File name: Pandora56s1_MaunaLoaHI_20250627_L2Fit_fout2c9d20210409p1-8.txt File generation date: 20250628T103828.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Thomas Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 56 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora56_OF_v5d20200131.txt Instrument calibration file used: Pandora56s1_CF_v9d20210409.txt Level 1 file used: Pandora56s1_MaunaLoaHI_20250627_L1_smca1c9d20210409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20250627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 290 432 Nominal wavelengths inside fitting window [nm]: 305.0686 305.2091 305.3497 305.4902 305.6307 305.7712 305.9118 306.0522 306.1927 306.3332 306.4737 306.6141 306.7546 306.8950 307.0354 307.1758 307.3162 307.4566 307.5970 307.7373 307.8777 308.0180 308.1584 308.2987 308.4390 308.5793 308.7196 308.8599 309.0001 309.1404 309.2806 309.4208 309.5611 309.7013 309.8415 309.9817 310.1218 310.2620 310.4022 310.5423 310.6824 310.8226 310.9627 311.1028 311.2429 311.3829 311.5230 311.6631 311.8031 311.9431 312.0832 312.2232 312.3632 312.5032 312.6432 312.7831 312.9231 313.0630 313.2030 313.3429 313.4828 313.6227 313.7626 313.9025 314.0423 314.1822 314.3220 314.4619 314.6017 314.7415 314.8813 315.0211 315.1609 315.3006 315.4404 315.5801 315.7199 315.8596 315.9993 316.1390 316.2787 316.4183 316.5580 316.6977 316.8373 316.9769 317.1166 317.2562 317.3958 317.5354 317.6749 317.8145 317.9540 318.0936 318.2331 318.3726 318.5121 318.6516 318.7911 318.9306 319.0701 319.2095 319.3489 319.4884 319.6278 319.7672 319.9066 320.0460 320.1853 320.3247 320.4640 320.6034 320.7427 320.8820 321.0213 321.1606 321.2999 321.4392 321.5784 321.7177 321.8569 321.9961 322.1353 322.2745 322.4137 322.5529 322.6921 322.8312 322.9704 323.1095 323.2486 323.3877 323.5268 323.6659 323.8050 323.9440 324.0831 324.2221 324.3612 324.5002 324.6392 324.7782 324.9172 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250627T170638.7Z 9309.712948 64 1 50.16 2 73.39 70.61 103.03 61.02 0.00 1 0.00 1 0 25 5.112e-02 6.608e-03 4.078e-02 3.647e-03 4.079289e-01 1.924876e-03 4.258714e-03 -6.000000e+00 3.087510e-02 226.23 -2.00 3.11 -2.00 319.27 0.00e+00 1.484087e-03 4.790754e-04 1.726544e-04 -6.000000e+00 1.320681e-03 272.24 -2.00 20.00 -2.00 318.76 0.00e+00 3.448 0.000 302.00 328.00 3 5.0520e+00 5.3087e-03 2.8175e-02 -6.0000e+00 7.6598e-02 3.2823e-03 6.1203e-03 1.8642e-02 -6.0000e+00 8.3151e-02 -1.2857e-02 4.6647e-03 9.4459e-03 -6.0000e+00 4.9313e-02 -1.8293e-05 2.4470e-03 3.1676e-03 -6.0000e+00 2.0559e-02 2.3881e-04 -1.5297e-04 1.1894e-04 3.9429e-05 -6.0000e+00 1.6264e-03 -1.4340e-03 0.0000e+00 11 8 0 10 0 0 47.22 20.57 0.35 -0.00143 -0.00258 13 3 1 5 0 3858.300 25.58 20.05 20.57 18.73 20.7 702.31 18305 -6666 -245 -20126 -40387 6439 6225 -14524 -919 -8837 -13907 -9664 7771 -8012 -1233 -5876 -308 4787 -5218 -1782 -2571 -8520 3298 -5847 -1349 -84 1828 -4715 -600 2350 -2546 3675 -1697 323 -3060 1172 3146 -652 -675 -1016 84 -840 -1379 -626 6 -2107 950 484 209 875 1599 322 794 719 2411 1197 -302 -410 -26 256 1468 1610 1850 1625 1232 -1012 -131 357 1617 461 359 333 -403 218 -254 -122 -262 460 -59 -23 465 -1606 -963 -1186 -1003 -977 -563 133 -194 -656 -185 -201 1376 518 886 606 770 500 -94 -337 -611 -548 110 500 -396 -1516 -749 -444 247 -57 44 -401 311 448 16 1088 555 953 -541 -322 -365 -348 23 -155 385 653 845 1348 959 292 -30 -679 43 138 -335 -688 -129 575 -280 -342 -86 836 -653 363 -187 -7 -649 -1477 148 152 -477 -29 -322 -558 -404 317 -455 -76 -430 -23 367 -468 -161 -239 -852 303 -622 -145 -9 199 -531 -63 246 -305 462 -247 48 -462 170 487 -120 -148 -257 23 -251 -431 -198 2 -687 300 154 67 289 560 124 322 310 1069 553 -144 -196 -12 119 697 820 1014 959 746 -606 -75 203 965 305 260 249 -305 159 -173 -77 -153 260 -35 -15 345 -1343 -858 -1125 -1000 -1026 -619 148 -217 -720 -191 -195 1248 467 834 627 883 625 -126 -451 -788 -661 125 568 -473 -1921 -991 -612 357 -87 72 -669 509 707 23 1560 789 1392 -827 -517 -590 -562 36 -236 563 921 1147 1832 1377 452 -50 -1168 75 250 -635 -1360 -259 1169 -577 -688 -167 1561 -1218 SS 20250627T171700.4Z 9309.720143 67 1 50.35 2 71.08 71.22 100.98 62.10 0.00 1 0.00 1 0 17 3.097e-02 6.340e-03 2.350e-02 3.028e-03 3.616329e-01 1.590316e-03 3.808329e-03 -6.000000e+00 1.870663e-02 226.23 -2.00 3.11 -2.00 318.84 0.00e+00 1.218711e-04 3.462358e-04 2.153276e-04 -6.000000e+00 8.001437e-04 272.24 -2.00 20.00 -2.00 318.31 0.00e+00 3.050 0.000 302.00 328.00 3 5.0441e+00 4.3219e-03 2.4933e-02 -6.0000e+00 4.6409e-02 -1.8099e-02 4.9280e-03 1.6442e-02 -6.0000e+00 5.0379e-02 2.5536e-03 3.4934e-03 8.2523e-03 -6.0000e+00 2.9878e-02 -5.8914e-03 1.8215e-03 2.3909e-03 -6.0000e+00 1.2457e-02 3.2884e-04 -1.0822e-04 9.9270e-05 3.1416e-05 -6.0000e+00 9.8537e-04 -1.7772e-03 0.0000e+00 10 0 0 10 0 0 48.30 20.70 0.39 -0.00178 -0.00259 15 3 1 5 0 3355.980 25.68 20.03 20.70 19.74 20.7 706.02 -20341 -9651 -114 -5326 1281 -17751 2758 4192 3504 -8674 2488 5191 -4590 2805 -7491 -703 -1676 2026 2200 1996 30 -3498 -889 5313 -650 -2163 -3924 2000 1450 1052 593 -1954 4642 -4821 1167 -3627 -1773 239 -60 -2716 -1588 -1800 -623 -994 -1096 -740 -168 148 1227 -673 -312 1673 2268 1294 649 1510 12 573 -77 1570 940 1458 603 973 71 22 11 -126 1504 1814 755 -561 142 345 239 -47 535 939 311 143 -1134 -908 -1650 -1017 -788 -262 -695 -686 -614 -185 31 27 186 605 1143 1307 422 466 -440 -11 -679 -534 364 480 -797 -953 -983 -839 169 148 101 142 -496 408 -217 834 923 439 231 -523 -428 -310 402 505 109 637 691 1132 812 313 217 -568 -73 -56 -89 -283 -377 418 -421 -162 -257 627 -510 -874 -411 -5 -218 46 -754 103 169 157 -467 125 272 -302 200 -676 -66 -172 213 242 228 4 -439 -112 668 -92 -323 -597 276 194 145 87 -322 778 -919 206 -673 -351 54 -16 -848 -543 -656 -232 -378 -419 -282 -63 55 454 -261 -127 722 1041 628 331 786 6 306 -41 816 506 835 374 641 48 14 7 -79 966 1288 584 -455 115 271 178 -32 335 567 198 100 -897 -786 -1539 -1001 -814 -283 -794 -799 -717 -211 33 27 177 561 1108 1377 489 590 -592 -15 -874 -652 420 556 -977 -1227 -1317 -1169 247 227 163 235 -813 636 -321 1181 1288 627 344 -819 -686 -492 623 762 159 884 934 1525 1148 473 346 -943 -122 -97 -161 -535 -736 816 -833 -317 -489 1149 -923 SS 20250627T172330.1Z 9309.724654 71 1 51.41 2 69.63 71.58 99.68 62.75 0.00 1 0.00 1 0 25 1.888e-02 5.663e-03 1.592e-02 2.528e-03 3.386612e-01 1.326222e-03 3.582315e-03 -6.000000e+00 1.140060e-02 226.23 -2.00 3.11 -2.00 318.55 0.00e+00 4.575042e-05 2.650665e-04 1.671398e-04 -6.000000e+00 4.876080e-04 272.24 -2.00 20.00 -2.00 318.02 0.00e+00 2.846 0.000 302.00 328.00 3 4.9183e+00 3.5744e-03 2.3291e-02 -6.0000e+00 2.8284e-02 -1.9926e-02 4.0534e-03 1.5369e-02 -6.0000e+00 3.0702e-02 -5.6571e-04 2.7540e-03 7.6922e-03 -6.0000e+00 1.8208e-02 -2.5077e-03 1.4241e-03 2.2156e-03 -6.0000e+00 7.5922e-03 4.3618e-04 -6.7709e-05 8.3011e-05 2.9316e-05 -6.0000e+00 6.0047e-04 -2.3305e-03 0.0000e+00 11 1 0 11 8 0 92.53 20.77 0.31 -0.00233 -0.00284 17 3 1 5 0 3024.080 25.79 20.03 20.77 20.36 20.8 709.01 -11309 1207 -3579 -612 -4405 -5367 -384 -5067 3795 -3029 -4555 -2812 -8053 -639 -3816 3772 120 -1366 -308 303 279 1187 2237 1654 -601 250 1009 -2349 1549 3270 4331 2333 948 409 -2254 -3184 -1595 -979 619 155 -1105 -1578 -1539 -1494 -461 -999 -277 -754 437 -30 693 549 1471 599 1065 890 -14 300 290 508 1148 552 198 591 -135 -554 1146 895 1123 1982 -90 291 -440 -286 179 216 -222 53 836 -643 -222 -1000 -994 -1326 -651 -685 -287 -7 -355 -340 153 199 722 584 1095 914 857 149 -437 -134 -740 -362 -231 363 -417 -1081 -709 -517 250 211 216 -240 -182 189 364 672 711 603 52 -344 -357 -534 42 269 341 534 609 697 754 338 77 -211 -249 -319 -333 -163 -8 388 -486 -347 -249 1106 -577 -574 59 -189 -30 -213 -255 -18 -282 213 -193 -305 -197 -666 -57 -403 410 15 -177 -41 42 40 169 324 255 -100 43 171 -397 242 503 702 422 188 84 -465 -665 -355 -248 182 53 -418 -637 -642 -632 -194 -421 -115 -311 178 -12 304 259 725 315 581 500 -8 171 165 286 661 338 130 413 -96 -379 741 574 761 1457 -73 244 -373 -236 138 154 -147 34 550 -472 -179 -891 -946 -1330 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