File name: Pandora56s1_MaunaLoaHI_20241117_L2Fit_fwvt1c9d20210409p1-8.txt File generation date: 20250131T235606.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20241117_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20241117 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1715 1864 Nominal wavelengths inside fitting window [nm]: 492.1202 492.2407 492.3612 492.4817 492.6021 492.7225 492.8430 492.9634 493.0838 493.2041 493.3245 493.4448 493.5651 493.6854 493.8057 493.9260 494.0463 494.1665 494.2867 494.4069 494.5271 494.6473 494.7674 494.8876 495.0077 495.1278 495.2479 495.3679 495.4880 495.6080 495.7281 495.8481 495.9680 496.0880 496.2080 496.3279 496.4478 496.5677 496.6876 496.8075 496.9273 497.0472 497.1670 497.2868 497.4066 497.5263 497.6461 497.7658 497.8855 498.0052 498.1249 498.2446 498.3642 498.4839 498.6035 498.7231 498.8426 498.9622 499.0818 499.2013 499.3208 499.4403 499.5598 499.6792 499.7987 499.9181 500.0375 500.1569 500.2763 500.3957 500.5150 500.6343 500.7537 500.8730 500.9922 501.1115 501.2307 501.3500 501.4692 501.5884 501.7075 501.8267 501.9458 502.0650 502.1841 502.3032 502.4222 502.5413 502.6603 502.7794 502.8984 503.0174 503.1363 503.2553 503.3742 503.4932 503.6121 503.7310 503.8498 503.9687 504.0875 504.2063 504.3251 504.4439 504.5627 504.6815 504.8002 504.9189 505.0376 505.1563 505.2750 505.3936 505.5122 505.6309 505.7495 505.8680 505.9866 506.1052 506.2237 506.3422 506.4607 506.5792 506.6976 506.8161 506.9345 507.0529 507.1713 507.2897 507.4081 507.5264 507.6447 507.7630 507.8813 507.9996 508.1179 508.2361 508.3543 508.4725 508.5907 508.7089 508.8271 508.9452 509.0633 509.1814 509.2995 509.4176 509.5357 509.6537 509.7717 509.8897 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241117T165102.2Z 9087.702108 241 1 49.73 2 86.66 111.74 69.16 293.29 0.00 1 0.00 1 0 22 3.326e-03 3.304e-03 5.665e-04 5.659e-04 1.000527e+03 3.173820e+01 7.466620e+01 -6.000000e+00 1.819293e+02 270.14 -2.00 20.00 -2.00 505.31 0.00e+00 7.202505e-04 1.531455e-05 3.858885e-05 -6.000000e+00 9.171596e-05 270.14 -2.00 20.00 -2.00 500.64 0.00e+00 9.574488e-01 1.127168e-02 1.070739e-02 -6.000000e+00 6.753250e-02 223.77 -2.00 3.11 -2.00 502.21 0.00e+00 13.065 0.010 489.00 513.00 1 5.2924e+00 8.6156e-04 1.1506e-02 -6.0000e+00 5.1601e-03 -1.2082e-02 2.2064e-04 6.6015e-04 -6.0000e+00 1.3401e-03 2.9274e-03 7.3885e-03 6.2410e-05 1.9390e-05 -6.0000e+00 3.7447e-04 -1.1186e-03 -6.7003e-05 10 0 0 10 0 0 97.18 19.82 1.81 -0.00112 0.05013 27 5 1 4 0 1841.490 24.96 20.01 19.82 7.03 19.3 643.34 -618 -322 50 -69 423 613 505 616 353 327 2 -202 -538 -457 -478 -422 9 210 133 -91 160 117 151 377 370 262 325 -60 -577 -395 -256 -430 286 588 66 25 148 108 -226 -1 35 75 205 300 384 349 310 197 -96 -548 -589 -649 -862 -422 -240 -13 -102 10 41 237 401 404 267 377 115 9 -13 88 -378 -430 -102 -146 -188 56 24 -221 -285 -174 -431 -446 -424 -187 -544 -165 -94 -402 -70 -130 -128 -185 62 368 407 161 242 390 25 -221 -308 -676 -653 -675 -146 -29 -278 -204 -122 -249 -215 74 -65 187 212 283 447 504 647 555 484 369 276 20 256 421 149 286 168 79 348 226 -105 -57 -148 -314 -194 63 -90 -274 -74 -5 49 160 753 24 226 38 -178 -413 -510 -505 -583 -311 48 -68 429 611 509 621 354 325 2 -202 -534 -450 -473 -424 9 212 136 -95 166 122 157 394 387 273 336 -61 -574 -385 -248 -425 288 607 68 25 150 108 -233 -1 35 76 209 308 395 359 316 198 -98 -545 -573 -622 -830 -412 -240 -13 -103 10 42 240 407 411 273 382 115 9 -12 85 -374 -423 -100 -144 -182 55 24 -214 -281 -169 -417 -433 -414 -178 -525 -160 -92 -397 -69 -129 -127 -185 63 364 405 161 239 390 24 -214 -292 -637 -618 -653 -144 -28 -278 -204 -121 -244 -210 73 -65 189 217 285 452 512 659 564 488 378 280 20 257 424 151 290 170 80 352 229 -105 -57 -145 -306 -190 62 -88 -274 -75 -5 51 166 779 25 235 39 -181 -414 -505 -500 SQ 20241117T170130.7Z 9087.709383 244 1 50.52 2 84.38 112.68 71.34 293.78 0.00 1 0.00 1 0 22 2.981e-03 2.974e-03 4.309e-04 4.305e-04 7.115140e+02 2.380788e+01 5.106539e+01 -6.000000e+00 1.630901e+02 270.14 -2.00 20.00 -2.00 505.28 0.00e+00 5.043386e-04 1.163673e-05 2.884939e-05 -6.000000e+00 8.221624e-05 270.14 -2.00 20.00 -2.00 500.56 0.00e+00 6.620060e-01 8.580343e-03 7.996094e-03 -6.000000e+00 6.053482e-02 223.77 -2.00 3.11 -2.00 502.14 0.00e+00 9.094 0.003 489.00 513.00 1 5.1843e+00 6.5600e-04 7.9976e-03 -6.0000e+00 4.6255e-03 -9.3382e-03 1.6877e-04 4.6127e-04 -6.0000e+00 1.2012e-03 4.7213e-03 7.1170e-03 4.7423e-05 1.4153e-05 -6.0000e+00 3.3569e-04 1.1660e-03 -7.5614e-05 10 0 0 10 0 0 94.69 19.83 2.00 0.00117 0.05053 45 9 1 4 0 1122.540 25.07 20.01 19.83 7.66 19.2 645.73 -499 -149 140 -52 333 672 600 496 267 260 88 -211 -446 -311 -454 -399 23 225 59 -55 228 85 160 350 242 297 306 -163 -562 -286 -370 -364 173 432 -84 -25 163 97 -161 48 -12 22 109 248 314 339 340 201 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-285 103 -168 -256 20 -45 -31 135 785 94 125 88 -164 -383 -369 -338 SQ 20241117T171236.3Z 9087.717087 247 1 50.18 2 81.98 113.73 73.64 294.34 0.00 1 0.00 1 0 22 2.759e-03 2.753e-03 3.729e-04 3.724e-04 5.386785e+02 2.038879e+01 4.061963e+01 -6.000000e+00 1.509373e+02 270.14 -2.00 20.00 -2.00 505.27 0.00e+00 3.933248e-04 1.004697e-05 2.296997e-05 -6.000000e+00 7.608801e-05 270.14 -2.00 20.00 -2.00 500.52 0.00e+00 5.019694e-01 7.427076e-03 5.764516e-03 -6.000000e+00 5.602028e-02 223.77 -2.00 3.11 -2.00 502.11 0.00e+00 6.746 0.001 489.00 513.00 1 5.1093e+00 5.6766e-04 5.9319e-03 -6.0000e+00 4.2806e-03 -1.0061e-02 1.4650e-04 3.4091e-04 -6.0000e+00 1.1115e-03 6.3253e-03 7.0230e-03 4.0986e-05 1.1560e-05 -6.0000e+00 3.1067e-04 2.8727e-04 -6.5071e-05 10 0 0 10 0 0 96.47 19.85 2.13 0.00029 0.04900 63 12 1 4 0 796.420 25.07 19.98 19.85 8.04 19.3 647.64 -508 -163 45 -10 318 650 547 436 259 319 97 -254 -457 -248 -363 -333 96 223 0 -101 110 149 195 356 263 305 250 -66 -727 -291 -283 -360 210 467 -57 -8 228 64 -126 -10 12 7 135 232 246 307 284 180 -32 -503 -477 -692 -689 -324 -131 -68 -136 24 -66 103 278 252 212 218 218 -46 33 -12 -257 -283 -113 -161 -124 143 49 -294 -192 -171 -307 -273 -217 -290 -526 -93 -142 -236 -239 -76 -144 -220 14 223 373 85 314 327 -45 -210 -294 -404 -633 -550 -186 38 -258 -272 -73 -214 -72 132 -39 33 186 236 270 385 552 476 366 340 237 97 330 365 25 304 211 152 161 255 -48 3 3 -217 -153 65 -86 -247 -47 88 -4 130 230 191 96 61 -105 -290 -254 -349 -484 -159 45 -11 326 676 559 447 264 330 99 -257 -457 -246 -361 -335 98 227 0 -106 115 156 204 374 277 319 259 -68 -726 -292 -284 -366 211 483 -60 -8 238 66 -129 -11 12 7 137 238 253 314 288 185 -32 -496 -472 -677 -674 -312 -129 -69 -136 24 -67 103 279 254 214 219 217 -47 33 -12 -250 -274 -109 -157 -121 141 48 -289 -185 -163 -292 -260 -207 -280 -514 -92 -141 -229 -233 -75 -141 -217 14 224 378 87 315 323 -44 -206 -282 -385 -607 -537 -181 38 -261 -275 -73 -212 -71 131 -40 33 187 239 276 395 566 487 371 340 234 96 323 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