File name: Pandora56s1_MaunaLoaHI_20250513_L2Fit_fwvt1c9d20210409p1-8.txt
File generation date: 20250514T102525.6Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c9p1-8
Local principal investigator: Thomas Hanisco
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 56
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora56_OF_v5d20200131.txt
Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt
Level 1 file used: Pandora56s1_MaunaLoaHI_20250513_L1_smca1c9d20210409p1-8.txt
Full location name: Mauna Loa
Short location name: MaunaLoaHI
Country of location: USA
Location latitude [deg]: 19.4795
Location longitude [deg]: -155.6027
Location altitude [m]: 4169
Local noon date: 20250513
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1715 1864
Nominal wavelengths inside fitting window [nm]: 492.1202 492.2407 492.3612 492.4817 492.6021 492.7225 492.8430 492.9634 493.0838 493.2041 493.3245 493.4448 493.5651 493.6854 493.8057 493.9260 494.0463 494.1665 494.2867 494.4069 494.5271 494.6473 494.7674 494.8876 495.0077 495.1278 495.2479 495.3679 495.4880 495.6080 495.7281 495.8481 495.9680 496.0880 496.2080 496.3279 496.4478 496.5677 496.6876 496.8075 496.9273 497.0472 497.1670 497.2868 497.4066 497.5263 497.6461 497.7658 497.8855 498.0052 498.1249 498.2446 498.3642 498.4839 498.6035 498.7231 498.8426 498.9622 499.0818 499.2013 499.3208 499.4403 499.5598 499.6792 499.7987 499.9181 500.0375 500.1569 500.2763 500.3957 500.5150 500.6343 500.7537 500.8730 500.9922 501.1115 501.2307 501.3500 501.4692 501.5884 501.7075 501.8267 501.9458 502.0650 502.1841 502.3032 502.4222 502.5413 502.6603 502.7794 502.8984 503.0174 503.1363 503.2553 503.3742 503.4932 503.6121 503.7310 503.8498 503.9687 504.0875 504.2063 504.3251 504.4439 504.5627 504.6815 504.8002 504.9189 505.0376 505.1563 505.2750 505.3936 505.5122 505.6309 505.7495 505.8680 505.9866 506.1052 506.2237 506.3422 506.4607 506.5792 506.6976 506.8161 506.9345 507.0529 507.1713 507.2897 507.4081 507.5264 507.6447 507.7630 507.8813 507.9996 508.1179 508.2361 508.3543 508.4725 508.5907 508.7089 508.8271 508.9452 509.0633 509.1814 509.2995 509.4176 509.5357 509.6537 509.7717 509.8897
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250513T155457.0Z 9264.663160 196 1 50.99 2 89.24 70.56 85.77 240.65 0.00 1 0.00 1 0 22 4.887e-03 4.888e-03 8.947e-04 8.933e-04 2.698100e+03 5.281984e+01 2.139433e+02 -6.000000e+00 2.687509e+02 271.32 -2.00 20.00 -2.00 505.34 0.00e+00 1.228651e-03 2.430266e-05 6.278864e-05 -6.000000e+00 1.351372e-04 271.32 -2.00 20.00 -2.00 500.80 0.00e+00 1.314107e+00 1.769822e-02 2.014955e-02 -6.000000e+00 9.979978e-02 227.44 -2.00 3.11 -2.00 502.35 0.00e+00 19.900 0.035 489.00 513.00 1 5.4630e+00 1.3505e-03 1.7800e-02 -6.0000e+00 7.6222e-03 -3.0770e-02 3.4403e-04 1.0781e-03 -6.0000e+00 1.9860e-03 1.3140e-03 9.6720e-03 9.8089e-05 4.0371e-05 -6.0000e+00 5.5048e-04 8.3792e-02 -7.3699e-04 12 8 8 10 0 0 -25.83 20.16 2.28 0.08379 0.15088 14 3 1 4 0 3642.150 25.28 20.00 20.16 9.64 20.0 659.77 -891 -284 88 -20 309 943 763 877 29 156 129 -501 -463 -522 -405 -591 106 484 256 147 166 434 307 463 301 422 570 -209 -821 -436 -571 -388 232 581 102 -137 -41 28 -329 53 112 106 383 264 452 588 308 325 -242 -774 -840 -1014 -1010 -722 -144 -138 -101 373 112 451 448 542 329 595 226 18 75 -203 -301 -474 -237 -429 -275 -12 -121 -377 -666 -242 -488 -506 -451 -242 -634 -404 -122 -359 -127 -250 -254 -109 141 395 645 494 513 407 220 -324 -163 -1016 -1087 -994 -505 -106 -241 -85 -146 -516 -298 -57 -7 172 479 364 576 580 858 741 432 395 422 156 304 458 370 441 343 72 452 218 -142 -132 -183 -441 -376 -221 -244 -239 114 -197 25 -57 2409 16 41 196 -366 -476 -833 -662 -814 -265 82 -20 302 934 765 880 29 155 126 -488 -445 -500 -389 -578 105 472 255 147 168 437 311 471 307 429 573 -208 -800 -416 -546 -377 230 590 103 -138 -40 29 -335 54 114 105 385 268 461 598 311 323 -237 -770 -818 -976 -975 -708 -139 -137 -102 377 114 457 456 553 337 605 228 18 74 -199 -292 -456 -228 -415 -269 -12 -119 -370 -645 -231 -464 -482 -432 -233 -620 -398 -121 -359 -128 -251 -256 -107 139 394 648 496 510 398 218 -316 -156 -970 -1044 -975 -492 -105 -244 -86 -147 -519 -299 -58 -7 179 487 374 595 603 893 773 449 406 428 157 306 462 376 448 350 73 461 222 -144 -132 -182 -437 -374 -223 -251 -250 121 -205 26 -60 2502 17 44 207 -383 -490 -878 -697
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SQ 20250513T160145.2Z 9264.667885 204 1 50.10 2 87.72 71.11 87.13 241.24 0.00 1 0.00 1 0 22 3.535e-03 3.516e-03 5.324e-04 5.318e-04 1.686668e+03 3.063231e+01 1.273098e+02 -6.000000e+00 1.944534e+02 271.32 -2.00 20.00 -2.00 505.31 0.00e+00 9.006080e-04 1.442254e-05 4.746858e-05 -6.000000e+00 9.775020e-05 271.32 -2.00 20.00 -2.00 500.68 0.00e+00 1.164173e+00 1.059471e-02 1.519655e-02 -6.000000e+00 7.214163e-02 227.44 -2.00 3.11 -2.00 502.24 0.00e+00 15.762 0.017 489.00 513.00 1 4.8848e+00 8.0855e-04 1.3956e-02 -6.0000e+00 5.5110e-03 -1.6474e-02 2.0745e-04 8.2706e-04 -6.0000e+00 1.4339e-03 3.4120e-03 8.6237e-03 5.8378e-05 2.6430e-05 -6.0000e+00 3.9821e-04 3.1681e-02 -3.4217e-04 10 0 0 10 0 0 13.01 20.16 1.83 0.03168 0.09150 32 6 1 4 0 1565.410 25.28 20.01 20.16 9.67 20.1 660.90 -789 -158 114 -58 322 638 684 455 305 262 98 -307 -469 -400 -473 -361 28 285 156 14 199 54 269 439 373 428 401 -172 -774 -385 -468 -469 223 521 130 -59 194 129 -206 -40 139 101 226 330 362 422 400 187 -31 -525 -593 -808 -854 -422 -192 30 -58 131 -12 161 361 381 246 297 236 -52 105 -73 -416 -321 -264 -199 -184 86 -4 -332 -415 -370 -385 -291 -367 -341 -662 -175 -147 -322 -207 -60 -122 -201 139 348 457 197 270 394 -13 -195 -342 -591 -841 -693 -306 -51 -185 -337 -113 -436 -182 33 57 165 270 447 351 597 748 636 542 505 355 26 199 352 195 298 243 211 285 335 -48 -111 -100 -441 -208 39 -105 -247 -116 -10 -26 235 387 93 244 99 -67 -453 -447 -513 -743 -152 110 -57 325 635 687 460 306 259 96 -307 -464 -394 -469 -351 28 288 160 14 200 55 272 446 380 434 402 -175 -774 -377 -458 -466 226 525 133 -61 197 130 -207 -40 140 102 232 342 376 438 412 189 -31 -512 -582 -784 -831 -417 -188 30 -59 134 -12 165 371 381 247 297 241 -53 104 -72 -406 -310 -254 -193 -180 84 -4 -326 -402 -355 -367 -278 -352 -330 -649 -172 -146 -323 -202 -59 -119 -198 138 350 462 200 270 387 -12 -191 -328 -563 -808 -678 -298 -51 -188 -342 -114 -436 -182 33 58 165 274 458 362 618 776 659 558 513 357 26 198 353 196 301 245 213 287 336 -48 -109 -98 -430 -203 39 -105 -254 -118 -10 -26 243 403 97 254 103 -68 -455 -444 -509
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