File name: Pandora59s1_MaunaLoaHI_20181206_L2Fit_fwvt1c1d20180409p1-8.txt File generation date: 20241122T192822.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 59 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora59_OF_v2d20180409.txt Instrument calibration file used: Pandora59s1_CF_v1d20180409.txt Level 1 file used: Pandora59s1_MaunaLoaHI_20181206_L1_smca1c1d20180409p1-8.txt Full location name: Mauna Loa Short location name: MaunaLoaHI Country of location: USA Location latitude [deg]: 19.4795 Location longitude [deg]: -155.6027 Location altitude [m]: 4169 Local noon date: 20181206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, radiometric temperature correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial FieldCal based on session 5 First and last pixel inside fitting window: 1707 1857 Nominal wavelengths inside fitting window [nm]: 492.0532 492.1738 492.2944 492.4150 492.5355 492.6560 492.7766 492.8971 493.0175 493.1380 493.2584 493.3789 493.4993 493.6197 493.7401 493.8604 493.9808 494.1011 494.2214 494.3417 494.4620 494.5822 494.7025 494.8227 494.9429 495.0631 495.1833 495.3034 495.4236 495.5437 495.6638 495.7839 495.9040 496.0240 496.1441 496.2641 496.3841 496.5041 496.6241 496.7440 496.8640 496.9839 497.1038 497.2237 497.3435 497.4634 497.5832 497.7030 497.8228 497.9426 498.0624 498.1821 498.3019 498.4216 498.5413 498.6610 498.7806 498.9003 499.0199 499.1395 499.2591 499.3787 499.4983 499.6178 499.7373 499.8569 499.9764 500.0958 500.2153 500.3347 500.4542 500.5736 500.6929 500.8123 500.9317 501.0510 501.1703 501.2896 501.4089 501.5282 501.6474 501.7667 501.8859 502.0051 502.1243 502.2434 502.3626 502.4817 502.6008 502.7199 502.8390 502.9580 503.0771 503.1961 503.3151 503.4341 503.5531 503.6720 503.7910 503.9099 504.0288 504.1477 504.2665 504.3854 504.5042 504.6230 504.7418 504.8606 504.9794 505.0981 505.2168 505.3355 505.4542 505.5729 505.6916 505.8102 505.9288 506.0474 506.1660 506.2846 506.4031 506.5216 506.6402 506.7586 506.8771 506.9956 507.1140 507.2324 507.3509 507.4692 507.5876 507.7060 507.8243 507.9426 508.0609 508.1792 508.2975 508.4157 508.5339 508.6521 508.7703 508.8885 509.0066 509.1248 509.2429 509.3610 509.4791 509.5971 509.7152 509.8332 509.9512 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Columns 98-248: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 249-399: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20181206T164809.0Z 6914.700104 1 1 32.00 2 89.82 114.06 82.91 112.00 0.00 1 0.00 1 0 57 1.394e-01 2.522e-01 4.972e-03 4.874e-03 2.144813e+02 2.624023e+02 3.095106e+02 -6.000000e+00 7.327899e+03 269.75 -2.00 20.00 -2.00 505.25 0.00e+00 -2.310179e-02 1.268810e-04 1.096246e-03 -6.000000e+00 3.783451e-03 269.75 -2.00 20.00 -2.00 500.03 0.00e+00 4.351033e+00 9.762885e-02 1.806955e-01 -6.000000e+00 2.776123e+00 223.08 -2.00 3.11 -2.00 501.75 0.00e+00 20.959 0.041 489.00 513.00 1 9.2379e+00 7.4476e-03 3.5087e-02 -6.0000e+00 2.1166e-01 4.5015e-02 1.9585e-03 2.2759e-03 -6.0000e+00 5.5592e-02 3.0319e-05 -1.2093e-03 3.8402e-04 3.9024e-04 -6.0000e+00 1.4097e-02 -2.6571e-02 4.1053e-04 12 9 8 11 8 0 -242.44 20.78 0.21 -0.02657 -0.03496 8 2 1 4 0 4000.000 25.07 20.03 20.78 8957 11164 9620 9967 9919 10438 11193 10527 11826 13655 13452 15057 15404 17875 16703 17265 19817 23454 23372 24236 -106427 22379 23794 22598 21209 19146 18820 19004 19517 20067 20296 21405 22013 22821 23057 20121 18571 19168 18938 16985 15593 14405 10962 8920 7822 6114 3832 2861 2941 2055 474 1323 -1864 -1505 -2728 -1434 -3440 -4892 -3576 -6788 -6399 -6076 -5577 -8665 -7773 -8221 -7996 -5625 -8195 -7103 -9243 -4261 -6884 -3721 -5753 -4226 -6568 -7469 -7463 -6353 -4906 -2743 254 -71 1287 1733 2623 4673 8135 7387 5914 7272 3333 617 -2617 -2820 -3410 -3913 -2119 -1457 3265 5255 7980 10889 11976 11825 7158 10587 8811 9479 5930 3526 2373 -687 -1227 -1411 -1790 -1594 -4443 -2824 -1246 -4020 -967 -4238 -4092 -5656 -5878 -5743 -7563 -6659 -7312 -8178 -7416 -5335 -4934 -3903 -1099 -3404 647 291 1386 2077 4657 4185 4997 5824 2788 4615 5107 6578 900000 8520 10547 9296 9892 10104 10623 11580 11156 12483 14173 13972 15314 15464 17759 16846 17236 19848 23509 24265 25483 -272878 23793 25334 23702 22355 20365 19835 19675 20019 19973 19963 20973 21925 23279 23558 21275 19754 19903 19264 17212 15709 14468 11281 9307 8191 6436 4057 2993 2991 2037 468 1255 -1790 -1443 -2646 -1406 -3496 -5058 -3622 -7024 -6547 -6183 -5637 -8813 -7755 -8276 -7902 -5352 -7904 -6706 -8885 -3927 -6614 -3524 -5618 -4045 -6328 -7124 -7034 -5915 -4550 -2535 232 -67 1222 1641 2504 4434 7695 6962 5678 6891 3267 612 -2617 -2754 -3261 -3665 -1951 -1326 2883 4731 7237 10156 11513 11323 7126 10170 8408 8835 5679 3376 2286 -678 -1210 -1391 -1775 -1579 -4417 -2779 -1188 -3874 -893 -4031 -3878 -5415 -5604 -5433 -7247 -6306 -6933 -7733 -6882 -4824 -4467 -3570 -1009 -3233 617 279 1335 2015 4467 4083 4873 5634 2755 4403 4768 6002 900000 SO 20181206T165004.0Z 6914.701435 3 1 32.00 2 89.41 114.22 82.51 112.18 0.00 1 0.00 1 0 29 8.749e-02 1.526e-01 4.316e-03 4.266e-03 1.526617e+03 2.415662e+02 7.834935e+01 -6.000000e+00 4.597764e+03 269.75 -2.00 20.00 -2.00 505.27 0.00e+00 -1.115388e-02 1.121531e-04 5.273178e-04 -6.000000e+00 2.369891e-03 269.75 -2.00 20.00 -2.00 500.19 0.00e+00 2.523392e+00 8.493383e-02 9.442322e-02 -6.000000e+00 1.726404e+00 223.08 -2.00 3.11 -2.00 501.87 0.00e+00 20.294 0.037 489.00 513.00 1 9.0954e+00 6.4910e-03 2.3164e-02 -6.0000e+00 1.3187e-01 5.7331e-02 1.6772e-03 1.5168e-03 -6.0000e+00 3.4171e-02 3.6273e-05 -1.9269e-03 3.8728e-04 1.8177e-04 -6.0000e+00 8.8185e-03 3.8580e-03 9.8526e-05 12 9 8 11 8 0 -119.43 20.75 0.19 0.00386 -0.00951 8 2 1 4 0 4000.000 25.07 20.31 20.75 4070 4564 4764 4784 4141 5497 4977 5282 5556 6787 5892 6881 7247 8904 8345 7464 9081 11799 10916 12187 -83934 11758 12482 11942 10677 9232 9046 9225 9455 9546 9950 10376 10799 11832 12043 9403 9016 9216 8728 7699 9152 7732 4972 4763 3978 2806 2220 829 1752 1900 489 -239 -683 -57 -1329 -1196 -2156 -2846 -1580 -2436 -3022 -2820 -3354 -4367 -2787 -3509 -3873 -1781 -3043 -3091 -4066 -2576 -3404 -2289 -3050 -2206 -2970 -3007 -2952 -2898 -2835 -1861 188 63 9 103 1214 1799 5376 4438 3183 4270 2191 293 -1509 -1431 -1244 -1219 -772 -977 1400 2570 2449 5008 4341 5912 2159 6912 4580 4631 2514 2167 1645 275 -427 -206 -637 616 -2879 -773 -247 -2502 -1074 -2314 -1772 -1739 -4071 -2620 -4417 -3088 -4091 -4118 -3776 -3135 -4074 -2496 -674 -2640 886 -669 1093 371 2844 853 2663 3601 -254 2289 3239 3339 1263 3907 4414 4636 4810 4220 5656 5259 5643 5833 7148 6213 7121 7381 9003 8298 7553 9227 12013 11555 12736 -171824 12481 13136 12612 11396 9949 9682 9725 9714 9713 9921 10327 10901 11963 12501 10125 9691 9747 9120 7998 9268 7901 5220 5022 4153 2953 2326 867 1810 1904 480 -234 -660 -55 -1292 -1193 -2176 -2920 -1598 -2470 -3068 -2858 -3422 -4491 -2799 -3501 -3817 -1726 -2949 -2962 -3904 -2445 -3294 -2223 -2960 -2120 -2891 -2874 -2783 -2716 -2669 -1756 176 60 8 99 1173 1741 5050 4234 3094 4131 2175 290 -1499 -1391 -1200 -1145 -706 -898 1258 2334 2271 4746 4223 5755 2174 6532 4351 4354 2415 2100 1610 268 -420 -203 -631 604 -2911 -757 -241 -2458 -1028 -2236 -1706 -1672 -3924 -2527 -4240 -2972 -3888 -3943 -3552 -2902 -3799 -2317 -630 -2534 839 -655 1064 361 2777 841 2596 3476 -253 2214 3044 3098 1198 SO 20181206T165156.0Z 6914.702731 5 1 32.00 2 89.00 114.38 82.12 112.36 0.00 1 0.00 1 0 22 7.497e-02 1.255e-01 3.825e-03 3.789e-03 1.416342e+03 2.133704e+02 5.092362e+01 -6.000000e+00 3.939194e+03 269.75 -2.00 20.00 -2.00 505.26 0.00e+00 -8.194065e-03 9.962414e-05 3.709101e-04 -6.000000e+00 2.031540e-03 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