File name: Pandora56s1_MaunaLoaHI_20241112_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250131T235100.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20241112_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20241112 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241112T194245.5Z 9082.821360 225 1 50.62 2 51.49 134.43 156.92 12.92 0.00 1 0.00 1 0 17 8.416e-03 5.818e-03 4.036e-03 1.926e-03 1.877474e-01 1.008368e-03 2.043833e-03 -6.000000e+00 5.044345e-03 223.95 -2.00 3.11 -2.00 316.35 0.00e+00 3.380793e-04 1.119642e-04 1.238032e-04 -6.000000e+00 2.156677e-04 270.26 -2.00 20.00 -2.00 315.87 0.00e+00 1.603 0.000 302.00 328.00 3 5.5547e+00 2.6028e-03 1.2881e-02 -6.0000e+00 1.2459e-02 -3.8041e-02 2.9072e-03 8.3403e-03 -6.0000e+00 1.3545e-02 3.6350e-03 1.6861e-03 4.1795e-03 -6.0000e+00 8.0375e-03 -3.1400e-03 7.7630e-04 1.2081e-03 -6.0000e+00 3.3657e-03 6.3633e-04 -5.6606e-04 6.2783e-05 1.7208e-05 -6.0000e+00 2.6747e-04 -1.0620e-02 0.0000e+00 10 0 0 10 0 0 99.23 20.86 0.54 -0.01062 -0.01487 17 3 1 5 0 2977.600 25.79 20.01 20.86 18.60 19.8 696.75 779 -1598 -1389 -2438 -2703 -287 397 1129 1560 -608 -1251 -1440 359 -414 285 -477 -641 256 1305 501 871 1202 954 923 457 -199 67 -962 -256 323 758 205 418 -72 -3063 -1786 -1436 -1738 475 -780 -443 -637 -427 -831 -405 -367 -326 -148 -596 569 916 331 1364 1473 867 637 1180 -11 58 527 620 1815 1044 974 620 -346 -636 -916 586 927 671 317 565 476 98 -123 -632 -1377 -1455 -1252 -1033 -1535 -1287 -1094 -571 -452 66 486 247 -23 -368 -242 -817 -648 -492 -116 468 542 462 17 -142 -581 -860 -139 -477 -548 -416 -291 1 840 714 660 473 523 45 -236 -187 -65 180 181 -145 178 585 222 243 439 -154 246 451 391 -205 -416 -400 -198 -378 -191 -253 367 275 52 315 -274 -685 146 -329 -287 -492 -500 -49 70 215 322 -134 -279 -328 86 -112 83 -151 -212 86 447 177 312 429 346 347 180 -81 27 -371 -92 112 267 76 163 -29 -1217 -691 -590 -801 251 -470 -286 -433 -298 -587 -284 -255 -222 -97 -391 366 605 227 973 1095 668 501 933 -9 46 414 499 1497 927 888 566 -306 -534 -742 483 817 635 317 569 467 92 -108 -508 -1067 -1139 -1040 -931 -1495 -1341 -1180 -652 -540 81 619 317 -29 -442 -271 -858 -658 -507 -126 545 676 600 22 -178 -697 -1003 -163 -583 -700 -558 -401 1 1232 1074 1007 715 755 62 -306 -236 -84 242 255 -214 262 845 311 329 573 -193 308 572 522 -284 -595 -573 -292 -574 -299 -411 608 453 86 509 -431 -1078 SS 20241112T194849.7Z 9082.825575 229 1 50.32 2 50.48 135.76 156.55 16.44 0.00 1 0.00 1 0 17 8.792e-03 6.282e-03 2.853e-03 1.450e-03 1.852178e-01 7.603822e-04 2.036132e-03 -6.000000e+00 5.270675e-03 223.95 -2.00 3.11 -2.00 316.14 0.00e+00 5.059385e-04 8.068933e-05 1.360913e-04 -6.000000e+00 2.252885e-04 270.26 -2.00 20.00 -2.00 315.67 0.00e+00 1.569 0.000 302.00 328.00 3 5.1837e+00 1.9576e-03 1.2664e-02 -6.0000e+00 1.3018e-02 -4.2747e-02 2.1830e-03 8.2508e-03 -6.0000e+00 1.4152e-02 -8.2703e-04 1.2619e-03 4.1346e-03 -6.0000e+00 8.3976e-03 -2.9293e-05 5.7681e-04 1.2025e-03 -6.0000e+00 3.5175e-03 9.4776e-04 -8.7142e-04 4.7075e-05 1.7337e-05 -6.0000e+00 2.7941e-04 -1.2372e-02 0.0000e+00 11 1 0 11 8 0 99.64 20.89 0.33 -0.01237 -0.01892 24 5 1 5 0 2096.210 25.90 20.01 20.89 18.73 20.0 697.89 474 -2059 -974 -1619 -1356 1552 -1874 1058 932 -488 -1470 -749 -751 883 720 325 393 39 880 641 913 602 1407 1194 834 973 -1046 -1091 -528 101 580 478 -214 -1378 -3379 -2552 -1771 -1444 -940 -745 -660 -551 -382 -539 -325 -264 -171 -444 -34 -118 569 942 1319 1389 1138 1076 1000 390 192 166 786 1271 1582 1357 683 -281 -644 -538 495 870 825 599 240 356 311 -621 -694 -1227 -1611 -1148 -875 -1379 -1382 -1262 -736 -569 14 408 123 68 -386 -636 -793 -1052 -455 -70 652 757 446 44 -299 -806 -697 -208 -265 -610 -401 -200 60 694 939 847 742 480 199 1 -287 167 160 -61 -115 183 264 301 471 299 52 246 355 180 -142 -674 -588 -364 -514 -179 -185 440 220 67 339 -176 -535 98 -467 -221 -353 -270 287 -369 217 209 -116 -354 -182 -197 250 224 110 137 14 322 241 347 230 538 473 345 408 -444 -446 -204 37 218 189 -89 -586 -1421 -1059 -767 -703 -517 -461 -444 -386 -274 -391 -235 -189 -121 -306 -23 -79 387 666 967 1062 890 857 807 316 154 133 643 1083 1409 1258 637 -252 -546 -442 414 780 792 602 243 354 297 -556 -575 -966 -1283 -975 -806 -1363 -1439 -1375 -833 -675 17 518 156 86 -466 -719 -843 -1073 -469 -76 757 935 576 57 -378 -972 -813 -244 -323 -782 -530 -273 85 1008 1408 1278 1099 686 268 2 -362 215 214 -86 -166 266 379 421 635 390 65 306 452 238 -196 -946 -841 -530 -773 -277 -295 710 360 109 538 -275 -827 SS 20241112T195418.2Z 9082.829377 232 1 49.56 2 49.59 137.00 156.15 19.52 0.00 1 0.00 1 0 17 8.318e-03 6.478e-03 2.574e-03 1.334e-03 1.830728e-01 6.973669e-04 2.005704e-03 -6.000000e+00 4.986936e-03 223.95 -2.00 3.11 -2.00 316.10 0.00e+00 3.350419e-04 7.346427e-05 1.308821e-04 -6.000000e+00 2.131470e-04 270.26 -2.00 20.00 -2.00 315.62 0.00e+00 1.540 0.000 302.00 328.00 3 5.0580e+00 1.7951e-03 1.2461e-02 -6.0000e+00 1.2318e-02 -4.5027e-02 2.0051e-03 8.1389e-03 -6.0000e+00 1.3390e-02 -2.7306e-03 1.1570e-03 4.0751e-03 -6.0000e+00 7.9454e-03 6.9294e-04 5.2574e-04 1.1709e-03 -6.0000e+00 3.3283e-03 1.1006e-03 -8.8282e-04 4.3133e-05 1.7136e-05 -6.0000e+00 2.6436e-04 -1.2778e-02 0.0000e+00 11 8 0 10 0 0 99.60 20.92 0.39 -0.01278 -0.01941 28 6 1 5 0 1769.910 25.90 20.01 20.92 18.86 19.9 698.38 -211 -908 -1078 -2100 -841 58 594 628 703 -508 -1487 130 -12 1017 647 -510 -378 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