.7358e-03 6.4858e-03 -6.0000e+00 1.5395e-02 -6.3585e-03 1.3723e-03 1.8765e-03 -6.0000e+00 6.4252e-03 3.5615e-04 -4.4704e-04 9.1474e-05 2.4894e-05 -6.0000e+00 5.0938e-04 4.4138e-03 -1.2522e-04 11 1 0 11 8 0 99.36 20.67 0.42 0.00441 0.00105 13 3 1 5 0 3977.560 25.68 20.02 20.67 18.18 19.5 697.13 -6567 -1789 5088 1920 5945 -3099 -8791 4666 -1831 4117 -1663 3433 -1538 -1596 779 -1538 -1002 -1805 210 1855 -796 -626 347 807 48 1145 -974 -697 1179 -803 1207 233 395 -2048 -1388 -975 -2047 -629 -259 -674 -4533 167 -693 -771 783 358 -1039 -950 884 58 457 970 1170 1638 555 1121 1182 318 593 818 768 1002 1730 1033 700 -352 -931 300 520 807 539 547 -139 -90 -292 71 -236 -322 -147 -224 -343 -1215 -1310 -1517 -866 -951 -318 249 -95 -401 -237 -22 305 328 436 267 633 284 143 -611 68 -674 -264 213 -550 -681 -362 -76 66 357 86 391 171 334 422 -200 522 506 -278 250 -380 54 321 78 -76 -10 352 851 663 115 -223 -631 40 -72 -147 -25 -267 535 -169 -197 1 -211 -101 -536 -151 412 153 421 -234 -739 380 -175 390 -171 353 -185 -219 117 -259 -178 -338 40 359 -161 -128 72 175 11 270 -233 -159 251 -173 267 56 102 -553 -363 -254 -583 -201 -97 -288 -2214 82 -350 -399 399 182 -529 -474 429 29 236 532 673 986 350 721 762 207 384 526 508 695 1269 806 550 -266 -675 211 384 648 467 497 -126 -80 -245 55 -169 -223 -104 -173 -292 -1140 -1310 -1592 -949 -1101 -381 306 -118 -482 -272 -23 303 320 436 289 748 362 192 -825 87 -824 -309 250 -682 -886 -488 -106 95 544 136 626 271 504 603 -274 705 695 -403 377 -587 83 486 115 -108 -13 465 1115 902 166 -334 -986 64 -116 -248 -45 -480 974 -313 -357 1 -365 -170 SS 20240805T175818.5Z 8983.748825 223 1 17.63 2 63.83 80.48 79.41 77.89 0.00 1 0.00 1 0 17 1.034e-02 5.994e-03 6.400e-03 2.386e-03 2.586836e-01 1.253048e-03 2.774359e-03 -6.000000e+00 6.238941e-03 225.58 -2.00 3.11 -2.00 316.89 0.00e+00 5.617130e-04 1.604009e-04 1.453207e-04 -6.000000e+00 2.669991e-04 272.07 -2.00 20.00 -2.00 316.37 0.00e+00 2.255 0.000 302.00 328.00 3 4.6670e+00 3.2660e-03 1.8054e-02 -6.0000e+00 1.5457e-02 -2.7307e-02 3.6525e-03 1.1586e-02 -6.0000e+00 1.6780e-02 -1.4097e-03 2.1621e-03 5.7769e-03 -6.0000e+00 9.9555e-03 -2.7658e-03 1.0319e-03 1.6871e-03 -6.0000e+00 4.1618e-03 9.1295e-04 1.3102e-04 7.7207e-05 2.2526e-05 -6.0000e+00 3.2893e-04 -1.7959e-03 6.3640e-05 12 1 1 12 1 1 99.20 20.74 0.36 -0.00180 -0.00081 8 5 1 5 0 1958.470 25.79 20.00 20.74 18.67 19.5 699.70 -2121 -2665 -1909 -4835 42 -2488 -2126 600 -1309 693 -3112 16 1545 -844 1585 -715 -30 645 656 910 48 493 1838 974 1409 190 -728 -848 588 -1745 1269 872 951 -1133 -2744 -1863 -1540 -806 328 -773 -533 -977 -236 -1083 -203 -740 24 -945 -53 92 -30 1704 1069 1566 884 1010 760 184 -37 389 772 963 1277 1557 1026 -206 -428 -692 487 843 332 452 760 421 -96 285 -1514 -786 -496 -932 -1329 -735 -1539 -1892 -417 -710 -215 486 -184 221 -170 -153 -840 -601 -397 715 871 408 143 68 -199 -968 -825 -152 -325 -443 -527 -146 -70 378 701 628 505 390 218 -272 113 299 280 12 -238 58 438 134 231 618 100 527 559 9 294 -392 -328 -211 -633 -286 -270 197 374 285 206 -423 -591 -277 -381 -275 -684 5 -311 -276 83 -198 108 -513 3 279 -174 360 -178 -8 175 185 258 14 144 540 301 455 64 -246 -275 178 -544 399 290 336 -411 -987 -672 -583 -341 156 -422 -314 -600 -148 -684 -129 -472 15 -582 -32 56 -19 1103 738 1111 643 751 574 140 -28 290 590 768 1075 1358 904 -174 -352 -556 403 743 311 438 740 405 -89 246 -1230 -611 -394 -791 -1226 -722 -1616 -2052 -467 -841 -260 604 -228 269 -201 -170 -892 -621 -416 795 1026 517 187 89 -255 -1194 -978 -180 -403 -569 -703 -202 -99 556 1052 962 757 566 301 -364 149 400 391 18 -353 86 640 191 318 828 131 681 742 13 423 -575 -493 -323 -998 -462 -446 332 626 476 338 -683 -944 SS 20240805T180248.8Z 8983.751953 226 1 49.72 2 62.78 80.77 78.40 78.22 0.00 1 0.00 1 0 17 8.615e-03 5.685e-03 3.401e-03 1.168e-03 2.493881e-01 6.112833e-04 2.669174e-03 -6.000000e+00 5.197854e-03 225.58 -2.00 3.11 -2.00 317.20 0.00e+00 5.134904e-04 8.393554e-05 2.008204e-04 -6.000000e+00 2.223373e-04 272.07 -2.00 20.00 -2.00 316.68 0.00e+00 2.176 0.000 302.00 328.00 3 4.1852e+00 1.6024e-03 1.7410e-02 -6.0000e+00 1.2878e-02 -3.0981e-02 1.7963e-03 1.1164e-02 -6.0000e+00 1.3978e-02 -1.6374e-03 1.0747e-03 5.5766e-03 -6.0000e+00 8.2933e-03 -2.7180e-03 5.1773e-04 1.6245e-03 -6.0000e+00 3.4686e-03 1.5781e-03 4.2957e-05 3.8058e-05 2.1495e-05 -6.0000e+00 2.7393e-04 -4.0647e-03 1.0109e-04 10 0 0 10 0 0 99.82 20.78 0.35 -0.00406 -0.00374 43 8 1 5 0 1156.250 25.79 20.00 20.78 18.91 19.5 700.67 1367 -1595 -1150 -494 -3211 -1189 -103 1008 408 -486 -1367 -1451 -674 -756 7 318 -708 801 -105 989 775 655 913 425 332 538 106 -1467 -259 -333 549 -64 363 -1080 -3307 -2497 -2264 -1248 -280 -662 -720 -947 -474 -626 -356 145 -324 72 -182 24 1013 683 1226 1445 1065 873 889 329 199 563 967 1519 1345 1366 814 -511 -531 -841 403 1029 713 532 438 388 80 -214 -809 -1106 -1075 -997 -1053 -1173 -1475 -1676 -804 -731 -119 356 82 181 -234 -264 -1003 -763 97 148 769 488 421 -1 -240 -627 -868 41 -561 -655 -475 -252 82 548 836 613 582 439 -50 -40 -57 421 3 134 -48 75 116 194 382 210 161 209 432 191 80 -507 -626 -421 -397 -117 50 274 256 51 245 -173 -511 164 -214 -156 -63 -391 -136 -12 128 57 -72 -208 -229 -116 -147 1 69 -164 190 -26 249 199 170 240 117 96 160 31 -424 -70 -88 150 -19 113 -349 -1065 -790 -764 -478 -125 -342 -410 -572 -269 -361 -205 90 -199 43 -108 14 616 442 765 945 723 607 627 233 139 392 689 1142 1088 1166 702 -425 -413 -638 314 876 664 523 435 374 73 -178 -616 -800 -793 -803 -948 -1165 -1460 -1760 -890 -863 -147 454 105 226 -276 -286 -1010 -796 104 157 899 629 535 -2 -317 -777 -1023 48 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