File name: Pandora56s1_MaunaLoaHI_20250519_L2Fit_fwvt1c9d20210409p1-8.txt
File generation date: 20250520T102800.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c9p1-8
Local principal investigator: Thomas Hanisco
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 56
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora56_OF_v5d20200131.txt
Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt
Level 1 file used: Pandora56s1_MaunaLoaHI_20250519_L1_smca1c9d20210409p1-8.txt
Full location name: Mauna Loa
Short location name: MaunaLoaHI
Country of location: USA
Location latitude [deg]: 19.4795
Location longitude [deg]: -155.6027
Location altitude [m]: 4169
Local noon date: 20250519
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1715 1864
Nominal wavelengths inside fitting window [nm]: 492.1202 492.2407 492.3612 492.4817 492.6021 492.7225 492.8430 492.9634 493.0838 493.2041 493.3245 493.4448 493.5651 493.6854 493.8057 493.9260 494.0463 494.1665 494.2867 494.4069 494.5271 494.6473 494.7674 494.8876 495.0077 495.1278 495.2479 495.3679 495.4880 495.6080 495.7281 495.8481 495.9680 496.0880 496.2080 496.3279 496.4478 496.5677 496.6876 496.8075 496.9273 497.0472 497.1670 497.2868 497.4066 497.5263 497.6461 497.7658 497.8855 498.0052 498.1249 498.2446 498.3642 498.4839 498.6035 498.7231 498.8426 498.9622 499.0818 499.2013 499.3208 499.4403 499.5598 499.6792 499.7987 499.9181 500.0375 500.1569 500.2763 500.3957 500.5150 500.6343 500.7537 500.8730 500.9922 501.1115 501.2307 501.3500 501.4692 501.5884 501.7075 501.8267 501.9458 502.0650 502.1841 502.3032 502.4222 502.5413 502.6603 502.7794 502.8984 503.0174 503.1363 503.2553 503.3742 503.4932 503.6121 503.7310 503.8498 503.9687 504.0875 504.2063 504.3251 504.4439 504.5627 504.6815 504.8002 504.9189 505.0376 505.1563 505.2750 505.3936 505.5122 505.6309 505.7495 505.8680 505.9866 506.1052 506.2237 506.3422 506.4607 506.5792 506.6976 506.8161 506.9345 507.0529 507.1713 507.2897 507.4081 507.5264 507.6447 507.7630 507.8813 507.9996 508.1179 508.2361 508.3543 508.4725 508.5907 508.7089 508.8271 508.9452 509.0633 509.1814 509.2995 509.4176 509.5357 509.6537 509.7717 509.8897
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250519T155117.2Z 9270.660616 189 1 48.67 2 89.61 68.97 38.29 176.62 0.00 1 0.00 1 0 29 5.977e-03 5.979e-03 8.776e-04 8.749e-04 2.778517e+03 5.182916e+01 2.046332e+02 -6.000000e+00 3.289375e+02 271.51 -2.00 20.00 -2.00 505.38 0.00e+00 1.409001e-03 2.390913e-05 7.281635e-05 -6.000000e+00 1.653112e-04 271.51 -2.00 20.00 -2.00 500.98 0.00e+00 1.333686e+00 1.726486e-02 2.492807e-02 -6.000000e+00 1.219226e-01 227.38 -2.00 3.11 -2.00 502.50 0.00e+00 20.609 0.039 489.00 513.00 1 5.2771e+00 1.3185e-03 1.8530e-02 -6.0000e+00 9.3143e-03 -5.1309e-02 3.3371e-04 1.1433e-03 -6.0000e+00 2.4237e-03 1.4836e-03 8.5924e-03 9.6431e-05 4.1527e-05 -6.0000e+00 6.7314e-04 6.3268e-02 -5.3919e-04 12 8 8 10 0 0 7.37 19.99 4.07 0.06327 0.12287 16 3 1 4 0 3041.370 25.17 20.02 19.99 7.63 19.9 650.45 -1155 -847 -200 211 309 1030 842 951 394 154 -99 -533 -708 -952 -502 -600 174 457 338 237 155 438 457 572 677 479 558 -284 -875 -702 -844 -583 -13 778 143 111 170 85 -71 -5 209 380 436 480 634 653 507 437 -238 -849 -934 -1316 -1145 -514 -161 155 94 273 328 497 505 625 503 754 411 -12 -3 -385 -606 -682 -324 -663 -181 -45 -128 -326 -517 -687 -731 -474 -606 -318 -777 -552 -321 -402 -307 -275 -320 -77 241 526 681 624 501 533 177 -435 -564 -1265 -1068 -1071 -511 -156 -277 -255 -349 -543 -400 -151 68 251 618 791 843 985 1160 1141 671 779 410 94 202 410 506 218 292 153 200 402 19 -16 -508 -665 -608 -249 -278 -397 -38 -35 108 166 2485 21 153 19 -318 -742 -962 -959 -1014 -763 -186 201 290 978 811 915 378 146 -94 -499 -656 -881 -465 -565 166 446 335 237 156 442 445 560 664 470 542 -283 -857 -675 -813 -569 -12 764 143 112 169 85 -70 -5 207 380 441 491 651 670 516 439 -236 -826 -888 -1241 -1082 -492 -158 156 96 270 326 493 503 624 504 751 407 -11 -3 -383 -599 -670 -318 -656 -180 -44 -125 -315 -511 -674 -713 -462 -595 -303 -751 -538 -316 -397 -305 -273 -319 -77 244 537 701 642 510 534 174 -421 -537 -1203 -1020 -1046 -512 -155 -279 -258 -350 -543 -399 -152 69 260 647 835 896 1019 1203 1184 695 824 431 99 211 429 532 223 299 157 205 411 19 -17 -526 -688 -632 -253 -288 -420 -41 -38 118 176 2686 22 165 20 -347 -799 -1027 -1024
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SQ 20250519T155754.3Z 9270.665212 197 1 50.07 2 88.15 69.51 38.21 179.11 0.00 1 0.00 1 0 22 4.193e-03 4.165e-03 4.720e-04 4.715e-04 1.440656e+03 2.685791e+01 1.050867e+02 -6.000000e+00 2.307646e+02 271.51 -2.00 20.00 -2.00 505.32 0.00e+00 1.048238e-03 1.280723e-05 5.413730e-05 -6.000000e+00 1.160351e-04 271.51 -2.00 20.00 -2.00 500.74 0.00e+00 1.246575e+00 9.347784e-03 1.443986e-02 -6.000000e+00 8.567266e-02 227.38 -2.00 3.11 -2.00 502.29 0.00e+00 16.971 0.022 489.00 513.00 1 4.5480e+00 7.1417e-04 1.5053e-02 -6.0000e+00 6.5428e-03 -3.0098e-02 1.8266e-04 8.6667e-04 -6.0000e+00 1.7064e-03 4.2703e-03 1.1366e-02 5.1977e-05 2.6959e-05 -6.0000e+00 4.7231e-04 5.4306e-02 -6.2628e-04 11 8 0 10 0 0 -35.56 20.00 2.46 0.05431 0.13315 41 8 1 4 0 1221.180 25.17 20.02 20.00 7.77 20.0 651.85 -806 -285 67 176 388 710 788 579 333 236 -82 -348 -633 -405 -598 -441 24 387 101 16 234 219 299 546 490 336 440 -158 -788 -502 -563 -492 238 585 134 -40 180 10 -201 -41 97 139 238 392 448 456 493 230 -38 -523 -730 -960 -970 -537 -161 13 -42 204 82 288 424 484 435 346 292 2 -12 -99 -386 -432 -318 -348 -277 69 -24 -349 -401 -439 -581 -479 -483 -533 -581 -278 -219 -313 -288 -189 -121 -175 77 269 503 361 495 362 36 -188 -543 -886 -939 -726 -412 -100 -121 -343 -207 -283 -187 -12 0 118 368 508 534 856 878 814 664 462 336 86 406 363 217 360 305 217 258 417 -30 -95 -159 -520 -380 -122 -185 -343 -22 39 34 191 735 213 215 122 -245 -421 -556 -638 -755 -265 64 173 379 703 789 582 333 234 -80 -338 -608 -386 -574 -428 24 390 101 16 236 221 303 555 499 342 443 -157 -767 -494 -554 -477 235 593 138 -42 185 10 -204 -42 98 142 239 397 457 464 497 229 -38 -515 -705 -916 -928 -521 -160 13 -43 205 83 291 429 491 442 351 293 2 -12 -96 -383 -425 -312 -344 -268 68 -24 -340 -396 -429 -566 -467 -474 -512 -563 -272 -215 -311 -287 -188 -121 -176 76 268 506 363 493 355 36 -183 -522 -845 -900 -708 -402 -99 -123 -348 -208 -283 -186 -12 0 122 374 521 552 887 913 845 686 472 339 87 407 365 220 365 310 221 262 421 -30 -95 -157 -512 -375 -122 -189 -357 -22 41 36 200 771 225 227 128 -254 -430 -577 -644
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